Some thoughts on the organic structure of bituminous coal
Abstract
Our current operating hypothesis is that coal consists of a cross linked macromolecular network of high aromatic clusters held together by linkages which include ethers and methylene groups. These clusters are arranged like beads on a string with 3 to 5 beads between branch points. Coal can be liqufied most readily by cleaving the links between the clusters. Doing chemistry on the clusters in the whole coal is very difficult because of the problems of getting to the clusters by reagents. It is fortunate that the linkages between clusters are quite reactive. But even with this, it is clear that coal liquefaction is a formidable chemical problem. There is much wisdom is Sternberg's suggestion that the chemistry of the freed clusters (pre-asphaltenes) be developed. Our model indicates that the chemistry which results in freeing the clusters from the network also should be explored and broadened.
- Authors:
- Publication Date:
- Research Org.:
- Oak Ridge National Lab., Tenn. (USA)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 5255629
- Report Number(s):
- CONF-780319-1
- DOE Contract Number:
- W-7405-ENG-26
- Resource Type:
- Conference
- Resource Relation:
- Conference: Coal chemistry workshop, Menlo Park, CA, USA, 8 Mar 1978
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 01 COAL, LIGNITE, AND PEAT; BITUMINOUS COAL; STRUCTURAL CHEMICAL ANALYSIS; STRUCTURAL MODELS; ALKYLATION; OXIDATION; STRAINS; STRESSES; BLACK COAL; CARBONACEOUS MATERIALS; CHEMICAL REACTIONS; COAL; ENERGY SOURCES; FOSSIL FUELS; FUELS; 010600* - Coal, Lignite, & Peat- Properties & Composition
Citation Formats
Larsen, J. W. Some thoughts on the organic structure of bituminous coal. United States: N. p., 1978.
Web.
Larsen, J. W. Some thoughts on the organic structure of bituminous coal. United States.
Larsen, J. W. 1978.
"Some thoughts on the organic structure of bituminous coal". United States. https://www.osti.gov/servlets/purl/5255629.
@article{osti_5255629,
title = {Some thoughts on the organic structure of bituminous coal},
author = {Larsen, J. W.},
abstractNote = {Our current operating hypothesis is that coal consists of a cross linked macromolecular network of high aromatic clusters held together by linkages which include ethers and methylene groups. These clusters are arranged like beads on a string with 3 to 5 beads between branch points. Coal can be liqufied most readily by cleaving the links between the clusters. Doing chemistry on the clusters in the whole coal is very difficult because of the problems of getting to the clusters by reagents. It is fortunate that the linkages between clusters are quite reactive. But even with this, it is clear that coal liquefaction is a formidable chemical problem. There is much wisdom is Sternberg's suggestion that the chemistry of the freed clusters (pre-asphaltenes) be developed. Our model indicates that the chemistry which results in freeing the clusters from the network also should be explored and broadened.},
doi = {},
url = {https://www.osti.gov/biblio/5255629},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1978},
month = {Sun Jan 01 00:00:00 EST 1978}
}