Metamagnetism and kinetic arrest in a long-range ferromagnetically ordered multicaloric double perovskite Y2CoMnO6

Madhogaria, R. P.; Clements, E. M.; Kalappattil, V.; Phan, M. H.; Srikanth, H.; Das, R.; Dang, N. T.; Kozlenko, D. P.; Bingham, N. S.

doi:10.1016/j.jmmm.2020.166821

Title: Metamagnetism and kinetic arrest in a long-range ferromagnetically ordered multicaloric double perovskite Y₂CoMnO₆

Journal Article · Mon Mar 30 00:00:00 EDT 2020 · Journal of Magnetism and Magnetic Materials

DOI:https://doi.org/10.1016/j.jmmm.2020.166821· OSTI ID:1800500

Madhogaria, R. P. ^[1]; Clements, E. M. ^[1]; Kalappattil, V. ^[1]; Phan, M. H. ^[1]; Srikanth, H. ^[1]; Das, R. ^[2]; Dang, N. T. ^[3]; Kozlenko, D. P. ^[4]; Bingham, N. S. ^[5]

Univ. of South Florida, Tampa, FL (United States)
Phenikaa University, Hanoi (Vietnam)
Duy Tan University, Da Nang (Vietnam)
Joint Inst. for Nuclear Research (JINR), Dubna (Russian Federation). Frank Laboratory of Neutron Physics
Yale Univ., New Haven, CT (United States)

A systematic magnetic study of the double perovskite oxide Y₂CoMnO₆(YCMO) has been performed. A monoclinic P21/n phase of YCMO was synthesized using a sol-gel method. Neutron diffraction (ND) measurements evidence the onset of long-range ferromagnetic (FM) ordering at TC ~ 76 K, which persists down to 5 K. The presence of 25% antisite disorder, estimated from the ND data, leads to the appearance of short-range antiferromagnetic (AFM) interactions. The existence of thermal hysteresis due to competing interactions between FM and AFM phases is observed in the M vs. T measurements. The pinning of magnetic domain walls at the Co/Mn antiphase boundaries results in a metamagnetic-like behavior. The field dependence of thermomagnetic irreversibility and the nature of virgin curves indicate the occurrence of a kinetic arrest phenomenon, which is further verified via cooling and heating of the system in an unequal fields (CHUF) protocol. In full agreement with the ND data, a detailed analysis of critical exponents near the paramagnetic (PM)-FM phase transition also establishes YCMO as a long-range interacting mean-field system. A close examination of the temperature- and field-dependent magnetic entropy change yields an in-depth understanding of coexisting magnetically ordered and disordered phases in YCMO, leading to a comprehensive magnetic phase diagram of this multifunctional double perovskite system.

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Research Organization:: Univ. of South Florida, Tampa, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC); Vietnam National Foundation for Science and Technology Development (NAFOSTED); Russian Foundation for Basic Research

Grant/Contract Number:: FG02-07ER46438; 103.02-2017.364; 18-02-00359-a

OSTI ID:: 1800500

Alternate ID(s):: OSTI ID: 1609026

Journal Information:: Journal of Magnetism and Magnetic Materials, Vol. 507, Issue C; ISSN 0304-8853

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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References (37)

