Surface functionalized mesoporous material and method of making same

Feng, Xiangdong; Liu, Jun; Fryxell, Glen E

Title: Surface functionalized mesoporous material and method of making same

Patent · Tue Dec 04 00:00:00 EST 2001

OSTI ID:874147

Feng, Xiangdong ^[1]; Liu, Jun ^[1]; Fryxell, Glen E ^[2]

West Richland, WA
Kennewick, WA

According to the present invention, an organized assembly of functional molecules with specific interfacial functionality (functional group(s)) is attached to available surfaces including within mesopores of a mesoporous material. The method of the present invention avoids the standard base soak that would digest the walls between the mesopores by boiling the mesoporous material in water for surface preparation then removing all but one or two layers of water molecules on the internal surface of a pore. Suitable functional molecule precursor is then applied to permeate the hydrated pores and the precursor then undergoes condensation to form the functional molecules on the interior surface(s) of the pore(s).

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC06-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: US 6326326

Application Number:: 09/020,028

OSTI ID:: 874147

Country of Publication:: United States

Language:: English

References (32)

Catalytic combustion of natural gas as the role of on-site heat supply in rapid catalytic CO2H2O reforming of methane Inui, T.; Saigo, K.; Fujii, Y. Catalysis Today, Vol. 26, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00151-9	journal	December 1995
MCM-41 type silicas as supports for immobilized catalysts Brunel, Daniel; Cauvel, Anne; Fajula, François Zeolites: A Refined Tool for Designing Catalytic Sites, Proceedings of the International Zeolite Symposium, p. 173-180 https://doi.org/10.1016/S0167-2991(06)81887-2	book	January 1995
Synthesis of zeolites using organosilicon compounds as structure-directing agents Li, Hong-Xin; Camblor, Miguel A.; Davis, M. E. Microporous Materials, Vol. 3, Issue 1-2 https://doi.org/10.1016/0927-6513(94)00013-1	journal	September 1994
Recent advances in the synthesis, characterization and applications of mesoporous molecular sieves Beck, Jeffrey S.; Vartuli, James C. Current Opinion in Solid State and Materials Science, Vol. 1, Issue 1 https://doi.org/10.1016/S1359-0286(96)80014-3	journal	February 1996
Removal of Cadmium, Lead, Mercury, Tin, Antimony, and Arsenic from Drinking and Seawaters by Colloid Precipitate Flotation Ghazy, S. E. Separation Science and Technology, Vol. 30, Issue 6 https://doi.org/10.1080/01496399508015408	journal	April 1995
Removal of mercury vapor from air with sulfur-impregnated adsorbents Otani, Yoshio.; Kanaoka, Chikao.; Emi, Hitoshi. Environmental Science & Technology, Vol. 22, Issue 6 https://doi.org/10.1021/es00171a015	journal	June 1988
Novel compact steam reformer for fuel cells with heat generation by catalytic combustion augmented by induction heating1This CEC Project is funded in the Brite Euram programme under contract no: BRE2-CT94-0588. Partners: Gastec (NL), AEA Technology (UK), EA Technology (UK), Degussa (D), IST (Port.), PowerGen (UK), TGI (Spain), Stork Alpha Engineering (NL).1 Polman, E. A.; Der Kinderen, J. M.; Thuis, F. M. A. Catalysis Today, Vol. 47, Issue 1-4 https://doi.org/10.1016/S0920-5861(98)00316-2	journal	January 1999
Microchannel reactors for fuel processing applications. I. Water gas shift reactor Tonkovich, A. Y.; Zilka, J. L.; LaMont, M. J. Chemical Engineering Science, Vol. 54, Issue 13-14 https://doi.org/10.1016/S0009-2509(98)00346-7	journal	July 1999
