CO2 Capture by Absorption with Potassium Carbonate
The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. In Campaign 3 of the pilot plant, the overall mass transfer coefficient for the stripper with 7 m MEA decreased from 0.06 to 0.01 mol/(m{sup 3}.s.kPa) as the rich loading increased from 0.45 to 0.6 mol CO{sub 2}/mol MEA. Anion chromatography has demonstrated that nitrate and nitrite are major degradation products of MEA and PZ with pure oxygen. In measurements with the high temperature FTIR in 7 m MEA the MEA vapor pressure varied from 2 to 20 Pa at 35 to 70 C. In 2.5 m PZ the PZ vapor pressure varied from 0.2 to 1 Pa from 37 to 70 C.
- Research Organization:
- University of Texas
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FC26-02NT41440
- OSTI ID:
- 876056
- Country of Publication:
- United States
- Language:
- English
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CO2 Capture by Absorption with Potassium Carbonate
CO2 Capture by Absorption with Potassium Carbonate