A critical literature review of the advances in methane dehydroaromatization over multifunctional metal-promoted zeolite catalysts

Menon, Unmesh; Rahman, Mustafizur; Khatib, Sheima J.

doi:10.1016/j.apcata.2020.117870

Title: A critical literature review of the advances in methane dehydroaromatization over multifunctional metal-promoted zeolite catalysts

Journal Article · Sun Oct 18 00:00:00 EDT 2020 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2020.117870· OSTI ID:1852802

Menon, Unmesh ^[1]; Rahman, Mustafizur ^[1];

^[1]

Texas Tech Univ., Lubbock, TX (United States)

We report the drastic rise in shale gas production has encouraged the quest for alternative uses of methane as a chemical feedstock in the manufacturing industry. While two-step syngas routes for methane valorization are deployed commercially, direct one-step routes for methane conversion are attracting much attention. As steam cracking installations have shifted from using oil-based naphtha to shale-based natural gas liquids, production of aromatics has dropped. Methane dehydroaromatization (MDA) is a one-step reaction capable of valorizing methane to hydrogen and benzene. Challenges with the MDA reaction are two-fold: the reaction is thermodynamically limited with low one-pass methane conversion and even the best catalytic systems, Mo/zeolites, suffer rapid deactivation from coking. A catalyst design strategy to improve stability is the use of multifunctional Mo-X/zeolite systems where X is a dopant capable of modulating the stability. In this paper we provide a complete overview of the main Mo-X/zeolite systems used in MDA and critically draw connections among the different types of dopants (X) employed, as a function of the role they play in the reaction/deactivation pathway. We have also dedicated a section to emerging trends with non-Mo based catalysts. The goal of this review article is to establish a basis that will facilitate the identification of useful multifunctional catalytic systems, and recognize gaps in the knowledge of these systems that deserve more attention. Improving MDA systems to the point to which they can be commercially deployed requires a multifaceted approach that combines optimization of the designs of both the catalyst and the reactor configuration. We therefore also provide a brief overview of the most recent advances in process intensification strategies employed with different reactor configurations.

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Research Organization:: Texas Tech Univ., Lubbock, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019074

OSTI ID:: 1852802

Alternate ID(s):: OSTI ID: 1778322

Journal Information:: Applied Catalysis. A, General, Vol. 608, Issue C; ISSN 0926-860X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (109)

Selective Dehydroaromatization of Methane toward Benzene on Re/HZSM-5 Catalysts and Effects of CO/CO2 Addition Wang, Linsheng; Ohnishi, Ryuichiro; Ichikawa, Masaru Journal of Catalysis, Vol. 190, Issue 2 https://doi.org/10.1006/jcat.1999.2748	journal	March 2000
CH4 dehydroaromatization on Mo/H–ZSM-5: 1. Effects of co-processing H2 and CH3COOH Bedard, Jeremy; Hong, Do-Young; Bhan, Aditya Journal of Catalysis, Vol. 306 https://doi.org/10.1016/j.jcat.2013.06.003	journal	October 2013
Active phase, catalytic activity, and induction period of Fe/zeolite material in nonoxidative aromatization of methane Tan, Pinglian Journal of Catalysis, Vol. 338 https://doi.org/10.1016/j.jcat.2016.01.027	journal	June 2016
Effects of Co-fed O2 and CO2 on the deactivation of Mo/HZSM-5 for methane aromatization Tan, P. L.; Wong, K. W.; Au, C. T. Applied Catalysis A: General, Vol. 253, Issue 1 https://doi.org/10.1016/S0926-860X(03)00541-6	journal	October 2003
