Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Gao, Wen‐Yang; Sur, Aishanee; Wang, Chen‐Hao; Lorzing, Gregory R.; Antonio, Alexandra M.; Taggart, Garrett A.; Ezazi, Andrew A.; Bhuvanesh, Nattamai; Bloch, Eric D.; Powers, David C.

doi:10.1002/anie.202002638

Title: Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Journal Article · Mon Apr 06 00:00:00 EDT 2020 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202002638· OSTI ID:1780803

^[1];

^[1]; Lorzing, Gregory R. ^[2]; Antonio, Alexandra M. ^[2]; Taggart, Garrett A. ^[2];

^[1]; Bhuvanesh, Nattamai ^[1];

^[2];

^[1]

Texas A & M Univ., College Station, TX (United States)
Univ. of Delaware, Newark, DE (United States)

Abstract Atomistic control of the coordination environment of lattice ions and the distribution of metal sites within crystalline mixed‐metal coordination polymers remain significant synthetic challenges. Herein is reported the mechanochemical synthesis of a reticular family of crystalline heterobimetallic metal–organic frameworks (MOFs) is now achieved by polymerization of molecular Ru ₂ [II,III] complexes, featuring unprotected carboxylic acid substituents, with Cu(OAc) ₂ . The resulting crystalline heterobimetallic MOFs are solid solutions of Ru ₂ and Cu ₂ sites housed within [M ₃ L ₂ ] phases. The developed mechanochemical strategy is modular and allows for systematic control of the primary coordination sphere of the Ru ₂ sites within an isoreticular family of materials. This strategy is anticipated to provide a rational approach to atomically precise mixed‐metal materials.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018977; AC02-06CH11357; SC0012704

OSTI ID:: 1780803

Alternate ID(s):: OSTI ID: 1615441

Journal Information:: Angewandte Chemie (International Edition), Vol. 59, Issue 27; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 12 works

Citation information provided by
Web of Science

References (70)

