Synthesis of perhydroxydodecaborate salts and related species

Patent · Mon Jan 01 00:00:00 EST 2001

OSTI ID:874138

Hawthorne, M Frederick ^[1]; Peymann, Toralf ^[2]; Herzog, Axel Hans-Joachim ^[2]

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1. Encino, CA
2. Los Angeles, CA

New icosahedral borohydrates Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ]; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by refluxing the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with a hydroxylating agent, preferably 30%.sub.w hydrogen peroxide.

• Research Organization: Univ. of California (United States)
• DOE Contract Number: FG03-95ER61975
• Assignee: The Regents of the University of California (Oakland, CA)
• Patent Number(s): US 6323372
• OSTI ID: 874138
• Country of Publication: United States
• Language: English

Related Subjects

synthesis
perhydroxydodecaborate
salts
related
species
icosahedral
borohydrates
cssub2
closo-bsub12
ohsub12
cscloso-1-h-1-cbsub11
ohsub11
closo-112-hsub2
-112-csub2
bsub10
ohsub10
disclosed
set
forth
preparation
refluxing
boranes
hsub12
sup2-
closo-1-cbsub11
sup-
closo-112-chsub2
ohsub2
hsub10
hydroxylating
agent
30subw
hydrogen
peroxide
set forth
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