Increasing the catalytic stability by optimizing the formation of zeolite-supported Mo carbide species ex situ for methane dehydroaromatization Rahman, Mustafizur; Infantes-Molina, Antonia; Boubnov, Alexey Journal of Catalysis, Vol. 375 https://doi.org/10.1016/j.jcat.2019.06.002	journal	July 2019
Methane aromatization using Mo-based catalysts prepared by microwave heating Qi, Suitao; Yang, Bolun Catalysis Today, Vol. 98, Issue 4 https://doi.org/10.1016/j.cattod.2004.09.049	journal	December 2004
Impact of the presence of Mo carbide species prepared ex situ in Mo/HZSM-5 on the catalytic properties in methane aromatization Rahman, Mustafizur; Sridhar, Apoorva; Khatib, Sheima J. Applied Catalysis A: General, Vol. 558 https://doi.org/10.1016/j.apcata.2018.03.023	journal	May 2018
Methane and ethane activation without adding oxygen: promotional effect of W in Mo-W/HZSM-5 Wong, She-Tin; Xu, Yide; Wang, Linsheng Catalysis Letters, Vol. 38, Issue 1-2 https://doi.org/10.1007/BF00806897	journal	January 1996
Progress in Nonoxidative Dehydroaromatization of Methane in the Last 6 Years Sun, Kaidi; Ginosar, Daniel M.; He, Ting Industrial & Engineering Chemistry Research, Vol. 57, Issue 6 https://doi.org/10.1021/acs.iecr.7b04707	journal	February 2018
Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Catalysts for Nonoxidative Methane Conversion Borry, Richard W.; Kim, Young Ho; Huffsmith, Anne The Journal of Physical Chemistry B, Vol. 103, Issue 28 https://doi.org/10.1021/jp990866v	journal	July 1999
Activity Descriptors Derived from Comparison of Mo and Fe as Active Metal for Methane Conversion to Aromatics Vollmer, Ina; Ould-Chikh, Samy; Aguilar-Tapia, Antonio Journal of the American Chemical Society, Vol. 141, Issue 47 https://doi.org/10.1021/jacs.9b09710	journal	November 2019
Comparison of the activity stabilities of nanosized and microsized zeolites based Fe–Mo/HZSM-5 catalysts in the non-oxidative CH4 dehydroaromatization under periodic CH4–H2 switching operation at 1073K Xu, Yuebing; Suzuki, Yoshizo; Zhang, Zhan-Guo Applied Catalysis A: General, Vol. 452 https://doi.org/10.1016/j.apcata.2012.11.027	journal	February 2013
Catalytic conversion of methane to benzene over Mo/ZSM-5 Wang, Dingjun; Lunsford, Jack H.; Rosynek, Michael P. Topics in Catalysis, Vol. 3, Issue 3-4 https://doi.org/10.1007/BF02113855	journal	August 1996
Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology Ma, Shuqi; Guo, Xiaoguang; Zhao, Lingxiao Journal of Energy Chemistry, Vol. 22, Issue 1 https://doi.org/10.1016/S2095-4956(13)60001-7	journal	January 2013
Effect of Cr Addition on the Methane Aromatization Performance of the Mo/HZSM-5 Catalyst Zhang, Y.; Wang, D.; Fei, J. Australian Journal of Chemistry, Vol. 55, Issue 8 https://doi.org/10.1071/CH01170	journal	January 2002
Direct conversion of methane on Mo/ZSM-5 catalysts to produce benzene and hydrogen: achievements and perspectives Ismagilov, Zinfer R.; Matus, Ekaterina V.; Tsikoza, Lidia T. Energy & Environmental Science, Vol. 1, Issue 5 https://doi.org/10.1039/b810981h	journal	January 2008
Progress in Developing a Structure‐Activity Relationship for the Direct Aromatization of Methane Vollmer, Ina; Yarulina, Irina; Kapteijn, Freek ChemCatChem, Vol. 11, Issue 1 https://doi.org/10.1002/cctc.201800880	journal	July 2018
Determination of Molybdenum Species Evolution during Non‐Oxidative Dehydroaromatization of Methane and its Implications for Catalytic Performance Agote‐Arán, Miren; Kroner, Anna B.; Islam, Husn U. ChemCatChem, Vol. 11, Issue 1 https://doi.org/10.1002/cctc.201801299	journal	October 2018
Pressurized Dehydrocondensation of Methane toward Benzene and Naphthalene on Mo/HZSM-5 Catalyst: Optimization of Reaction Parameters and Promotion by CO2 Addition Shu, Yuying; Ohnishi, Ryuichiro; Ichikawa, Masaru Journal of Catalysis, Vol. 206, Issue 1 https://doi.org/10.1006/jcat.2001.3481	journal	February 2002
