Adsorption-controlled growth of ferroelectric PbTiO{sub 3} and Bi{sub 4}Ti{sub 3}O{sub 12} films for nonvolatile memory applications by MBE

Conference · Mon Sep 01 00:00:00 EDT 1997

OSTI ID:541895

Theis, C D; Yeh, J; Schlom, D G ^[1]; Hawley, M E; Brown, G W ^[2]

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1. Pennsylvania State Univ., University Park, PA (United States). Dept. of Materials Science and Engineering
2. Los Alamos National Lab., NM (United States). Center for Materials Science

Epitaxial PbTiO{sub 3} and Bi{sub 4}Ti{sub 3}O{sub 12} thin films have been grown on (100) SrTiO{sub 3} and (100) LaAlO{sub 3} substrates by reactive molecular beam epitaxy (MBE). Titanium is supplied to the film in the form of shuttered bursts each containing a one monolayer dose of titanium atoms for the growth of PbTiO{sub 3} and three monolayers for the growth of Bi{sub 4}Ti{sub 3}O{sub 12}. Lead, bismuth, and ozone are continuously supplied to the surface of the depositing film. Growth of phase pure, c-axis oriented epitaxial films with bulk lattice constants is achieved using an overpressure of these volatile species. With the proper choice of substrate temperature (600--650 C) and ozone background pressure (P{sub O{sub 3}} = 2 {times} 10{sup {minus}5} Torr), the excess of the volatile metals and ozone desorb from the surface of the depositing film leaving a phase-pure stoichiometric crystal. The smooth PbTiO{sub 3} surface morphology revealed by atomic force microscopy (AFM) suggests that the PbTiO{sub 3} films grow in a layer-by-layer fashion. In contrast the Bi{sub 4}Ti{sub 3}O{sub 12} films contain islands which evolve either continuously or around screw dislocations via a spiral-type growth mechanism.

• Research Organization: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
• Sponsoring Organization: USDOE Assistant Secretary for Human Resources and Administration, Washington, DC (United States); Office of Naval Research, Washington, DC (United States)
• DOE Contract Number: W-7405-ENG-36
• OSTI ID: 541895
• Report Number(s): LA-UR-97-2076; CONF-970302-; ON: DE97008979; CNN: Grant N00014-94-1-0690; TRN: AHC29723%%114
• Resource Relation: Conference: Spring meeting of the Materials Research Society, San Francisco, CA (United States), 31 Mar - 4 Apr 1997; Other Information: PBD: [1997]
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
LEAD COMPOUNDS
TITANATES
BISMUTH COMPOUNDS
CRYSTAL GROWTH
FERROELECTRIC MATERIALS
STRONTIUM COMPOUNDS
MOLECULAR BEAM EPITAXY
CRYSTAL STRUCTURE
MEMORY DEVICES