POLYOXOMETALATES FOR RADIOACTIVE WASTE TREATMENT
The research project has two major goals: (1) the selective sequestration of lanthanide (Ln) and actinide (An) cations, and technetium species, from tank waste solutions, using radiation-resistant and thermally-stable polyoxometalate anions as complexants, and (2) the conversion of complexed Ln/An/Tc to reduced oxide bronzes (e.g. MxWO3) under relatively mild conditions, and evaluation of the use of such bronzes as waste forms.
- Research Organization:
- Georgetown University, Washington, DC (US)
- Sponsoring Organization:
- USDOE Office of Environmental Management (EM) (US)
- DOE Contract Number:
- FG07-96ER14695
- OSTI ID:
- 827110
- Report Number(s):
- EMSP-54716-2000; R&D Project: EMSP 54716; TRN: US0403187
- Resource Relation:
- Other Information: PBD: 1 Jun 2000
- Country of Publication:
- United States
- Language:
- English
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