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Title: Phosphorous adsorption and precipitation in a permeable reactive wall: Applications for wastewater disposal systems

Conference ·
OSTI ID:576633
 [1];  [1];  [2]
  1. Univ. of Waterloo, Ontario (Canada)
  2. National Water Research Institute, Burlington, Ontario (Canada)

A permeable reactive mixture has been developed using low cost, readily available materials that is capable of providing effective, long-term phosphorous treatment in areas impacted by on-land wastewater disposal. The reactive mixture creates a geochemical environment suitable for P-attenuation by both adsorption and precipitation reactions. Potential benefits include significant reductions in phosphorous loading to receiving groundwater and surface water systems, and the accumulation of P-mass in a finite and accessible volume of material. The mixture may be applied as a component within surface treatment systems or in subsurface applications such as horizontal or vertical permeable reactive walls. The mixture averaged > 90% treatment efficiency over 3.6 years of continuous-flow laboratory column experiments. The mixture was further evaluated at the pilot-scale to treat municipal wastewater, and the field-scale to treat a well-characterized septic system plume using an in situ funnel and gate system. Average PO{sub 4}-P concentrations in effluent exiting the reactive mixture range between 0 - 0.3 mg/L. Mineralogical analyses have isolated the phases responsible for phosphorous uptake, and discrete phosphate precipitates have been identified.

Research Organization:
US Department of Energy (USDOE), Washington DC (United States)
OSTI ID:
576633
Report Number(s):
CONF-970208-Proc.; ON: DE98001967; TRN: 98:005205
Resource Relation:
Conference: International containment technology conference and exhibition, St. Petersburg, FL (United States), 9-12 Feb 1997; Other Information: PBD: [1997]; Related Information: Is Part Of International Containment Technology Conference: Proceedings; PB: 1140 p.
Country of Publication:
United States
Language:
English