Ligand substitution reaction of platinum (II) complexes. Chloro (diethylenetriamine) platinum (II)-chloride exchange
- Iowa State Univ., Ames, IA (United States)
Kinetics of the isotopic exchange of chloride in cholro-(diethylenetriamine)platinum(II) chloride has been studied using chlorine-36 as the tracer, employing an ion exchange quenching technique and activity determination by a liquid scintillation system. The aquation equilibrium constant was determined by means of titrations of the acidic proton on the H2O ligand formed according to the reaction: [Pt(dien)Cl+] + H2O = [Pt(dien)H2O2+] + Cl-; Keq (author).
- Research Organization:
- Ames Lab., Ames, IA (United States)
- Sponsoring Organization:
- US Atomic Energy Commission (AEC)
- DOE Contract Number:
- W-7405-ENG-82
- NSA Number:
- NSA-25-020975
- OSTI ID:
- 4031228
- Report Number(s):
- IS-T-403
- Resource Relation:
- Other Information: Thesis. UNCL. Orig. Receipt Date: 31-DEC-71
- Country of Publication:
- United States
- Language:
- English
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