Potential agents for removal of actinides from waste solutions
Abstract
The uptake of Th(IV) from nitric acid and hydrochloric acid solutions by chelating ion exchange resins containing catechol, 1,2- hydroxypyridinone (1,2-HOPO) and 3,4-hydroxypyridinone (3,4-HOPO) functional groups, has been investigated. These polystyrene based materials show excellent kinetics for uptake of Th(IV) and have a high loading capacity. Liquid/liquid extractants have also been synthesized by addition of lipophilic side chains to the chelating groups (1,2-HOPO; 3,4-HOPO; 3,2-HOPO; catecholamide; terephthalamide). The initial evaluation of the extraction properties has been carried out.
- Authors:
- Publication Date:
- Research Org.:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 611768
- Report Number(s):
- UCRL-JC-125728; CONF-960804-
ON: DE98051116; TRN: 98:005474
- DOE Contract Number:
- W-7405-ENG-48
- Resource Type:
- Conference
- Resource Relation:
- Conference: SPECTRUM `96: international conference on nuclear and hazardous waste management, Seattle, WA (United States), 18-23 Aug 1996; Other Information: PBD: 1 Jul 1996
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 05 NUCLEAR FUELS; 40 CHEMISTRY; THORIUM; POLYSTYRENE; PYROCATECHOL; RADIOACTIVE WASTE DISPOSAL; ACTINIDES; REMOVAL; ION EXCHANGE; CHELATING AGENTS; CHELATES
Citation Formats
Romanovski, V V, Whisenhunt, D W, Veeck, A C, Andersen, W A, Hoffman, D C, Jide, X, White, D, and Raymond, K N. Potential agents for removal of actinides from waste solutions. United States: N. p., 1996.
Web.
Romanovski, V V, Whisenhunt, D W, Veeck, A C, Andersen, W A, Hoffman, D C, Jide, X, White, D, & Raymond, K N. Potential agents for removal of actinides from waste solutions. United States.
Romanovski, V V, Whisenhunt, D W, Veeck, A C, Andersen, W A, Hoffman, D C, Jide, X, White, D, and Raymond, K N. 1996.
"Potential agents for removal of actinides from waste solutions". United States. https://www.osti.gov/servlets/purl/611768.
@article{osti_611768,
title = {Potential agents for removal of actinides from waste solutions},
author = {Romanovski, V V and Whisenhunt, D W and Veeck, A C and Andersen, W A and Hoffman, D C and Jide, X and White, D and Raymond, K N},
abstractNote = {The uptake of Th(IV) from nitric acid and hydrochloric acid solutions by chelating ion exchange resins containing catechol, 1,2- hydroxypyridinone (1,2-HOPO) and 3,4-hydroxypyridinone (3,4-HOPO) functional groups, has been investigated. These polystyrene based materials show excellent kinetics for uptake of Th(IV) and have a high loading capacity. Liquid/liquid extractants have also been synthesized by addition of lipophilic side chains to the chelating groups (1,2-HOPO; 3,4-HOPO; 3,2-HOPO; catecholamide; terephthalamide). The initial evaluation of the extraction properties has been carried out.},
doi = {},
url = {https://www.osti.gov/biblio/611768},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jul 01 00:00:00 EDT 1996},
month = {Mon Jul 01 00:00:00 EDT 1996}
}
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