Direct fabrication of /sup 238/PuO/sub 2/ fuel forms

Technical Report · Thu Jul 01 00:00:00 EDT 1982

DOI:https://doi.org/10.2172/6743143· OSTI ID:6743143

Burney, G A; Congdon, J W

The current process for the fabrication of /sup 238/PuO/sub 2/ heat sources includes precipitation of small particle plutonium oxalate crystals (4 to 6 ..mu..m diameter), a calcination to PuO/sub 2/, ball milling, cold pressing, granulation (60 to 125 ..mu..m), and granule sintering prior to hot pressing the fuel pellet. A new two-step direct-strike Pu(III) oxalate precipitation method which yields mainly large well-developed rosettes (50 to 100 ..mu..m diameter) has been demonstrated in the laboratory and in the plant. These large rosettes are formed by agglomeration of small (2 to 4 ..mu..m) crystals, and after calcining and sintering, were directly hot pressed into fuel forms, thus eliminating several of the powder conditioning steps. Conditions for direct hot pressing of the large heat-treated rosettes were determined and a full-scale General Purpose Heat Source pellet was fabricated. The pellet had the desired granule-type microstructure to provide dimensional stability at high temperature. 27 figures.

• Research Organization: Du Pont de Nemours (E.I.) and Co., Aiken, SC (United States). Savannah River Lab.
• DOE Contract Number: AC09-76SR00001
• OSTI ID: 6743143
• Report Number(s): DP-1621; ON: DE83001658
• Country of Publication: United States
• Language: English

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FUEL PELLETS
HOT PRESSING
OXALATES
PLUTONIUM 238
PRECIPITATION
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HEAT SOURCES
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OXYGEN COMPOUNDS
PELLETS
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PLUTONIUM ISOTOPES
PLUTONIUM OXIDES
PRESSING
RADIOISOTOPES
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