Methane Nonoxidative Aromatization over Ru−Mo/HZSM-5 in a Membrane Catalytic Reactor Iliuta, Maria C.; Larachi, Faïçal; Grandjean, Bernard P. A. Industrial & Engineering Chemistry Research, Vol. 41, Issue 10 https://doi.org/10.1021/ie010977s	journal	May 2002
Bifunctional Behavior of Mo/HZSM-5 Catalysts in Methane Aromatization Shu, Jun; Adnot, Alain; Grandjean, Bernard P. A. Industrial & Engineering Chemistry Research, Vol. 38, Issue 10 https://doi.org/10.1021/ie990145i	journal	October 1999
Initial Carbon−Carbon Bond Formation during the Early Stages of Methane Dehydroaromatization Çağlayan, Mustafa; Lucini Paioni, Alessandra; Abou‐Hamad, Edy Angewandte Chemie International Edition, Vol. 59, Issue 38 https://doi.org/10.1002/anie.202007283	journal	July 2020
Shape Selectivity in Methane Dehydroaromatization Over Mo/MCM-22 Catalysts During a Lifetime Experiment Bai, J.; Liu, Shenglin; Xie, Sujuan Catalysis Letters, Vol. 90, Issue 3/4 https://doi.org/10.1023/B:CATL.0000004104.12763.80	journal	October 2003
Absorptive Hydrogen Scavenging for Enhanced Aromatics Yield During Non‐oxidative Methane Dehydroaromatization on Mo/H‐ZSM‐5 Catalysts Kumar, Anurag; Song, Kepeng; Liu, Lingmei Angewandte Chemie, Vol. 130, Issue 47 https://doi.org/10.1002/ange.201809433	journal	November 2018
Probing cobalt localization on HZSM-5 for efficient methane dehydroaromatization catalysts Xu, Yuebing; Chen, Mengyao; Wang, Ting Journal of Catalysis, Vol. 387 https://doi.org/10.1016/j.jcat.2020.04.021	journal	July 2020
Thermodynamic Analysis of Nonoxidative Dehydroaromatization of Methane Moghimpour Bijani, P.; Sohrabi, M.; Sahebdelfar, S. Chemical Engineering & Technology, Vol. 35, Issue 10 https://doi.org/10.1002/ceat.201100436	journal	June 2012
On the deactivation of Mo/HZSM-5 in the methane dehydroaromatization reaction Tempelman, Christiaan H. L.; Hensen, Emiel J. M. Applied Catalysis B: Environmental, Vol. 176-177 https://doi.org/10.1016/j.apcatb.2015.04.052	journal	October 2015
The effect of dopants on the activity of MoO3/ZSM-5 catalysts for the dehydroaromatisation of methane Burns, S.; Hargreaves, J. S. J.; Pal, P. Catalysis Today, Vol. 114, Issue 4 https://doi.org/10.1016/j.cattod.2006.02.030	journal	May 2006
Conversion of methane to aromatics over Mo2C/ZSM-5 catalyst in different reactor types Cook, Bruce; Mousko, Dimitri; Hoelderich, Wolfgang Applied Catalysis A: General, Vol. 365, Issue 1 https://doi.org/10.1016/j.apcata.2009.05.037	journal	August 2009
Direct conversion of methane under nonoxidative conditions Xu, Yide; Bao, Xinhe; Lin, Liwu Journal of Catalysis, Vol. 216, Issue 1-2 https://doi.org/10.1016/S0021-9517(02)00124-0	journal	May 2003
On the dynamic nature of Mo sites for methane dehydroaromatization Vollmer, Ina; van der Linden, Bart; Ould-Chikh, Samy Chemical Science, Vol. 9, Issue 21 https://doi.org/10.1039/C8SC01263F	journal	January 2018
Bifunctional catalysis of Mo/HZSM-5 in the dehydroaromatization of methane with CO/CO2 to benzene and naphthalene Liu, S.; Wang, L.; Ohnishi, R. Kinetics and Catalysis, Vol. 41, Issue 1 https://doi.org/10.1007/BF02756152	journal	January 2000
Conversion of methane into higher hydrocarbons in the presence of ethylene over H-ZSM-5 loaded with silver cations Baba, Toshihide; Sawada, Hidenori Physical Chemistry Chemical Physics, Vol. 4, Issue 15 https://doi.org/10.1039/b200615b	journal	July 2002
Metal cation–acidic proton bifunctional catalyst for methane activation: conversion of 13CH4 in the presence of ethylene over metal cations-loaded H-ZSM-5 Baba, Toshihide; Abe, Yoshimune Applied Catalysis A: General, Vol. 250, Issue 2 https://doi.org/10.1016/S0926-860X(03)00321-1	journal	September 2003
Enhancement of Molybdenum/ZSM-5 Catalysts in Methane Aromatization by the Addition of Iron Promoters and by Reduction/Carburization Pretreatment Sridhar, Apoorva; Rahman, Mustafizur; Khatib, Sheima J. ChemCatChem, Vol. 10, Issue 12 https://doi.org/10.1002/cctc.201800002	journal	May 2018
Tuning the acidity and reducibility of Fe/ZSM-5 catalysts for methane dehydroaromatization Denardin, Felipe; Perez-Lopez, Oscar W. Fuel, Vol. 236 https://doi.org/10.1016/j.fuel.2018.09.128	journal	January 2019
Enhanced Methane Dehydroaromatization via Coupling with Chemical Looping Brady, Casper; Murphy, Brian; Xu, Bingjun ACS Catalysis, Vol. 7, Issue 6 https://doi.org/10.1021/acscatal.7b00879	journal	May 2017
Methane Dehydroaromatization by Mo/HZSM-5: Mono- or Bifunctional Catalysis? Kosinov, Nikolay; Coumans, Ferdy J. A. G.; Uslamin, Evgeny A. ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02497	journal	December 2016
Effect of Pd or Ir on the catalytic performance of Mo/H-ZSM-5 during the non-oxidative conversion of natural gas to petrochemicals Aboul-Gheit, Ahmed K.; Awadallah, Ahmed E.; El-Kossy, Salah M. Journal of Natural Gas Chemistry, Vol. 17, Issue 4 https://doi.org/10.1016/S1003-9953(09)60005-0	journal	December 2008
Aromatization of Methane Over Mo-Fe/ZSM-5 Catalysts Masiero, Sara S.; Marcilio, Nilson R.; Perez-Lopez, Oscar W. Catalysis Letters, Vol. 131, Issue 1-2 https://doi.org/10.1007/s10562-009-0032-x	journal	June 2009
Effect of boron addition on a MoO3/Al2O3 catalyst Usman, U.; Takaki, Mayu; Kubota, Takeshi Applied Catalysis A: General, Vol. 286, Issue 1 https://doi.org/10.1016/j.apcata.2005.03.020	journal	May 2005
Study of Methane Dehydroaromatization on Impregnated Mo/ZSM-5 Catalysts and Characterization of Nanostructured Molybdenum Phases and Carbonaceous Deposits Matus, Ekaterina V.; Ismagilov, Ilyas Z.; Sukhova, Olga B. Industrial & Engineering Chemistry Research, Vol. 46, Issue 12 https://doi.org/10.1021/ie0609564	journal	June 2007
Metal/zeolite catalysts of methane dehydroaromatization Mamonov, N. A.; Fadeeva, E. V.; Grigoriev, D. A. Russian Chemical Reviews, Vol. 82, Issue 6 https://doi.org/10.1070/RC2013v082n06ABEH004346	journal	June 2013
Stable Mo/HZSM-5 methane dehydroaromatization catalysts optimized for high-temperature calcination-regeneration Kosinov, Nikolay; Coumans, Ferdy J. A. G.; Li, Guanna Journal of Catalysis, Vol. 346 https://doi.org/10.1016/j.jcat.2016.12.006	journal	February 2017
Non-oxidative dehydroaromatization of methane over Ga-promoted Mo/HZSM-5-based catalysts Liu, Bingsi; Yang, Yong; Sayari, Abdelhamid Applied Catalysis A: General, Vol. 214, Issue 1 https://doi.org/10.1016/S0926-860X(01)00470-7	journal	June 2001
The function of Cu(II) ions in the Mo/CuH-ZSM-5 catalyst for methane conversion under non-oxidative condition Li, Shuang; Zhang, Chunlei; Kan, Qiubin Applied Catalysis A: General, Vol. 187, Issue 2 https://doi.org/10.1016/S0926-860X(99)00231-8	journal	October 1999
Catalytic Methane Dehydroaromatization with Stable Nano Fe Doped on Mo/HZSM-5 Synthesized with a Simple and Environmentally Friendly Method and Clarification of a Perplexing Catalysis Mechanism Dilemma in This Field for a Period of Time Sun, Kaidi; Gong, Weibo; Gasem, Khaled Industrial & Engineering Chemistry Research, Vol. 56, Issue 40 https://doi.org/10.1021/acs.iecr.7b02213	journal	September 2017
Highly active, selective and stable Mo/Ru-HZSM-5 catalysts for oxygen-free methane aromatization Hassan, A.; Sayari, A. Applied Catalysis A: General, Vol. 297, Issue 2 https://doi.org/10.1016/j.apcata.2005.09.004	journal	January 2006
Gas to Liquids: Natural Gas Conversion to Aromatic Fuels and Chemicals in a Hydrogen-Permeable Ceramic Hollow Fiber Membrane Reactor Xue, Jian; Chen, Yan; Wei, Yanying ACS Catalysis, Vol. 6, Issue 4 https://doi.org/10.1021/acscatal.6b00004	journal	March 2016
