Morphology in electrochemically grown conducting polymer films
Abstract
A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventioonally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol.
- Inventors:
-
- Rishon-Letzion, IL
- Los Alamos, NM
- Rehovot, IL
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- OSTI Identifier:
- 868259
- Patent Number(s):
- US 5108573
- Assignee:
- United States of America as represented by United States (Washington, DC)
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- morphology; electrochemically; grown; conducting; polymer; films; film; improved; space; filling; formed; metal; electrode; surface; self-assembling; monolayer; directly; functional; binds; chemical; forms; bonding; site; molecules; forming; conventioonally; deposited; electrochemical; deposition; example; polyaniline; gold; intermediate; p-aminothiophenol; chemical bond; chemical deposition; polymer films; formed directly; polymer film; metal electrode; metal surface; electrode surface; conducting polymer; chemical bonding; conducting film; /204/205/429/
Citation Formats
Rubinstein, Israel, Gottesfeld, Shimshon, and Sabatani, Eyal. Morphology in electrochemically grown conducting polymer films. United States: N. p., 1992.
Web.
Rubinstein, Israel, Gottesfeld, Shimshon, & Sabatani, Eyal. Morphology in electrochemically grown conducting polymer films. United States.
Rubinstein, Israel, Gottesfeld, Shimshon, and Sabatani, Eyal. 1992.
"Morphology in electrochemically grown conducting polymer films". United States. https://www.osti.gov/servlets/purl/868259.
@article{osti_868259,
title = {Morphology in electrochemically grown conducting polymer films},
author = {Rubinstein, Israel and Gottesfeld, Shimshon and Sabatani, Eyal},
abstractNote = {A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventioonally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol.},
doi = {},
url = {https://www.osti.gov/biblio/868259},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 1992},
month = {Wed Jan 01 00:00:00 EST 1992}
}
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Works referenced in this record:
Organized self-assembling monolayers on electrodes. 2. Monolayer-based ultramicroelectrodes for the study of very rapid electrode kinetics
journal, December 1987
- Sabatani, Eyal.; Rubinstein, Israel.
- The Journal of Physical Chemistry, Vol. 91, Issue 27
Organized self-assembling monolayers on electrodes
journal, March 1987
- Sabatani, E.; Rubinstein, Israel; Maoz, Rivak
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 219, Issue 1-2