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Title: Analysis of organic carbon and moisture in Hanford single-shell tank waste

Technical Report ·
DOI:https://doi.org/10.2172/80983· OSTI ID:80983

This report documents a revised analysis performed by Pacific Northwest Laboratory involving the organic carbon laboratory measurement data for Hanford single-shell tanks (SSTs) obtained from a review of the laboratory analytical data. This activity has as its objective to provide a best-estimate, including confidence levels, of total organic carbon (TOC) and moisture in each of the 149 SSTs at Hanford. The TOC and moisture information presented in this report is useful as part of the criteria to identify SSTs for additional measurements, or monitoring for the Organic Safety Program. In April 1994, an initial study of the organic carbon in Hanford single-shell tanks was completed at PNL. That study reflected the estimates of TOC based on tank characterizations datasets that were available at the time. Also in that study, estimation of dry basis TOC was based on generalized assumptions pertaining to the moisture of the tank wastes. The new information pertaining to tank moisture and TOC data that has become available from the current study influences the best estimates of TOC in each of the SSTs. This investigation of tank TOC and moisture has resulted in improved estimates based on waste phase: saltcake, sludge, or liquid. This report details the assumptions and methodologies used to develop the estimates of TOC and moisture in each of the 149 SSTs at Hanford.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
80983
Report Number(s):
PNL-10360; ON: DE95014506; TRN: 95:016530
Resource Relation:
Other Information: PBD: May 1995
Country of Publication:
United States
Language:
English