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Title: Fully screen-printed bifacial large area 22.6% N-type Si solar cell with lightly doped ion-implanted boron emitter and tunnel oxide passivated rear contact

Journal Article · · Solar Energy Materials and Solar Cells

We report on the fabrication of fully screen-printed bifacial large area (239 cm2) high-efficiency n-type Si solar cells with ion-implanted homogeneous boron emitter on the front side and carrier-selective tunnel oxide passivated contact (TOPCon) on the rear. Our phosphorus-doped poly-Si/SiOx passivated contact with SiNx capping layer gave excellent surface passivation with a very low recombination current density (J0_TOPCon) of ~1 fA/cm2 after a simulated firing treatment at ~770 °C without metallization. After screen-printed and fire-through metallization on n-TOPCon with ~13% metal coverage, metallized J0_TOPCon value increased to only ~5 fA/cm2. In addition, homogenous boron implanted emitter (~180 Ω/sq) passivated with ALD Al2O3 layer capped with PECVD SiNx/SiOx double-layer antireflection (DLAR) coating gave excellent passivation with emitter recombination current density of ~12 fA/cm2 prior to metallization. The industrial screen-printed, fire-through contacts with floating busbars on this boron emitter gave metallized emitter recombination current density of ~31 fA/cm2. Furthermore, this resulted in a low-cost industrial screen-printed n-type bifacial Si solar cell with 22.6% efficiency and 702 mV open-circuit voltage (Voc).

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
Grant/Contract Number:
EE0007554
OSTI ID:
1893732
Alternate ID(s):
OSTI ID: 1619841; OSTI ID: 1893901
Journal Information:
Solar Energy Materials and Solar Cells, Vol. 214; ISSN 0927-0248
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 23 works
Citation information provided by
Web of Science

References (16)

Surface passivation of crystalline silicon solar cells: Present and future journal December 2018
Passivated rear contacts for high-efficiency n-type Si solar cells providing high interface passivation quality and excellent transport characteristics journal January 2014
Optical and electrical characterization of poly-Si/SiOx contacts and their implications on solar cell design journal September 2017
Tunnel oxide passivated carrier-selective contacts based on ultra-thin SiO 2 layers journal November 2015
Nitric acid oxidation of Si (NAOS) method for low temperature fabrication of SiO2/Si and SiO2/SiC structures journal July 2010
Metal contact recombination in monoPoly™ solar cells with screen-printed & fire-through contacts journal April 2019
Screen printed, large area bifacial N-type back junction silicon solar cells with selective phosphorus front surface field and boron doped poly-Si/SiO x passivated rear emitter journal December 2018
monoPoly™ cells: Large-area crystalline silicon solar cells with fire-through screen printed contact to doped polysilicon surfaces journal December 2018
Passivating Contacts for Crystalline Silicon Solar Cells: From Concepts and Materials to Prospects journal March 2018
n-Type Si solar cells with passivating electron contact: Identifying sources for efficiency limitations by wafer thickness and resistivity variation journal December 2017
The application of poly-Si/SiOx contacts as passivated top/rear contacts in Si solar cells journal January 2017
Mass production of industrial tunnel oxide passivated contacts (i‐TOPCon) silicon solar cells with average efficiency over 23% and modules over 345 W journal July 2019
Excellent passivation of highly doped p-type Si surfaces by the negative-charge-dielectric Al2O3 journal September 2007
24.58% total area efficiency of screen-printed, large area industrial silicon solar cells with the tunnel oxide passivated contacts (i-TOPCon) design journal March 2020
Development of thin polysilicon layers for application in monoPoly™ cells with screen-printed and fired metallization journal April 2020
From Laboratory to Production: Learning Models of Efficiency and Manufacturing Cost of Industrial Crystalline Silicon and Thin-Film Photovoltaic Technologies journal November 2018