Evidence of large magneto-dielectric effect coupled to a metamagnetic transition in Yb ₂ CoMnO ₆ Blasco, J.; García-Muñoz, J. L.; García, J. Applied Physics Letters, Vol. 107, Issue 1 https://doi.org/10.1063/1.4926403	journal	July 2015
Multicaloric effect in multiferroic Y ₂ CoMnO ₆ Krishna Murthy, J.; Venimadhav, A. Journal of Physics D: Applied Physics, Vol. 47, Issue 44 https://doi.org/10.1088/0022-3727/47/44/445002	journal	October 2014
Review of the magnetocaloric effect in manganite materials Phan, Manh-Huong; Yu, Seong-Cho Journal of Magnetism and Magnetic Materials, Vol. 308, Issue 2 https://doi.org/10.1016/j.jmmm.2006.07.025	journal	January 2007
A universal curve for the magnetocaloric effect: an analysis based on scaling relations Franco, V.; Conde, A.; Romero-Enrique, J. M. Journal of Physics: Condensed Matter, Vol. 20, Issue 28 https://doi.org/10.1088/0953-8984/20/28/285207	journal	June 2008
Ferromagnetic interactions in non-metallic perovskites Blasse, G. Journal of Physics and Chemistry of Solids, Vol. 26, Issue 12 https://doi.org/10.1016/0022-3697(65)90231-3	journal	December 1965
Pronounced first-order metamagnetic transition in the paramagnetic heavy-fermion system CeTiGe Deppe, M.; Lausberg, S.; Weickert, F. Physical Review B, Vol. 85, Issue 6 https://doi.org/10.1103/PhysRevB.85.060401	journal	February 2012
Room temperature ferromagnetism in pure Y ₂ O ₃ nanoparticles Zhu, Zhonghua; Gao, Daqiang; Yang, Guijin EPL (Europhysics Letters), Vol. 97, Issue 1 https://doi.org/10.1209/0295-5075/97/17005	journal	January 2012
The DN-6 Neutron Diffractometer for High-Pressure Research at Half a Megabar Scale Kozlenko, Denis; Kichanov, Sergey; Lukin, Evgenii Crystals, Vol. 8, Issue 8 https://doi.org/10.3390/cryst8080331	journal	August 2018
Static critical phenomena in ferromagnets with quenched disorder Kaul, S. N. Journal of Magnetism and Magnetic Materials, Vol. 53, Issue 1-2 https://doi.org/10.1016/0304-8853(85)90128-3	journal	November 1985
Approximate Equation of State For Nickel Near its Critical Temperature Arrott, Anthony; Noakes, John E. Physical Review Letters, Vol. 19, Issue 14 https://doi.org/10.1103/PhysRevLett.19.786	journal	October 1967
Metamagnetic behaviour and effect of field cooling on sharp magnetization jumps in multiferroic Y ₂ CoMnO ₆ Krishna Murthy, J.; Chandrasekhar, K. D.; Wu, H. C. EPL (Europhysics Letters), Vol. 108, Issue 2 https://doi.org/10.1209/0295-5075/108/27013	journal	October 2014
Macroscopic Measurement of Resonant Magnetization Tunneling in High-Spin Molecules Friedman, Jonathan R.; Sarachik, M. P.; Tejada, J. Physical Review Letters, Vol. 76, Issue 20 https://doi.org/10.1103/PhysRevLett.76.3830	journal	May 1996
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
First-order transition from antiferromagnetism to ferromagnetism in ${C e (F e}_{0.96} {Al}_{0.04})_{2}$ Manekar, M. A.; Chaudhary, S.; Chattopadhyay, M. K. Physical Review B, Vol. 64, Issue 10 https://doi.org/10.1103/PhysRevB.64.104416	journal	August 2001
Magnetic order and magnetoelectric properties of $R_{2} CoMn O_{6}$ perovskites ( $R = Ho$ , Tm, Yb, and Lu) Blasco, J.; García-Muñoz, J. L.; García, J. Physical Review B, Vol. 96, Issue 2 https://doi.org/10.1103/PhysRevB.96.024409	journal	July 2017
The CTM4XAS program for EELS and XAS spectral shape analysis of transition metal L edges Stavitski, Eli; de Groot, Frank M. F. Micron, Vol. 41, Issue 7 https://doi.org/10.1016/j.micron.2010.06.005	journal	October 2010
Atomic and magnetic structures, disorder effects, and unconventional superexchange interactions in $A_{2} {MnGaO}_{5 + δ}$ $(A = S r, Ca)$ oxides of layered brownmillerite-type structure Pomjakushin, V. Yu.; Balagurov, A. M.; Elzhov, T. V. Physical Review B, Vol. 66, Issue 18 https://doi.org/10.1103/PhysRevB.66.184412	journal	November 2002
Ultrasharp Magnetization Steps in Perovskite Manganites Mahendiran, R.; Maignan, A.; Hébert, S. Physical Review Letters, Vol. 89, Issue 28 https://doi.org/10.1103/PhysRevLett.89.286602	journal	December 2002
Macroscopic phase diagram and magnetocaloric study of metamagnetic transitions in the spin chain system ${Ca}_{3} {Co}_{2} O_{6}$ Lampen, P.; Bingham, N. S.; Phan, M. H. Physical Review B, Vol. 89, Issue 14 https://doi.org/10.1103/PhysRevB.89.144414	journal	April 2014
Ferromagnetic Y2CoMnO6: Spin-Glass-Like Behavior and Dielectric Relaxation Zhang, Chao; Wang, Xiaofei; Yan, Haitao Journal of Electronic Materials, Vol. 43, Issue 4 https://doi.org/10.1007/s11664-014-2981-0	journal	January 2014