Removal of Mercury from Waste Water: Large-Scale Performance of an Ion Exchange Process Ritter, J. A.; Bibler, J. P. Water Science and Technology, Vol. 25, Issue 3 https://doi.org/10.2166/wst.1992.0089	journal	February 1992
Mercury removal from aqueous streams utilizing microemulsion liquid membranes Larson, Karen A.; Wiencek, John M. Environmental Progress, Vol. 13, Issue 4 https://doi.org/10.1002/ep.670130414	journal	November 1994
Removal of gaseous mercury from air using a gold coated denuder Munthe, J.; Schroeder, W. H.; Xiao, Z. Atmospheric Environment. Part A. General Topics, Vol. 24, Issue 8 https://doi.org/10.1016/0960-1686(90)90260-T	journal	January 1990
Synthesis of a novel microporous crystal with organic groups covalently bonded to the skeleton Maeda, Kazuyuki; Kiyozumi, Yoschimichi; Mizukami, Fujio Zeolite Science 1994: Recent Progress and Discussions - Supplementary Materials to the 10th International Zeolite Conference, Garmish-Partenkirchen, Germany, July 17-22, 1994, p. 44-45 https://doi.org/10.1016/S0167-2991(06)81078-5	book	January 1995
1,5,7-Triazabicyclo[4.4.0]dec-5-ene Immobilized in MCM-41: A Strongly Basic Porous Catalyst Rao, Yarlagadda V. Subba; De Vos, Dirk E.; Jacobs, Pierre A. Angewandte Chemie International Edition in English, Vol. 36, Issue 23 https://doi.org/10.1002/anie.199726611	journal	December 1997
Functionalized Monolayers on Ordered Mesoporous Supports Feng, X.; Fryxell, G. E.; Wang, L. -Q. Science, Vol. 276, Issue 5314 https://doi.org/10.1126/science.276.5314.923	journal	May 1997
Metal foam supported perovskite catalysts Podyacheva, O. Yu.; Ketov, A. A.; Ismagilov, Z. R. Reaction Kinetics and Catalysis Letters, Vol. 60, Issue 2 https://doi.org/10.1007/BF02475685	journal	March 1997
Monolithic catalyst supports with foam structure Leonov, A. N.; Smorygo, O. L.; Sheleg, V. K. Reaction Kinetics and Catalysis Letters, Vol. 60, Issue 2 https://doi.org/10.1007/BF02475687	journal	March 1997
Synthesis of hybrid inorganic–organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors Burkett, Sandra L.; Sims, Stephen D.; Mann, Stephen Chem. Commun., Issue 11 https://doi.org/10.1039/CC9960001367	journal	January 1996
Synthesis and Characterization of a Reactive Vinyl-Functionalized MCM-41: Probing the Internal Pore Structure by a Bromination Reaction Lim, Myong H.; Blanford, Christopher F.; Stein, Andreas Journal of the American Chemical Society, Vol. 119, Issue 17 https://doi.org/10.1021/ja9638824	journal	April 1997
Electrokinetic Remediation of Mercury-Contaminated Soils Using Iodine/Iodide Lixiviant Cox, Chris D.; Shoesmith, Matthew A.; Ghosh, Mriganka M. Environmental Science & Technology, Vol. 30, Issue 6 https://doi.org/10.1021/es950633r	journal	January 1996
Aminopropylated MCMs as base catalysts: a comparison with aminopropylated silica Macquarrie, Duncan J.; Jackson, Dominic B. Chemical Communications, Issue 18 https://doi.org/10.1039/a704156j	journal	January 1997
Development and study of metal foam heat-exchanging tubular reactor: Catalytic combustion of methane combined with methane steam reforming Ismagilov, Z. R.; Podyacheva, O. Yu.; Pushkarev, V. V. Studies in Surface Science and Catalysis https://doi.org/10.1016/S0167-2991(00)80888-5	book	January 2000
Synthesis of Ordered Microporous Silicates with Organosulfur Surface Groups and Their Applications as Solid Acid Catalysts Lim, Myong H.; Blanford, Christopher F.; Stein, Andreas Chemistry of Materials, Vol. 10, Issue 2 https://doi.org/10.1021/cm970713p	journal	February 1998
