Methods of selectively incorporating metals onto substrates

Ernst, Richard D.; Eyring, Edward M.; Turpin, Gregory C.; Dunn, Brian C.

Title: Methods of selectively incorporating metals onto substrates

Patent · Tue Sep 30 00:00:00 EDT 2008

OSTI ID:984514

Ernst, Richard D. ^[1]; Eyring, Edward M. ^[1]; Turpin, Gregory C. ^[1]; Dunn, Brian C. ^[1]

Salt Lake City, UT

A method for forming multi-metallic sites on a substrate is disclosed and described. A substrate including active groups such as hydroxyl can be reacted with a pretarget metal complex. The target metal attached to the active group can then be reacted with a secondary metal complex such that an oxidation-reduction (redox) reaction occurs to form a multi-metallic species. The substrate can be a highly porous material such as aerogels, xerogels, zeolites, and similar materials. Additional metal complexes can be reacted to increase catalyst loading or control co-catalyst content. The resulting compounds can be oxidized to form oxides or reduced to form metals in the ground state which are suitable for practical use.

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Research Organization:: Univ. of Kentucky, Lexington, KY (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FC26-05NT42456

Assignee:: University of Utah Research Foundation (Salt Lake City, UT)

Patent Number(s):: 7,429,404

Application Number:: 11/215,828; TRN: US201016%%1344

OSTI ID:: 984514

Country of Publication:: United States

Language:: English

References (18)

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