skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

Patent ·
OSTI ID:982354

The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

Research Organization:
Lake County Sanitation District, Lakeport, CA (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Energy Efficiency and Renewable Energy (EE)
DOE Contract Number:
FG07-96ID13428
Assignee:
Georgia Tech Research Corporation (Atlanta, GA)
Patent Number(s):
7,390,669
Application Number:
10/999,912
OSTI ID:
982354
Country of Publication:
United States
Language:
English

References (8)

The optical absorption of hydroxyl ions associated with divalent calcium in NaCl journal May 1969
Spectrophotometric in-line monitoring of the electrochemical production of polysulfides using an ATR-probe journal July 1998
Über Lichtabsorption und Konstitution von Komplexsalzen. II. Untersuchungen an aliphatischen Aminosäuren und inneren Komplexsalzen des Kupfers journal March 1930
Advanced Process Control Minimizes Kraft Mill Effluents journal January 1977
Police and society journal January 1993
Ménages et familles dans les recensements journal January 1974
ATR technique for UV/VIS analytical measurements journal January 1987
Determination of inorganic anions in Kraft pulping liquors by capillary electrophoresis journal March 1996

Similar Records

Effect of pulping variables on enthalpy of kraft black liquors: Empirical predictive models
Journal Article · Mon Jul 01 00:00:00 EDT 1996 · Industrial and Engineering Chemistry Research · OSTI ID:982354

Recaustization of kraft black liquor via bipolar electrodialysis
Technical Report · Tue May 01 00:00:00 EDT 1990 · OSTI ID:982354

Technical Report Cellulosic Based Black Liquor Gasification and Fuels Plant Final Technical Report
Technical Report · Wed Oct 31 00:00:00 EDT 2012 · OSTI ID:982354