Fundamental spectroscopic studies of carbenes and hydrocarbon radicals
This document details activities during this reporting period topics discussed are: The first spectroscopic identification of the HCCCO and DCCCO radicals; detection of new vibrationally excited states of the carbon chain radicals CCH and CCD and the three-membered carbene ring, cyclopropenylidene; determination of an accurate structure of the cumulene carbene H{sub 2}CCC; analysis the hyperfine structure in the SiC radical; and the undertaking of a systematic search for new sulfur bearing radicals.
- Research Organization:
- Harvard Univ., Cambridge, MA (United States)
- Sponsoring Organization:
- USDOE; USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-88ER13912
- OSTI ID:
- 5021895
- Report Number(s):
- DOE/ER/13912-4; ON: DE92014989
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBENES
MICROWAVE SPECTRA
RADICALS
ORGANIC SULFUR COMPOUNDS
PROGRESS REPORT
ROTATION-VIBRATION MODEL
SILICON CARBIDES
STRUCTURAL CHEMICAL ANALYSIS
VIBRATIONAL STATES
CARBIDES
CARBON COMPOUNDS
COLLECTIVE MODEL
DOCUMENT TYPES
ENERGY LEVELS
EXCITED STATES
MATHEMATICAL MODELS
NUCLEAR MODELS
ORGANIC COMPOUNDS
SILICON COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBENES
MICROWAVE SPECTRA
RADICALS
ORGANIC SULFUR COMPOUNDS
PROGRESS REPORT
ROTATION-VIBRATION MODEL
SILICON CARBIDES
STRUCTURAL CHEMICAL ANALYSIS
VIBRATIONAL STATES
CARBIDES
CARBON COMPOUNDS
COLLECTIVE MODEL
DOCUMENT TYPES
ENERGY LEVELS
EXCITED STATES
MATHEMATICAL MODELS
NUCLEAR MODELS
ORGANIC COMPOUNDS
SILICON COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties