skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Skin-like low-noise elastomeric organic photodiodes

Journal Article · · Science Advances
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [1];  [4]; ORCiD logo [5];  [5]; ORCiD logo [1]
  1. Georgia Inst. of Technology, Atlanta, GA (United States). Center for Organic Photonics and Electronics (COPE), School of Electrical and Computer Engineering
  2. Georgia Inst. of Technology, Atlanta, GA (United States). Center for Organic Photonics and Electronics (COPE), School of Electrical and Computer Engineering; Northeastern Univ., Boston, MA (United States)
  3. Georgia Inst. of Technology, Atlanta, GA (United States). George W. Woodruff School of Mechanical Engineering; Univ. of Connecticut, Storrs, CT (United States)
  4. Georgia Inst. of Technology, Atlanta, GA (United States). Center for Organic Photonics and Electronics (COPE), School of Electrical and Computer Engineering; Universidad Adolfo Ibáñez, Santiago (Chile)
  5. Georgia Inst. of Technology, Atlanta, GA (United States). George W. Woodruff School of Mechanical Engineering

Stretchable optoelectronics made of elastomeric semiconductors could enable the integration of intelligent systems with soft materials, such as those of the biological world. Organic semiconductors and photodiodes have been engineered to be elastomeric; however, for photodetector applications, it remains a challenge to identify an elastomeric bulk heterojunction (e-BHJ) photoactive layer that combines a low Young’s modulus and a high strain at break that yields organic photodiodes with low electronic noise values and high photodetector performance. Here, a blend of an elastomer, a donor-like polymer, and an acceptor-like molecule yields a skin-like e-BHJ with a Young’s modulus of a few megapascals, comparable to values of human tissues, and a high strain at break of 189%. Elastomeric organic photodiodes based on e-BHJ photoactive layers maintain low electronic noise current values in the tens of femtoamperes range and noise equivalent power values in the tens of picowatts range under at least 60% strain.

Research Organization:
Georgia Institute of Technology, Atlanta, GA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); US Department of the Navy, Office of Naval Research (ONR); US Air Force Office of Scientific Research (AFOSR); Chilean National Commission for Scientific and Technological Research (CONICYT); National Science Foundation (NSF)
Grant/Contract Number:
NA0003921; NA0002576; N00014-14-1-0580; N00014-16-1-2520; FA9550-16-1-0168; 72150387; 1400077
OSTI ID:
1842683
Journal Information:
Science Advances, Vol. 7, Issue 51; ISSN 2375-2548
Publisher:
AAASCopyright Statement
Country of Publication:
United States
Language:
English

References (29)

Flexible, highly efficient all-polymer solar cells journal October 2015
Mechanical Properties of Conjugated Polymers and Polymer-Fullerene Composites as a Function of Molecular Structure journal October 2013
Network-Stabilized Bulk Heterojunction Organic Photovoltaics journal October 2018
A Solid-State Intrinsically Stretchable Polymer Solar Cell journal November 2017
Accurate characterization of next-generation thin-film photodetectors journal December 2018
Intrinsically Stretchable Organic Solar Cells beyond 10% Power Conversion Efficiency Enabled by Transfer Printing Method journal June 2021
Recent Advances in Flexible Inorganic Light Emitting Diodes: From Materials Design to Integrated Optoelectronic Platforms journal September 2018
Highly stretchable polymer semiconductor films through the nanoconfinement effect journal January 2017
Intrinsically Stretchable Nanostructured Silver Electrodes for Realizing Efficient Strain Sensors and Stretchable Organic Photovoltaics journal August 2017
Increased elasticity of a low-bandgap conjugated copolymer by random segmentation for mechanically robust solar cells journal January 2014
Monitoring of Vital Signs with Flexible and Wearable Medical Devices journal February 2016
Ultraflexible organic photonic skin journal April 2016
Indentation Versus Tensile Measurements of Young's Modulus for Soft Biological Tissues journal June 2011
Highly Flexible and Efficient All-Polymer Solar Cells with High-Viscosity Processing Polymer Additive toward Potential of Stretchable Devices journal September 2018
A hemispherical electronic eye camera based on compressible silicon optoelectronics journal August 2008
The mechanical properties of the skin epidermis in relation to targeted gene and drug delivery journal November 2007
A Skin‐Inspired, Interactive, and Flexible Optoelectronic Device with Hydrated Melanin Nanoparticles in a Protein Hydrogel–Elastomer Hybrid journal February 2020
Stretchable organic optoelectronic devices: Design of materials, structures, and applications journal October 2021
Mechanical Properties of a Library of Low-Band-Gap Polymers journal March 2016
Stretchable Organic Solar Cells journal February 2011
Materials and technologies for soft implantable neuroprostheses journal September 2016
Waterproof AlInGaP optoelectronics on stretchable substrates with applications in biomedicine and robotics journal October 2010
A Flexible, Low Noise Reflective PPG Sensor Platform for Ear-Worn Heart Rate Monitoring
  • Patterson, James A. C.; McIlwraith, Douglas C.; Yang, Guang-Zhong
  • Implantable Body Sensor Networks Conference (BSN), 2009 Sixth International Workshop on Wearable and Implantable Body Sensor Networks https://doi.org/10.1109/BSN.2009.16
conference June 2009
Stretchable organic optoelectronic sensorimotor synapse journal November 2018
Recent Progress in Flexible and Stretchable Organic Solar Cells journal July 2020
[70]PCBM and Incompletely Separated Grades of Methanofullerenes Produce Bulk Heterojunctions with Increased Robustness for Ultra-Flexible and Stretchable Electronics journal May 2015
Ultraflexible Near-Infrared Organic Photodetectors for Conformal Photoplethysmogram Sensors journal July 2018
Intrinsically stretchable and healable semiconducting polymer for organic transistors journal November 2016
Large-area low-noise flexible organic photodiodes for detecting faint visible light journal November 2020

Similar Records

Stable solvent for solution-based electrical doping of semiconducting polymer films and its application to organic solar cells
Journal Article · Fri May 18 00:00:00 EDT 2018 · Energy & Environmental Science · OSTI ID:1842683

Increasing Volume in Conjugated Polymers to Facilitate Electrical Doping with Phosphomolybdic Acid
Journal Article · Thu May 06 00:00:00 EDT 2021 · ACS Applied Materials and Interfaces · OSTI ID:1842683

Effects of particle inclusions on cracking in ultrathin barrier films
Journal Article · Mon Oct 12 00:00:00 EDT 2020 · Thin Solid Films · OSTI ID:1842683

Related Subjects