Development of analytical procedures for coprocessing
Maya crude residue and Illinois No. 6 coal have been processed together over a range of reactant ratios to produce material for study of the product composition and of the coprocessing chemistry. The reaction conditions have been described in previous reports. Acid fractions have been derivatized to produce {sup 13}C tagged products suitable for NMR analysis. The acids have been identified as phenols and other oxygen acids, nitrogen acids including carbazoles, and benzylic and sulfur acids. All of the acid fractions appear to be essentially monofunctional. Base fractions were analyzed by nonaqueous titration and were shown to consist of azaarenes and arylamines. Two of the distillates boiling below 175{degrees}C were analyzed by PIANO capillary gas chromatography. Maya crude petroleum fractions similar to those obtained from coprocessing products have been analyzed for carbon isotope ratios. These fractions were prepared directly from the Maya crude without application of hydrogenation or other processing chemistry. Trends indicating isotopic fractionation coprocessing to that reported earlier for coprocessing products were observed. 14 figs., 13 tabs.
- Research Organization:
- National Energy Technology Lab. (NETL), Bartlesville, OK (United States). National Inst. for Petroleum and Energy Research (NIPER)
- Sponsoring Organization:
- DOE/FE
- DOE Contract Number:
- AC22-88PC88810
- OSTI ID:
- 6580348
- Report Number(s):
- DOE/PC/88810-6; ON: DE91000852
- Country of Publication:
- United States
- Language:
- English
Similar Records
Development of analytical procedures for coprocessing
Development of analytical procedures for coprocessing. Quarterly technical progress report, April 1--June 30, 1990
Related Subjects
02 PETROLEUM
COAL
COPROCESSING
YIELDS
PETROLEUM
CARBAZOLES
CARBON 13
CHEMICAL SHIFT
DERIVATIZATION
DISTILLATES
ISOTOPE RATIO
NUCLEAR MAGNETIC RESONANCE
ORGANIC ACIDS
PHENOLS
PROGRESS REPORT
AROMATICS
AZAARENES
AZOLES
CARBON ISOTOPES
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
DOCUMENT TYPES
ENERGY SOURCES
EVEN-ODD NUCLEI
FOSSIL FUELS
FUELS
HETEROCYCLIC COMPOUNDS
HYDROXY COMPOUNDS
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
MATERIALS
NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROCESSING
RESONANCE
STABLE ISOTOPES
010405* - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
020400 - Petroleum- Processing
010600 - Coal
Lignite
& Peat- Properties & Composition
023000 - Petroleum- Properties & Composition