Synthesis of metal complexes and uses thereof

Lee, Han

Title: Synthesis of metal complexes and uses thereof

Patent · Tue Apr 13 00:00:00 EDT 2021

OSTI ID:1823827

Lee, Han

The present disclosure provides novel methods of making aluminum complexes with utility for promoting epoxide carbonylation reactions. Methods include reacting neutral metal carbonyl compounds with alkylaluminum complexes. For example, a compound of formula I: is reacted with a neutral metal carbonyl compound (such as Q′dMe(CO)w′) to produce an aluminum-based carbonylation catalyst:

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Research Organization:: Novomer, Inc., Rochester, NY (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: EE0005766

Assignee:: Novomer, Inc. (Rochester, NY)

Patent Number(s):: 10,974,234

Application Number:: 16/054,904

OSTI ID:: 1823827

Resource Relation:: Patent File Date: 08/03/2018

Country of Publication:: United States

Language:: English

References (133)

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Absorbent article comprising a synthetic polymer derived from a renewable resource and methods of producing said article Collias, Dimitris Ioannis; Kellett, Patti Jean; Lingoes, Janette Villalobos https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110319849 US Patent Application 13/175145; 20110319849	patent-application	December 2011
Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof Sookraj, Sadesh H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190071538 US Patent Application 16/178214; 20190071538	patent-application	March 2019
Process for the production of gamma-butyrolactone Castiglioni, Gian Luca; Fumagalli, Carlo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6492535 US Patent Document 6,492,535	patent	December 2002
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Process for Production of Acrylates from Epoxides Porcelli, Richard V.; Farmer, Jay J.; LaPointe, Robert E. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170247309 US Patent Application 15/291011; 20170247309	patent-application	August 2017
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Process for Beta-lactone Production Allen, Scott D.; Valente, Ronald R.; Lee, Han https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160102040 US Patent Application 14/857313; 20160102040	patent-application	April 2016
Production of purified synthesis gas and carbon monoxide Marion, Charles P. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4081253 US Patent Document 4,081,253	patent	March 1978
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Process for preparing acrylic acid from ethylene oxide and carbon monoxide Pazicky, Marek; Raith, Christian; Paciello, Rocco https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140018570 US Patent Application 13/943068; 20140018570	patent-application	January 2014
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Process for preparing acrylic acid by a thermolysis of poly-3-hydroxypropionate catalyzed by at least one molecular active compound Raith, Christian; Pazicky, Marek; Paciello, Rocco https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140018574 US Patent Application 13/941856; 20140018574	patent-application	January 2014
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