A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H. Science, Vol. 283, Issue 5405, p. 1148-1150 https://doi.org/10.1126/science.283.5405.1148	journal	February 1999
Metalloligands to material: design strategies and network topologies Srivastava, Sumit; Gupta, Rajeev CrystEngComm, Vol. 18, Issue 48 https://doi.org/10.1039/C6CE01869F	journal	January 2016
Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang Angewandte Chemie International Edition, Vol. 57, Issue 14 https://doi.org/10.1002/anie.201713244	journal	March 2018
Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple ‘pseudo-fluid’ model for a ball milling reaction Ma, Xiaohe; Yuan, Wenbing; Bell, Steven E. J. Chemical Communications, Vol. 50, Issue 13 https://doi.org/10.1039/c3cc47898j	journal	January 2014
Benign by Design: Green and Scalable Synthesis of Zirconium UiO-Metal–Organic Frameworks by Water-Assisted Mechanochemistry Karadeniz, Bahar; Howarth, Ashlee J.; Stolar, Tomislav ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 11 https://doi.org/10.1021/acssuschemeng.8b04458	journal	October 2018
Structural Characterization and Remarkable Axial Ligand Effect on the Nucleophilic Reactivity of a Nonheme Manganese(III)-Peroxo Complex Annaraj, Jamespandi; Cho, Jaeheung; Lee, Yong-Min Angewandte Chemie, Vol. 121, Issue 23 https://doi.org/10.1002/ange.200900118	journal	May 2009
X-Ray Structure, Ligand Substitution, and Other Properties of Trinuclear Ruthenium Complex, [Ru ₃ (μ ₃ -O)(μ-C ₆ H ₅ COO) ₆ (py) ₃ ](PF ₆ ) (py = pyridine), and X-Ray Structure of Dinuclear Ruthenium Complex, [Ru ₂ (μ-C ₆ H ₅ COO) ₄ Cl] Abe, Masaaki; Sasaki, Yoichi; Yamaguchi, Tadashi Bulletin of the Chemical Society of Japan, Vol. 65, Issue 6 https://doi.org/10.1246/bcsj.65.1585	journal	June 1992
Oxygen-Atom Transfer by a Naked Manganese(V)-Oxo-Porphyrin Complex Reveals Axial Ligand Effect Crestoni, Maria Elisa; Fornarini, Simonetta; Lanucara, Francesco Chemistry - A European Journal, Vol. 15, Issue 32 https://doi.org/10.1002/chem.200901361	journal	August 2009
Mechanochemistry for Synthesis Friščić, Tomislav; Mottillo, Cristina; Titi, Hatem M. Angewandte Chemie, Vol. 132, Issue 3 https://doi.org/10.1002/ange.201906755	journal	September 2019
The asc Trinodal Platform: Two-Step Assembly of Triangular, Tetrahedral, and Trigonal-Prismatic Molecular Building Blocks Schoedel, Alexander; Cairns, Amy J.; Belmabkhout, Youssef Angewandte Chemie International Edition, Vol. 52, Issue 10, p. 2902-2905 https://doi.org/10.1002/anie.201206042	journal	February 2013
Network Diversity through Decoration of Trigonal-Prismatic Nodes: Two-Step Crystal Engineering of Cationic Metal-Organic Materials Schoedel, Alexander; Wojtas, Lukasz; Kelley, Stephen P. Angewandte Chemie International Edition, Vol. 50, Issue 48, p. 11421-11424 https://doi.org/10.1002/anie.201104688	journal	October 2011
Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments Hoskins, Bernard F.; Robson, Richard Journal of the American Chemical Society, Vol. 111, Issue 15 https://doi.org/10.1021/ja00197a079	journal	July 1989
Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design Masoomi, Mohammad Yaser; Morsali, Ali; Dhakshinamoorthy, Amarajothi Angewandte Chemie, Vol. 131, Issue 43 https://doi.org/10.1002/ange.201902229	journal	October 2019
A Transition State Analogue for the Oxidation of Binuclear Palladium(II) to Binuclear Palladium(III) Complexes Powers, David C.; Ritter, Tobias Organometallics, Vol. 32, Issue 7 https://doi.org/10.1021/om4000456	journal	February 2013
Positioning of the HKUST-1 metal–organic framework (Cu ₃ (BTC) ₂ ) through conversion from insoluble Cu-based precursors Toyao, Takashi; Liang, Kang; Okada, Kenji Inorganic Chemistry Frontiers, Vol. 2, Issue 5 https://doi.org/10.1039/C4QI00215F	journal	January 2015
Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks Fidelli, Athena M.; Karadeniz, Bahar; Howarth, Ashlee J. Chemical Communications, Vol. 54, Issue 51 https://doi.org/10.1039/C8CC03189D	journal	January 2018
Guest–Host Complexes of TCNQ and TCNE with Cu ₃ (1,3,5-benzenetricarboxylate) ₂ Usov, Pavel M.; Jiang, Henry; Chevreau, Hubert The Journal of Physical Chemistry C, Vol. 121, Issue 47 https://doi.org/10.1021/acs.jpcc.7b07807	journal	November 2017
Characterization of mechanochemically synthesized MOFs Klimakow, Maria; Klobes, Peter; Rademann, Klaus Microporous and Mesoporous Materials, Vol. 154 https://doi.org/10.1016/j.micromeso.2011.11.039	journal	May 2012
