One-dimensional magnetic variety in a family of TTF-bis-dithiolene metal complex compounds. [TTF. MS/sub 4/C/sub 4/ (CF/sub 3/)/sub 4/ (M = Cu, Au, Pt, Ni)]
Conference
·
OSTI ID:7263792
The donor-acceptor compounds TTF.MS/sub 4/C/sub 4/(CF/sub 3/)/sub 4/, where TTF = tetrathiafulvalene and M = Cu, Au, Pt, Ni, are mixed-stack quasi-one-dimensional magnetic insulators of remarkable variety. For M = Cu, Au, a novel progressive spin-lattice dimerization occurs (spin-Peierls transition). For M = Pt, Ni, ferro/ferrimagnetic chains develop with moderate/weak antiferromagnetic coupling.
- Research Organization:
- Brookhaven National Lab., Upton, N.Y. (USA); General Electric Co., Schenectady, N.Y. (USA); Lehigh Univ., Bethlehem, Pa. (USA); Yale Univ., New Haven, Conn. (USA)
- DOE Contract Number:
- E(30-1)-16
- OSTI ID:
- 7263792
- Report Number(s):
- BNL-21675; CONF-760922-8
- Resource Relation:
- Conference: International conference on magnetism, Amsterdam, Netherlands, 6 Sep 1976
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:7263792
Magnetic field effects on (TTF)CuS/sub 4/C/sub 4/(CF/sub 3/)/sub 4/, a spin-Peierls system
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COPPER COMPLEXES
MAGNETIC SUSCEPTIBILITY
GOLD COMPLEXES
NICKEL COMPLEXES
ORGANIC SULFUR COMPOUNDS
PLATINUM COMPLEXES
TEMPERATURE DEPENDENCE
COMPLEXES
MAGNETIC PROPERTIES
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
COPPER COMPLEXES
MAGNETIC SUSCEPTIBILITY
GOLD COMPLEXES
NICKEL COMPLEXES
ORGANIC SULFUR COMPOUNDS
PLATINUM COMPLEXES
TEMPERATURE DEPENDENCE
COMPLEXES
MAGNETIC PROPERTIES
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties