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Title: Preliminary flow sheet and process design for ZnSe thermochemical cycle

Technical Report ·
DOI:https://doi.org/10.2172/7181049· OSTI ID:7181049

A preliminary design of the ZnSe cycle for thermochemical hydrogen production has been prepared for use in deriving economic costs for hydrogen production. The process flowsheet identifies key equipment items as well as major streams. Flow and heat loads have been estimated based on one mole of hydrogen output. The thermal efficiency of this cycle depends on two factors: (1) the ability to perform the dissolution of ZnSO/sub 4/ and the hydrolysis of ZnSe with a minimum amount of aqueous HCl, and (2) the ability to match the process heat requirements with available heat from the exothermic steps in the cycle. Estimates of the cycle's thermal efficiency range from 34--57 percent depending upon the process heat utilization.

Research Organization:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
7181049
Report Number(s):
UCID-17172
Country of Publication:
United States
Language:
English