Promotional effect of Pt on non-oxidative methane transformation over Mo-HZSM-5 catalyst Chen, Laiyuan; Lin, Liwu; Xu, Zhusheng Catalysis Letters, Vol. 39, Issue 3-4 https://doi.org/10.1007/BF00805578	journal	January 1996
Catalytic Conversion of Methane into Aromatic Hydrocarbons over Iron Oxide Loaded ZSM-5 Zeolites Weckhuysen, Bert M.; Wang, Dingjun; Rosynek, Michael P. Angewandte Chemie International Edition in English, Vol. 36, Issue 21 https://doi.org/10.1002/anie.199723741	journal	November 1997
Stability, structure, and oxidation state of Mo/H-ZSM-5 catalysts during reactions of CH4 and CH4–CO2 mixtures Lacheen, H.; Iglesia, E. Journal of Catalysis, Vol. 230, Issue 1 https://doi.org/10.1016/j.jcat.2004.11.037	journal	February 2005
Effect of addition of a second metal in Mo/ZSM-5 catalyst for methane aromatization reaction under elevated pressures Fila, Vlastimil; Bernauer, Milan; Bernauer, Bohumil Catalysis Today, Vol. 256 https://doi.org/10.1016/j.cattod.2015.02.035	journal	November 2015
Methane Dehydro-aromatization under Nonoxidative Conditions over Mo/HZSM-5 Catalysts: EPR Study of the Mo Species on/in the HZSM-5 Zeolite Ma, Ding; Shu, Yuying; Bao, Xinhe Journal of Catalysis, Vol. 189, Issue 2 https://doi.org/10.1006/jcat.1999.2704	journal	January 2000
Counteracting Catalyst Deactivation in Methane Aromatization with a Two Zone Fluidized Bed Reactor Gimeno, María Pilar; Soler, Jaime; Herguido, Javier Industrial & Engineering Chemistry Research, Vol. 49, Issue 3 https://doi.org/10.1021/ie900682y	journal	February 2010
Enhanced methane dehydroaromatization in the presence of CO 2 over Fe- and Mg-modified Mo/ZSM-5 Cheng, Xu; Yan, Peng; Zhang, Xinzhuang Molecular Catalysis, Vol. 437 https://doi.org/10.1016/j.mcat.2017.05.011	journal	August 2017
The Effects of Silanation of External Acid Sites on the Structure and Catalytic Behavior of Mo/H–ZSM5 Ding, Weiping; Meitzner, George D.; Iglesia, Enrique Journal of Catalysis, Vol. 206, Issue 1 https://doi.org/10.1006/jcat.2001.3457	journal	February 2002
Promotional Effect of Ru on the Dehydrogenation and Aromatization of Methane in the Absence of Oxygen over Mo/HZSM-5 Catalysts Shu, Yuying; Xu, Yide; Wong, She-Tin Journal of Catalysis, Vol. 170, Issue 1 https://doi.org/10.1006/jcat.1997.1726	journal	August 1997
Methane dehydroaromatization over Fe-M/ZSM-5 catalysts (M= Zr, Nb, Mo) Denardin, Felipe G.; Perez-Lopez, Oscar W. Microporous and Mesoporous Materials, Vol. 295 https://doi.org/10.1016/j.micromeso.2019.109961	journal	March 2020
Structure and Evolution of Confined Carbon Species during Methane Dehydroaromatization over Mo/ZSM-5 Kosinov, Nikolay; Uslamin, Evgeny A.; Coumans, Ferdy J. A. G. ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b02491	journal	August 2018
Confined Carbon Mediating Dehydroaromatization of Methane over Mo/ZSM-5 Kosinov, Nikolay; Wijpkema, Alexandra S. G.; Uslamin, Evgeny Angewandte Chemie, Vol. 130, Issue 4 https://doi.org/10.1002/ange.201711098	journal	December 2017
Molybdenum Oxide, Oxycarbide, and Carbide: Controlling the Dynamic Composition, Size, and Catalytic Activity of Zeolite-Supported Nanostructures Zheng, Yiteng; Tang, Yadan; Gallagher, James R. The Journal of Physical Chemistry C, Vol. 123, Issue 36 https://doi.org/10.1021/acs.jpcc.9b05449	journal	August 2019
Use of Al2O3–SnO2 as a support of Pt for selective dehydrogenation of light paraffins Ballarini, Adriana D.; Ricci, Claudia G.; de Miguel, Sergio R. Catalysis Today, Vol. 133-135 https://doi.org/10.1016/j.cattod.2007.11.055	journal	April 2008
Improving effect of Fe additive on the catalytic stability of Mo/HZSM-5 in the methane dehydroaromatization Xu, Yuebing; Wang, Jide; Suzuki, Yoshizo Catalysis Today, Vol. 185, Issue 1 https://doi.org/10.1016/j.cattod.2011.09.026	journal	May 2012
