Separation of radium and actinium using zirconia

Brown, M. Alex

doi:10.1016/j.apradiso.2022.110238

Title: Separation of radium and actinium using zirconia

Journal Article · Mon Apr 11 00:00:00 EDT 2022 · Applied Radiation and Isotopes

DOI:https://doi.org/10.1016/j.apradiso.2022.110238· OSTI ID:1915449

Brown, M. Alex ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Herein, zirconia was investigated as a radiation-resistant support for radium and actinium aqueous ion separations. Acetate and total metal ion concentrations were experimentally evaluated as factors that could affect retention using La and Ba surrogates. Pseudo-second order rate constants were derived and the uptake of La was determined to be endothermic. Elution profiles containing Ba, La, ²²⁸Ra, ²²⁸Ac, and ²¹²Pb are presented and discussed.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1915449

Journal Information:: Applied Radiation and Isotopes, Vol. 185; ISSN 0969-8043

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (18)

Radiochemical aspects of alpha emitting radionuclides for medical application Ferrier, Maryline G.; Radchenko, Valery; Wilbur, D. Scott Radiochimica Acta, Vol. 107, Issue 9-11 https://doi.org/10.1515/ract-2019-0005	journal	September 2019
Selectivity of Th(IV) adsorption as compared to U(VI), La(III), Ce(III), Sm(III) and Gd(III) using mesoporous Al₂O₃ Karmakar, Rajib; Singh, Pritam; Sen, Kamalika Separation Science and Technology, Vol. 56, Issue 14 https://doi.org/10.1080/01496395.2020.1828461	journal	October 2020
Cyclotron production of 225Ac from an electroplated 226Ra target Nagatsu, Kotaro; Suzuki, Hisashi; Fukada, Masami European Journal of Nuclear Medicine and Molecular Imaging, Vol. 49, Issue 1 https://doi.org/10.1007/s00259-021-05460-7	journal	July 2021
Separation of Radium and Barium by Ion Exchange Elution Power, W. H.; Kirby, H. W.; McCluggage, W. C. Analytical Chemistry, Vol. 31, Issue 6 https://doi.org/10.1021/ac60150a002	journal	June 1959
Radioimmunotherapy of Infectious Diseases Dadachova, Ekaterina; Casadevall, Arturo Seminars in Nuclear Medicine, Vol. 39, Issue 2 https://doi.org/10.1053/j.semnuclmed.2008.10.007	journal	March 2009
Production and Supply of α-Particle–Emitting Radionuclides for Targeted α-Therapy Radchenko, Valery; Morgenstern, Alfred; Jalilian, Amir R. Journal of Nuclear Medicine, Vol. 62, Issue 11 https://doi.org/10.2967/jnumed.120.261016	journal	July 2021
Comparison of the solution chemistry of the actinides and lanthanides Choppin, Gregory R. Journal of the Less Common Metals, Vol. 93, Issue 2 https://doi.org/10.1016/0022-5088(83)90177-7	journal	September 1983
Chemistry of zirconia and its use in chromatography Nawrocki, J.; Rigney, M.; McCormick, A. Journal of Chromatography A, Vol. 657, Issue 2 https://doi.org/10.1016/0021-9673(93)80284-F	journal	December 1993
Production of actinium-225 for alpha particle mediated radioimmunotherapy Boll, Rose A.; Malkemus, Dairin; Mirzadeh, Saed Applied Radiation and Isotopes, Vol. 62, Issue 5 https://doi.org/10.1016/j.apradiso.2004.12.003	journal	May 2005
Optimizations of Radiolabeling of Immunoproteins with 213Bi Boll, Rose A.; Mirzadeh, Saed; Kennel, Stephen J. Radiochimica Acta, Vol. 79, Issue 2 https://doi.org/10.1524/ract.1997.79.2.145	journal	January 1997
Adsorption of thorium from aqueous solutions by perlite Talip, Z.; Eral, M.; Hiçsönmez, Ü. Journal of Environmental Radioactivity, Vol. 100, Issue 2 https://doi.org/10.1016/j.jenvrad.2008.09.004	journal	February 2009
An²²⁵Ac/²¹³Bi generator system for therapeutic clinical applications: construction and operation McDevitt, Michael R.; Finn, Ronald D.; Sgouros, George Applied Radiation and Isotopes, Vol. 50, Issue 5, p. 895-904 https://doi.org/10.1016/S0969-8043(98)00151-1	journal	May 1999
Overview of the Most Promising Radionuclides for Targeted Alpha Therapy: The “Hopeful Eight” Eychenne, Romain; Chérel, Michel; Haddad, Férid Pharmaceutics, Vol. 13, Issue 6 https://doi.org/10.3390/pharmaceutics13060906	journal	June 2021
Metal Oxide Sorbents for the Separation of Radium and Actinium Brown, M. Alex Industrial & Engineering Chemistry Research, Vol. 59, Issue 46 https://doi.org/10.1021/acs.iecr.0c04084	journal	November 2020
Sorption and diffusion behavior of actinium(iii) ions in contact with hydroxyapatite as a transporter of medical radionuclides Severin, A. V.; Vasiliev, A. N.; Gopin, A. V. Russian Chemical Bulletin, Vol. 69, Issue 12 https://doi.org/10.1007/s11172-020-3041-y	journal	December 2020
225Ac-PSMA-617 for PSMA-Targeted -Radiation Therapy of Metastatic Castration-Resistant Prostate Cancer Kratochwil, C.; Bruchertseifer, F.; Giesel, F. L. Journal of Nuclear Medicine, Vol. 57, Issue 12 https://doi.org/10.2967/jnumed.116.178673	journal	July 2016
Part I. Chromatography using ultra-stable metal oxide-based stationary phases for HPLC Nawrocki, J.; Dunlap, C.; McCormick, A. Journal of Chromatography A, Vol. 1028, Issue 1 https://doi.org/10.1016/j.chroma.2003.11.052	journal	February 2004
Radiation Stability of Sorbents in Medical ²²⁵Ac/²¹³Bi Generators Vasiliev, A. N.; Zobnin, V. A.; Pavlov, Yu. S. Solvent Extraction and Ion Exchange, Vol. 39, Issue 4 https://doi.org/10.1080/07366299.2020.1846892	journal	November 2020

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