A Novel Fixed Bed Catalyst for the Direct Combination of H2 and O2 to H2O2 Kosak, John R.; Scaros, Mike G.; Prunier, Michael L. Catalysis of Organic Reactions https://doi.org/10.1201/9781315138855-11	book	January 1995
Synthesis and characterization of ordered organo–silica–surfactant mesophases with functionalized MCM-41-type architecture Fowler, Christabel E.; Burkett, Sandra L.; Mann, Stephen Chemical Communications, Issue 18 https://doi.org/10.1039/a704644h	journal	January 1997
Functionalization of Y zeolites with organosilane reagents Cauvel, A.; Brunel, D.; Di Renzo, F. Catalysis by Microporous Materials, Proceedings of ZEOCAT '95, p. 286-293 https://doi.org/10.1016/S0167-2991(06)81234-6	book	January 1995
Surface Absorption of Monolayers Ulman, Abraham MRS Bulletin, Vol. 20, Issue 6, p. 46-51 https://doi.org/10.1557/S0883769400036976	journal	June 1995
Synthesis of the First Microporous Aluminum Phosphonate with Organic Groups Covalently Bonded to the Skeleton Maeda, Kazuyuki; Kiyozumi, Yoshimichi; Mizukami, Fujio Angewandte Chemie International Edition in English, Vol. 33, Issue 22, p. 2335-2337 https://doi.org/10.1002/anie.199423351	journal	December 1994
Hybrid Mesoporous Materials with Functionalized Monolayers Liu, Jun; Feng, Xiangdong; Fryxell, Glen E. Advanced Materials, Vol. 10, Issue 2, p. 161-165 https://doi.org/10.1002/(SICI)1521-4095(199801)10:2<161::AID-ADMA161>3.0.CO;2-Q	journal	January 1998
Synthesis and Application of New Phenyl-Functionalized Zeolites as Protection Against Radical Bromination at the Benzylic Position Itoh, Akichika; Masaki, Yukio Synlett, Vol. 12, Issue 12 https://doi.org/10.1055/s-1997-1070	journal	December 1997
Nucleophilic Displacements in Mixed Self-Assembled Monolayers ^† Fryxell, Glen E.; Rieke, Peter C.; Wood, Laurie L. Langmuir, Vol. 12, Issue 21 https://doi.org/10.1021/la9506842	journal	January 1996
Metal-form catalysts with supported active phase for deep oxidation of hydrocarbons Pestryakov, A. N.; Fyodorov, A. A.; Gaisinovich, M. S. Reaction Kinetics & Catalysis Letters, Vol. 54, Issue 1 https://doi.org/10.1007/BF02071195	journal	January 1995
On the reported attempts to radically improve the performance of the steam methane reforming reactor Adris, A. M.; Pruden, B. B.; Lim, C. J. The Canadian Journal of Chemical Engineering, Vol. 74, Issue 2 https://doi.org/10.1002/cjce.5450740202	journal	April 1996

Similar Records

Surface Functionalized Mesoporous Material and Method of Making Same

Patent · Fri Feb 06 00:00:00 EST 1998 · OSTI ID:874147

Feng, Xiangdong; Liu, Jun; Fryxell, Glen E

Supported mesoporous carbon ultrafiltration membrane and process for making the same

Patent · Tue Apr 13 00:00:00 EDT 2004 · OSTI ID:874147

Strano, Michael; Foley, Henry C.; Agarwal, Hans

Making nanostructured pyrotechnics in a beaker

Conference · Mon Apr 10 00:00:00 EDT 2000 · OSTI ID:874147

Gash, A E; Simpson, R L; Tillotson, T M; +2 more

Related Subjects

surface
functionalized
mesoporous
material
method
organized
assembly
functional
molecules
specific
interfacial
functionality
attached
available
surfaces
including
mesopores
avoids
standard
base
soak
digest
walls
boiling
water
preparation
removing
layers
internal
pore
molecule
precursor
applied
permeate
hydrated
pores
undergoes
condensation
form
interior
interior surface
porous material
surface functional
/502/423/

Title: Surface functionalized mesoporous material and method of making same

Citation Formats

References (32)

Similar Records

Related Subjects