Interactions between manganese oxides and multiple-ringed aromatic compounds
- Pacific Northwest Lab., Richland, WA (United States)
- Utah State Univ., Logan, UT (United States). Dept. of Civil and Environmental Engineering
Objective is to determine whether Mn reductive dissolution can oxidize multiple-ringed aromatics, such as PAHs, in an oxic environment Research indicated that certain PAHs (eg, dihydrodiols and diones that form free-radical intermediates) are susceptible to oxidation and polymerization. Over 14 days, 83, 76, 54, 70, and 20% of the Mn was reduced by 2,3-, 1,3-, and 1,4-naphthalenediol, quinizarin, and 1,4-naphthoquinone, respectively. 100, 100, and 65% of the first three PAHs were oxidized, respectively. Aromatics with diol functional groups were more easily oxidized than those with only dione groups. Relatively insoluble compounds like quinizarin can be oxidized; insoluble ''humic-like'' material precipitated, indicating a polymerization-humification process. Results suggest that electron transfer/organic release from the oxide surface is the rate-limiting step.
- Research Organization:
- Pacific Northwest Lab., Richland, WA (United States)
- Sponsoring Organization:
- USDOE; USGS; USDOE, Washington, DC (United States); Geological Survey, Reston, VA (United States)
- DOE Contract Number:
- AC06-76RL01830
- OSTI ID:
- 7037323
- Report Number(s):
- PNL-SA-21261; CONF-9208152-1; ON: DE92041342; CNN: 14-08-0001-G1723
- Resource Relation:
- Conference: ISSS working group meeting, Edmonton (Canada), 10-16 Aug 1992
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
MANGANESE OXIDES
REDUCTION
POLYCYCLIC AROMATIC HYDROCARBONS
OXIDATION
CHEMICAL REACTION KINETICS
DISSOLUTION
ELECTRON TRANSFER
PH VALUE
POLYMERIZATION
PRECIPITATION
WASTE PROCESSING
AROMATICS
CHALCOGENIDES
CHEMICAL REACTIONS
HYDROCARBONS
KINETICS
MANAGEMENT
MANGANESE COMPOUNDS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PROCESSING
REACTION KINETICS
SEPARATION PROCESSES
TRANSITION ELEMENT COMPOUNDS
WASTE MANAGEMENT
400201* - Chemical & Physicochemical Properties
320305 - Energy Conservation
Consumption
& Utilization- Industrial & Agricultural Processes- Industrial Waste Management