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Title: Hydrothermal interaction of solid wafers of Topopah Spring Tuff with J-13 water at 90 and 150{degree}C using Dickson-type, gold-bag rocking autoclaves: Long-term experiments

Technical Report ·
DOI:https://doi.org/10.2172/60462· OSTI ID:60462

The Nevada Nuclear Waste Storage Investigations Project conducted long-term experiments to study the hydrothermal interaction of rock and water representative of a potential high-level waste repository at Yucca Mountain, Nevada. The results of these experiments complement those obtained previously in short-term experiments at similar and higher temperatures. These long-term experiments also help in assessing the effects of kinetic inhibition in the precipitation of secondary minerals at the lower temperatures and allow a more complete determination of the approach of the fluid toward a steady-state composition. Considered collectively, the results of both short- and long-term experiments provide information useful in defining the near-field repository environment during and shortly after the thermal period caused by the emplacement of nuclear waste. These long-term experiments were conducted using solid wafers cut from drillcore samples of Topopah Spring tuff. A natural ground water was used as the reacting fluid. Analytical techniques for determining the composition of fluids and solids were similar to those used in previous short-term experiments. All experiments were run in Dickson-type, gold-bag rocking autoclaves that were periodically sampled under in situ conditions. Two long-term (304-day) experiments were run at temperatures of 90 and 150{degree}C and 50-bar pressure. 21 refs., 8 figs., 5 tabs.

Research Organization:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
60462
Report Number(s):
UCRL-53722; ON: DE88005709
Resource Relation:
Other Information: PBD: May 1987
Country of Publication:
United States
Language:
English