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Title: New Silicotitanate Waste Forms; Development and Characterization

Technical Report ·
DOI:https://doi.org/10.2172/829961· OSTI ID:829961

The objective of this program is to identify new waste forms and disposal strategies specific to crystalline silicotitanate (CST) secondary waste that is generated from cesium and strontium ion exchange processes. Waste forms that are developed in this work will offer an alternative to current disposal plans. The goals of the program are to reduce the costs associated with CST waste disposal, minimize the risk of contamination to the environment during CST processing, and provide DOE with technical alternatives for CST disposal. The technical objectives of the proposed work are to (1) fully characterize the phase relationships, structures, and thermodynamic and kinetic stabilities of crystalline silicotitanate waste forms and (2) establish a sound technical basis for understanding key waste form properties, such as melting temperatures and aqueous durability, based on an in-depth understanding of waste form structures and thermochemistry.

Research Organization:
Pacific Northwest National Lab., Richland, WA; Sandia National Labs., Albuquerque, NM; University of California-Davis, Davis, CA (US)
Sponsoring Organization:
USDOE Office of Environmental Management (EM) (US)
DOE Contract Number:
FG07-97ER45674
OSTI ID:
829961
Report Number(s):
EMSP-60345-2000; R&D Project: EMSP 60345; TRN: US0404819
Resource Relation:
Other Information: PBD: 1 Jun 2000
Country of Publication:
United States
Language:
English