Advances in Catalyst Design for the Conversion of Methane to Aromatics: A Critical Review Galadima, Ahmad; Muraza, Oki Catalysis Surveys from Asia, Vol. 23, Issue 3 https://doi.org/10.1007/s10563-018-9262-5	journal	March 2019
Non-oxidative conversion of methane to aromatics over modified Mo/HZSM5 catalysts Tang, S.; Chen, H.; Lin, J. Catalysis Communications, Vol. 2, Issue 1 https://doi.org/10.1016/S1566-7367(01)00005-X	journal	March 2001
Influence of ethylene and acetylene on the rate and reversibility of methane dehydroaromatization on Mo/H-ZSM-5 catalysts Razdan, Neil K.; Kumar, Anurag; Foley, Brandon L. Journal of Catalysis, Vol. 381 https://doi.org/10.1016/j.jcat.2019.11.004	journal	January 2020
W/HZSM-5 catalyst for methane dehydroaromatization: a multinuclear MAS NMR study Yang, Jun; Deng, Feng; Zhang, Mingjin Journal of Molecular Catalysis A: Chemical, Vol. 202, Issue 1-2 https://doi.org/10.1016/S1381-1169(03)00187-0	journal	August 2003
Oxygen-Free Methane Aromatization in a Catalytic Membrane Reactor Rival, Olivier; Grandjean, Bernard P. A.; Guy, Christophe Industrial & Engineering Chemistry Research, Vol. 40, Issue 10 https://doi.org/10.1021/ie001089k	journal	May 2001
XPS, XAES, and TG/DTA characterization of deposited carbon in methane dehydroaromatization over Ga–Mo/ZSM-5 catalyst Liu, B. S.; Jiang, L.; Sun, H. Applied Surface Science, Vol. 253, Issue 11 https://doi.org/10.1016/j.apsusc.2006.11.031	journal	March 2007
Synthesis, Structural Characterization, and Catalytic Properties of Tungsten-Exchanged H-ZSM5 ^† Ding, Weiping; Meitzner, George D.; Marler, David O. The Journal of Physical Chemistry B, Vol. 105, Issue 18 https://doi.org/10.1021/jp003413v	journal	May 2001
Raman and X-Ray Absorption Studies of Mo Species in Mo/H-ZSM5 Catalysts for Non-Oxidative CH4 Reactions Li, Wei; Meitzner, George D.; Borry, Richard W. Journal of Catalysis, Vol. 191, Issue 2 https://doi.org/10.1006/jcat.1999.2795	journal	April 2000
Promotional effect of Au on Fe/HZSM-5 catalyst for methane dehydroaromatization Sim, Jaeik Paul; Lee, Byung Jin; Han, Geun-Ho Fuel, Vol. 274 https://doi.org/10.1016/j.fuel.2020.117852	journal	August 2020
Methane activation without using oxidants over Mo/HZSM-5 zeolite catalysts Xu, Yide; Liu, Shetian; Guo, Xiexian Catalysis Letters, Vol. 30, Issue 1-4 https://doi.org/10.1007/BF00813680	journal	January 1995
Active sites of the methane dehydroaromatization catalyst W-ZSM-5: An HRTEM study Kozlov, V. V.; Zaikovskii, V. I.; Vosmerikov, A. V. Kinetics and Catalysis, Vol. 49, Issue 1 https://doi.org/10.1134/S0023158408010138	journal	January 2008
Nonoxidative conversion of methane into aromatic hydrocarbons on Ni-Mo/ZSM-5 catalysts Vosmerikov, A. V.; Zaikovskii, V. I.; Korobitsyna, L. L. Kinetics and Catalysis, Vol. 50, Issue 5 https://doi.org/10.1134/S0023158409050140	journal	September 2009
Direct conversion of natural gas to higher hydrocarbons: A review Majhi, Sachchit; Mohanty, Pravakar; Wang, Hui Journal of Energy Chemistry, Vol. 22, Issue 4 https://doi.org/10.1016/S2095-4956(13)60071-6	journal	July 2013
Conversion of Methane to Benzene over Transition Metal Ion ZSM-5 Zeolites Weckhuysen, Bert M.; Wang, Dingjun; Rosynek, Michael P. Journal of Catalysis, Vol. 175, Issue 2 https://doi.org/10.1006/jcat.1998.2010	journal	April 1998
The effects of boron and silver on the oxygen-free conversion of methane over Mo/H-ZSM-5 catalysts Ngobeni, M. W.; Carley, A. F.; Scurrell, M. S. Journal of Molecular Catalysis A: Chemical, Vol. 305, Issue 1-2 https://doi.org/10.1016/j.molcata.2008.10.047	journal	June 2009
Effect of Fe and Zn promoters on Mo/HZSM-5 catalyst for methane dehydroaromatization Abdelsayed, Victor; Shekhawat, Dushyant; Smith, Mark W. Fuel, Vol. 139 https://doi.org/10.1016/j.fuel.2014.08.064	journal	January 2015