On a generalised approach to first and second order magnetic transitions Banerjee, B. K. Physics Letters, Vol. 12, Issue 1 https://doi.org/10.1016/0031-9163(64)91158-8	journal	September 1964
Exchange bias Nogués, J.; Schuller, Ivan K. Journal of Magnetism and Magnetic Materials, Vol. 192, Issue 2 https://doi.org/10.1016/S0304-8853(98)00266-2	journal	February 1999
Critical behavior at paramagnetic to ferromagnetic phase transition in ${Pr}_{0.5} {Sr}_{0.5} {MnO}_{3}$ : A bulk magnetization study Pramanik, A. K.; Banerjee, A. Physical Review B, Vol. 79, Issue 21 https://doi.org/10.1103/PhysRevB.79.214426	journal	June 2009
Evidence of long-range ferromagnetic order and spin frustration effects in the double perovskite ${La}_{2} {CoMnO}_{6}$ Madhogaria, R. P.; Das, R.; Clements, E. M. Physical Review B, Vol. 99, Issue 10 https://doi.org/10.1103/PhysRevB.99.104436	journal	March 2019
Enhancement of Ferroelectricity in Strained BaTiO₃ Thin Films Choi, K. J.; Biegalski, M.; Li, Y. L. Science, Vol. 306, Issue 5698, p. 1005-1009 https://doi.org/10.1126/science.1103218	journal	November 2004
Strong pinning effect and magnetic nanodomain formation by coupling between magnetic and crystallographic domains in the ordered double perovskite ${Ba}_{2} Fe Mo O_{6}$ Asaka, T.; Yu, X. Z.; Tomioka, Y. Physical Review B, Vol. 75, Issue 18 https://doi.org/10.1103/PhysRevB.75.184440	journal	May 2007
Magnetization-steps in Y ₂ CoMnO ₆ double perovskite: The role of antisite disorder Nair, Harikrishnan S.; Pradheesh, R.; Xiao, Yinguo Journal of Applied Physics, Vol. 116, Issue 12 https://doi.org/10.1063/1.4896399	journal	September 2014
Observation of spontaneous magnetization jump and field-induced irreversibility in Nd ₅ Ge ₃ Maji, B.; Suresh, K. G.; Nigam, A. K. EPL (Europhysics Letters), Vol. 91, Issue 3 https://doi.org/10.1209/0295-5075/91/37007	journal	August 2010
Interfacial room temperature magnetism and enhanced magnetocaloric effect in strained ${La}_{0.66} {Ca}_{0.34} {MnO}_{3} / {BaTiO}_{3}$ heterostructures Bingham, N. S.; Suszka, A. K.; Vaz, C. A. F. Physical Review B, Vol. 96, Issue 2 https://doi.org/10.1103/PhysRevB.96.024419	journal	July 2017
The ferroelectric polarization of Y ₂ CoMnO ₆ aligns along the b-axis: the first-principles calculations Ma, C. Y.; Dong, S.; Zhou, P. X. Physical Chemistry Chemical Physics, Vol. 17, Issue 32 https://doi.org/10.1039/C5CP02501J	journal	January 2015
Valence states and metamagnetic phase transition in partially $B$ -site-disordered perovskite $Eu {Mn}_{0.5} {Co}_{0.5} O_{3}$ Vasiliev, A. N.; Volkova, O. S.; Lobanovskii, L. S. Physical Review B, Vol. 77, Issue 10 https://doi.org/10.1103/PhysRevB.77.104442	journal	March 2008
Multiple magnetic phases of ${La}_{2} {CoMnO}_{6 - δ}$ $(0 <~ δ <~ 0.05)$ Dass, R. I.; Goodenough, J. B. Physical Review B, Vol. 67, Issue 1 https://doi.org/10.1103/PhysRevB.67.014401	journal	January 2003
A2B′B″O6 perovskites: A review Vasala, Sami; Karppinen, Maarit Progress in Solid State Chemistry, Vol. 43, Issue 1-2 https://doi.org/10.1016/j.progsolidstchem.2014.08.001	journal	May 2015
Critical Behavior and Macroscopic Phase Diagram of the Monoaxial Chiral Helimagnet Cr1/3NbS2 Clements, Eleanor M.; Das, Raja; Li, Ling Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-06728-5	journal	July 2017
Critical behavior of amorphous ferromagnetic alloys Kaul, S. IEEE Transactions on Magnetics, Vol. 20, Issue 5 https://doi.org/10.1109/TMAG.1984.1063534	journal	September 1984
Heisenberg-like ferromagnetism in $3 d − 4 f$ intermetallic ${La}_{0.75} \Pr_{0.25} {Co}_{2} P_{2}$ with localized Co moments Lampen, P.; Phan, M. H.; Srikanth, H. Physical Review B, Vol. 90, Issue 17 https://doi.org/10.1103/PhysRevB.90.174404	journal	November 2014
Universal behavior for magnetic entropy change in magnetocaloric materials: An analysis on the nature of phase transitions Bonilla, Claudia Marcela; Herrero-Albillos, Julia; Bartolomé, Fernando Physical Review B, Vol. 81, Issue 22 https://doi.org/10.1103/PhysRevB.81.224424	journal	June 2010

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Title: Metamagnetism and kinetic arrest in a long-range ferromagnetically ordered multicaloric double perovskite Y2CoMnO6

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Title: Metamagnetism and kinetic arrest in a long-range ferromagnetically ordered multicaloric double perovskite Y₂CoMnO₆