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Title: STRONTIUM & TRANSURANIC (TRU) SEPARATION PROCESS IN THE DOUBLE SHELL TANK (DST) SYSTEM

Technical Report ·
DOI:https://doi.org/10.2172/841017· OSTI ID:841017

The supernatants stored in tanks 241-AN-102 (AN-102) and 241-AN-107 (AN-107) contain soluble strontium-90 ({sup 90}Sr) and transuranic (TRU) elements that require removal prior to vitrification to comply with the Waste Treatment and Immobilization Plant (WTP) immobilized low-activity waste (ILAW) specification and with the 1997 agreement with the Nuclear Regulatory Commission on incidental waste. A precipitation process has been developed and tested with tank waste samples and simulants using strontium nitrate (Sr(NO{sub 3}){sub 2}) and sodium permanganate (NaMnO{sub 4}) to separate {sup 90}Sr and TRU from these wastes. This report evaluates removing Sr/TRU from AN-102 and AN-107 supernates in the DST system before delivery to the WTP. The in-tank precipitation is a direct alternative to the baseline WTP process, using the same chemical separations. Implementing the Sr/TRU separation in the DST system beginning in 2012 provides {approx}6 month schedule advantage to the overall mission, without impacting the mission end date or planned SST retrievals.

Research Organization:
CH2M Hill Hanford Group, Inc., Richland, WA (United States)
Sponsoring Organization:
ENVIRONMENTAL MANAGEMENT (US)
DOE Contract Number:
AC27-99RL14047
OSTI ID:
841017
Report Number(s):
RPP-24809, Rev.0; TRN: US0502443
Resource Relation:
Other Information: PBD: 10 Jun 2005
Country of Publication:
United States
Language:
English