Remarkable non-oxidative conversion of methane to naphthalene and benzene on Co and Fe modified Mo/HZSM-5 catalysts Liu, Shetian; Dong, Qun; Ohnishi, Ryuichiro Chemical Communications, Issue 15 https://doi.org/10.1039/a702731a	journal	January 1997
Dehydroaromatization of methane over doped Pt/Mo/H-ZSM-5 zeolite catalysts: The promotional effect of tin Tshabalala, Themba E.; Coville, Neil J.; Scurrell, Michael S. Applied Catalysis A: General, Vol. 485 https://doi.org/10.1016/j.apcata.2014.07.022	journal	September 2014
Controlling kinetic and diffusive length-scales during absorptive hydrogen removal in methane dehydroaromatization on MoCx/H-ZSM-5 catalysts Razdan, Neil K.; Kumar, Anurag; Bhan, Aditya Journal of Catalysis, Vol. 372 https://doi.org/10.1016/j.jcat.2019.03.016	journal	April 2019
Some technological aspects of methane aromatization (direct and via oxidative coupling) Skutil, Krzysztof; Taniewski, Marian Fuel Processing Technology, Vol. 87, Issue 6 https://doi.org/10.1016/j.fuproc.2005.12.001	journal	June 2006
Direct Conversion of Methane to Value-Added Chemicals over Heterogeneous Catalysts: Challenges and Prospects Schwach, Pierre; Pan, Xiulian; Bao, Xinhe Chemical Reviews, Vol. 117, Issue 13 https://doi.org/10.1021/acs.chemrev.6b00715	journal	March 2017
Methane Conversion to Ethylene and Aromatics on PtSn Catalysts Gerceker, Duygu; Motagamwala, Ali Hussain; Rivera-Dones, Keishla R. ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b02724	journal	February 2017
Catalytic aromatization of methane Spivey, James J.; Hutchings, Graham Chem. Soc. Rev., Vol. 43, Issue 3 https://doi.org/10.1039/C3CS60259A	journal	January 2014
NGU: Development of a two-bed circulating fluidized bed reactor system for nonoxidative aromatization of methane over Mo/HZSM-5 catalyst Zhang, Zhanguo; Xu, Yuebing; Song, Yang Environmental Progress & Sustainable Energy, Vol. 35, Issue 2 https://doi.org/10.1002/ep.12287	journal	January 2016
A site-sensitive quasi-in situ strategy to characterize Mo/HZSM-5 during activation Vollmer, Ina; Kosinov, Nikolay; Szécsényi, Ágnes Journal of Catalysis, Vol. 370 https://doi.org/10.1016/j.jcat.2019.01.013	journal	February 2019
Effect of transition metal additives on the catalytic stability of Mo/HZSM-5 in the methane dehydroaromatization under periodic CH4–H2 switch operation at 1073K Xu, Yuebing; Wang, Jide; Suzuki, Yoshizo Applied Catalysis A: General, Vol. 409-410 https://doi.org/10.1016/j.apcata.2011.10.003	journal	December 2011
Efficient Conversion of Methane to Aromatics by Coupling Methylation Reaction Liu, Yi; Li, Defu; Wang, Tianyun ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b01362	journal	July 2016
Metastable fcc α-MoC1−x supported on HZSM5: preparation and catalytic performance for the non-oxidative conversion of methane to aromatic compounds Bouchy, C.; Schmidt, I.; Anderson, J. R. Journal of Molecular Catalysis A: Chemical, Vol. 163, Issue 1-2 https://doi.org/10.1016/S1381-1169(00)00392-7	journal	December 2000
Methane Nonoxidative Aromatization over Ru−Mo/HZSM-5 at Temperatures up to 973 K in a Palladium−Silver/Stainless Steel Membrane Reactor Iliuta, Maria C.; Grandjean, Bernard P. A.; Larachi, Faïçal Industrial & Engineering Chemistry Research, Vol. 42, Issue 2 https://doi.org/10.1021/ie020486n	journal	January 2003
Oxygen free conversion of natural gas to useful hydrocarbons and hydrogen over monometallic Mo and bimetallic Mo–Fe, Mo–Co or Mo–Ni/HZSM-5 catalysts prepared by mechanical mixing Aboul-Gheit, Ahmed K.; El-Masry, Mohamed S.; Awadallah, Ahmed E. Fuel Processing Technology, Vol. 102 https://doi.org/10.1016/j.fuproc.2012.04.017	journal	October 2012
