[Laser flash photolysis, EPR and Raman studies of liquids at elevated pressures]

Technical Report · Wed Jan 01 00:00:00 EST 1992

DOI:https://doi.org/10.2172/7180124· OSTI ID:7180124

Eyring, E M

The proposed research will solve a number of analytical chemical problems in solutions with measurement techniques that benefit from the use of elevated hydrostatic pressures: stopped-flow spectrophotometry (Gd[sup 3+] + L(ligand), [RuL[sub 5]H[sub 2]O][sup 2+], laser flash photolysis of Mo(CO)[sub 6] + L, flash photolysis of binuclear metalloproteins), EPR spectroscopy (Gd[sup 3+] ion-exchanged into ETS-10 and ETAS-10 molecular sieves), laser flash photolysis kinetic studies of Mo(CO)[sub 6]-2,2'-bipyridine, and electrochemical studies of metalloporphyrins using resonance Raman spectroscopy.

• Research Organization: Utah Univ., Salt Lake City, UT (United States). Dept. of Chemistry
• Sponsoring Organization: USDOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG02-84ER13227
• OSTI ID: 7180124
• Report Number(s): DOE/ER/13227-T5; ON: DE93001788
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PHOTOLYSIS
EXPERIMENT PLANNING
SOLUTIONS
BIPYRIDINES
CARBONYLS
ELECTRON SPIN RESONANCE
GADOLINIUM IONS
LIGANDS
MOLECULAR SIEVES
MOLYBDENUM COMPLEXES
PORPHYRINS
PROGRESS REPORT
PULSED IRRADIATION
RAMAN SPECTROSCOPY
ADSORBENTS
AZINES
CARBOXYLIC ACIDS
CHARGED PARTICLES
CHEMICAL REACTIONS
COMPLEXES
DECOMPOSITION
DISPERSIONS
DOCUMENT TYPES
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
IONS
IRRADIATION
LASER SPECTROSCOPY
MAGNETIC RESONANCE
MIXTURES
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PLANNING
PYRIDINES
RESONANCE
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400500* - Photochemistry