CH ₄ conversion over Ni/HZSM-5 catalyst in the absence of oxygen: decomposition or dehydroaromatization? Xu, Yuebing; Chen, Mengyao; Liu, Bing Chemical Communications, Vol. 56, Issue 32 https://doi.org/10.1039/D0CC01345E	journal	January 2020
Recent advances in methane dehydro-aromatization over transition metal ion-modified zeolite catalysts under non-oxidative conditions Xu, Yide; Lin, Liwu Applied Catalysis A: General, Vol. 188, Issue 1-2 https://doi.org/10.1016/S0926-860X(99)00210-0	journal	November 1999
The catalytic stability of Mo/HZSM-5 in methane dehydroaromatization at severe and periodic CH4–H2 switch operating conditions Xu, Yuebing; Lu, Jiangyin; Wang, Jide Chemical Engineering Journal, Vol. 168, Issue 1 https://doi.org/10.1016/j.cej.2011.01.047	journal	March 2011
Catalytic Upgrading of Methane to Higher Hydrocarbon in a Nonoxidative Chemical Conversion Nahreen, Shaima; Praserthdam, Supareak; Perez Beltran, Saul Energy & Fuels, Vol. 30, Issue 4 https://doi.org/10.1021/acs.energyfuels.5b02583	journal	March 2016
Direct Imaging of Atomically Dispersed Molybdenum that Enables Location of Aluminum in the Framework of Zeolite ZSM‐5 Liu, Lingmei; Wang, Ning; Zhu, Chongzhi Angewandte Chemie, Vol. 132, Issue 2 https://doi.org/10.1002/ange.201909834	journal	December 2019
Effect of impregnation of ZSM-5 with H3BO3 on its acidity: A microcalorimetric study of NH3 adsorption Sayed, Moein B.; Auroux, Aline; Vedrine, Jacques C. Applied Catalysis, Vol. 23, Issue 1 https://doi.org/10.1016/S0166-9834(00)81451-7	journal	May 1986
Progress in the direct catalytic conversion of methane to fuels and chemicals Karakaya, Canan; Kee, Robert J. Progress in Energy and Combustion Science, Vol. 55 https://doi.org/10.1016/j.pecs.2016.04.003	journal	July 2016
Methane Direct Conversion on Mo/ZSM-5 Catalysts Modified by Pd and Ru Sily, Priscila Dias; Noronha, Fabio Bellot; Passos, Fabio Barboza Journal of Natural Gas Chemistry, Vol. 15, Issue 2 https://doi.org/10.1016/S1003-9953(06)60012-1	journal	June 2006
Identification of molybdenum oxide nanostructures on zeolites for natural gas conversion Gao, J.; Zheng, Y.; Jehng, J. -M. Science, Vol. 348, Issue 6235 https://doi.org/10.1126/science.aaa7048	journal	April 2015
Methane dehydroaromatization under nonoxidative conditions over Mo/HZSM-5 catalysts: Identification and preparation of the Mo active species Liu, H.; Bao, X.; Xu, Y. Journal of Catalysis, Vol. 239, Issue 2 https://doi.org/10.1016/j.jcat.2006.02.018	journal	April 2006
Catalytic Dehydrocondensation of Methane with CO and CO2toward Benzene and Naphthalene on Mo/HZSM-5 and Fe/Co-Modified Mo/HZSM-5 Ohnishi, Ryuichiro; Liu, Shetian; Dong, Qun Journal of Catalysis, Vol. 182, Issue 1 https://doi.org/10.1006/jcat.1998.2319	journal	February 1999
Promotion effects of Pt and Rh on catalytic performances of Mo/HZSM-5 and Mo/HMCM-22 in selective methane-to-benzene reaction Kojima, Ryoichi; Kikuchi, Satoshi; Ma, Hongtao Catalysis Letters, Vol. 110, Issue 1-2 https://doi.org/10.1007/s10562-006-0087-x	journal	August 2006
Improved methane dehydrocondensation reaction on HMCM-22 and HZSM-5 supported rhenium and molybdenum catalysts Shu, Yuying; Ohnishi, Ryuichiro; Ichikawa, Masaru Applied Catalysis A: General, Vol. 252, Issue 2 https://doi.org/10.1016/S0926-860X(03)00467-8	journal	October 2003
Spectroscopic and Computational Study of Cr Oxide Structures and Their Anchoring Sites on ZSM-5 Zeolites Gao, Jie; Zheng, Yiteng; Tang, Yadan ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00333	journal	March 2015
Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior Sridhar, Apoorva; Rahman, Mustafizur; Infantes-Molina, Antonia Applied Catalysis A: General, Vol. 589 https://doi.org/10.1016/j.apcata.2019.117247	journal	January 2020

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