Tetracyanethylen: die charakteristischen Geometrien und Schwingungsabsorptionen seiner zahlreichen Strukturen Miller, Joel S. Angewandte Chemie, Vol. 118, Issue 16 https://doi.org/10.1002/ange.200503277	journal	April 2006
A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline Angewandte Chemie International Edition, Vol. 43, Issue 46 https://doi.org/10.1002/anie.200460592	journal	August 2004
Probing Substrate Diffusion in Interstitial MOF Chemistry with Kinetic Isotope Effects Wang, Chen-Hao; Das, Anuvab; Gao, Wen-Yang Angewandte Chemie, Vol. 130, Issue 14 https://doi.org/10.1002/ange.201713244	journal	March 2018
Synthesis and characterization of bimetallic metal–organic framework Cu–Ru-BTC with HKUST-1 structure Gotthardt, Meike A.; Schoch, Roland; Wolf, Silke Dalton Transactions, Vol. 44, Issue 5 https://doi.org/10.1039/C4DT02491E	journal	January 2015
Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds Huang, Yi-Hao; Lo, Wei-Shang; Kuo, Yun-Wei Chemical Communications, Vol. 53, Issue 43 https://doi.org/10.1039/C7CC03105J	journal	January 2017
Network Diversity through Decoration of Trigonal-Prismatic Nodes: Two-Step Crystal Engineering of Cationic Metal-Organic Materials Schoedel, Alexander; Wojtas, Lukasz; Kelley, Stephen P. Angewandte Chemie, Vol. 123, Issue 48 https://doi.org/10.1002/ange.201104688	journal	October 2011
Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes Jackson, Timothy A.; Rohde, Jan-Uwe; Seo, Mi Sook Journal of the American Chemical Society, Vol. 130, Issue 37 https://doi.org/10.1021/ja8022576	journal	September 2008
Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2 Hoskins, B. F.; Robson, Richard Journal of the American Chemical Society, Vol. 112, Issue 4 https://doi.org/10.1021/ja00160a038	journal	February 1990
Grid-Type Metal Ion Architectures: Functional Metallosupramolecular Arrays Ruben, Mario; Rojo, Javier; Romero-Salguero, Francisco J. Angewandte Chemie International Edition, Vol. 43, Issue 28 https://doi.org/10.1002/anie.200300636	journal	July 2004
A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction Férey, Gérard; Serre, Christian; Mellot-Draznieks, Caroline Angewandte Chemie, Vol. 116, Issue 46, p. 6456-6461 https://doi.org/10.1002/ange.200460592	journal	August 2004
Mechanochemical solvent-free in situ synthesis of drug-loaded {Cu2(1,4-bdc)2(dabco)}n MOFs for controlled drug delivery Nadizadeh, Zahra; Naimi-Jamal, M. Reza; Panahi, Leila Journal of Solid State Chemistry, Vol. 259 https://doi.org/10.1016/j.jssc.2017.12.027	journal	March 2018
Solvothermal growth of a ruthenium metal–organic framework featuring HKUST-1 structure type as thin films on oxide surfaces Kozachuk, Olesia; Yusenko, Kirill; Noei, Heshmat Chemical Communications, Vol. 47, Issue 30 https://doi.org/10.1039/c1cc11107h	journal	January 2011
The asc Trinodal Platform: Two-Step Assembly of Triangular, Tetrahedral, and Trigonal-Prismatic Molecular Building Blocks Schoedel, Alexander; Cairns, Amy J.; Belmabkhout, Youssef Angewandte Chemie, Vol. 125, Issue 10 https://doi.org/10.1002/ange.201206042	journal	February 2013
Role of Thiolate Ligand in Spin State and Redox Switching in the Cytochrome P450 Catalytic Cycle Suzuki, Hiroshi; Inabe, Kanako; Shirakawa, Yoshinori Inorganic Chemistry, Vol. 56, Issue 8 https://doi.org/10.1021/acs.inorgchem.6b02499	journal	March 2017
Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores Chen, Banglin; Eddaoudi, M.; Hyde, S. T. Science, Vol. 291, Issue 5506, p. 1021-1023 https://doi.org/10.1126/science.1056598	journal	February 2001
Tetracyanoethylene (TCNE): The Characteristic Geometries and Vibrational Absorptions of Its Numerous Structures Miller, Joel S. Angewandte Chemie International Edition, Vol. 45, Issue 16 https://doi.org/10.1002/anie.200503277	journal	April 2006
Ligand Substitution Reactions at Inorganic Centers ^† Richens, David T. Chemical Reviews, Vol. 105, Issue 6 https://doi.org/10.1021/cr030705u	journal	June 2005
Mechanochemical synthesis of metal–organic frameworks Chen, Dong; Zhao, Jiahua; Zhang, Pengfei Polyhedron, Vol. 162 https://doi.org/10.1016/j.poly.2019.01.024	journal	April 2019
A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors Prochowicz, D.; Sokołowski, K.; Justyniak, I. Chemical Communications, Vol. 51, Issue 19 https://doi.org/10.1039/C4CC09917F	journal	January 2015
Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design Masoomi, Mohammad Yaser; Morsali, Ali; Dhakshinamoorthy, Amarajothi Angewandte Chemie International Edition, Vol. 58, Issue 43 https://doi.org/10.1002/anie.201902229	journal	October 2019
Rational Synthesis of Mixed-Metal Microporous Metal–Organic Frameworks with Controlled Composition Using Mechanochemistry Ayoub, Ghada; Karadeniz, Bahar; Howarth, Ashlee J. Chemistry of Materials, Vol. 31, Issue 15 https://doi.org/10.1021/acs.chemmater.9b01068	journal	July 2019
Hetero-bimetallic metal–organic polyhedra Teo, Jesse M.; Coghlan, Campbell J.; Evans, Jack D. Chemical Communications, Vol. 52, Issue 2 https://doi.org/10.1039/C5CC08336B	journal	January 2016
Cation-controlled catalysis with crown ether-containing transition metal complexes Yoo, Changho; Dodge, Henry M.; Miller, Alexander J. M. Chemical Communications, Vol. 55, Issue 35 https://doi.org/10.1039/C9CC00803A	journal	January 2019
Hetero-bimetallic paddlewheel clusters in coordination polymers formed by a water-induced single-crystal-to-single-crystal transformation Albalad, Jorge; Aríñez-Soriano, Javier; Vidal-Gancedo, José Chemical Communications, Vol. 52, Issue 91 https://doi.org/10.1039/C6CC07653J	journal	January 2016
Facile Mechanosynthesis of the Archetypal Zn-Based Metal–Organic Frameworks Prochowicz, Daniel; Nawrocki, Jan; Terlecki, Michał Inorganic Chemistry, Vol. 57, Issue 21 https://doi.org/10.1021/acs.inorgchem.8b02026	journal	October 2018
Funktionale poröse Koordinationspolymere Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie, Vol. 116, Issue 18 https://doi.org/10.1002/ange.200300610	journal	April 2004
Mechanochemical synthesis of homo- and hetero-rare-earth(iii) metal–organic frameworks by ball milling Yuan, Wenbing; O'Connor, Jackie; James*, Stuart L. CrystEngComm, Vol. 12, Issue 11 https://doi.org/10.1039/c0ce00216j	journal	January 2010
Spectroscopic study of (two-dimensional) molecule-based magnets: [M ^II (TCNE)(NCMe) ₂ ][SbF ₆ ] (M = Fe, Mn, Ni) Olson, Christopher; Heth, Christopher L.; Lapidus, Saul H. The Journal of Chemical Physics, Vol. 135, Issue 2 https://doi.org/10.1063/1.3599047	journal	July 2011
Study of the mechanochemical formation and resulting properties of an archetypal MOF: Cu3(BTC)2 (BTC = 1,3,5-benzenetricarboxylate) Yuan, Wenbing; Garay, Ana Lazuen; Pichon, Anne CrystEngComm, Vol. 12, Issue 12 https://doi.org/10.1039/c0ce00486c	journal	January 2010
Structural Characterization and Remarkable Axial Ligand Effect on the Nucleophilic Reactivity of a Nonheme Manganese(III)-Peroxo Complex Annaraj, Jamespandi; Cho, Jaeheung; Lee, Yong-Min Angewandte Chemie International Edition, Vol. 48, Issue 23 https://doi.org/10.1002/anie.200900118	journal	May 2009
Liquid-Assisted Mechanochemical Synthesis of Copper Based MOF-505 for the Separation of CO ₂ over CH ₄ or N ₂ Chen, Yongwei; Wu, Houxiao; Liu, Zewei Industrial & Engineering Chemistry Research, Vol. 57, Issue 2 https://doi.org/10.1021/acs.iecr.7b03712	journal	January 2018
Reticular Chemistry—Construction, Properties, and Precision Reactions of Frameworks Yaghi, Omar M. Journal of the American Chemical Society, Vol. 138, Issue 48 https://doi.org/10.1021/jacs.6b11821	journal	November 2016
Mixed-metal metal–organic frameworks Abednatanzi, Sara; Gohari Derakhshandeh, Parviz; Depauw, Hannes Chemical Society Reviews, Vol. 48, Issue 9 https://doi.org/10.1039/C8CS00337H	journal	January 2019
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area Ferey, G.; Mellot-Draznieks, C.; Serre, C. Science, Vol. 309, Issue 5743, p. 2040-2042 https://doi.org/10.1126/science.1116275	journal	September 2005
Network diversity through two-step crystal engineering of a decorated 6-connected primary molecular building block Yang, Qing-Yuan; Chen, Kai-Jie; Schoedel, Alexander CrystEngComm, Vol. 18, Issue 44 https://doi.org/10.1039/C6CE01544A	journal	January 2016
Mechanochemistry: opportunities for new and cleaner synthesis James, Stuart L.; Adams, Christopher J.; Bolm, Carsten Chem. Soc. Rev., Vol. 41, Issue 1 https://doi.org/10.1039/C1CS15171A	journal	January 2012
Rates and Mechanisms of Substitution in Inorganic Complexes in Solution. Taube, Henry Chemical Reviews, Vol. 50, Issue 1 https://doi.org/10.1021/cr60155a003	journal	February 1952
Supramolecular concepts and new techniques in mechanochemistry: cocrystals, cages, rotaxanes, open metal–organic frameworks Friščić, Tomislav Chemical Society Reviews, Vol. 41, Issue 9 https://doi.org/10.1039/c2cs15332g	journal	January 2012
Mechanochemistry for Synthesis Friščić, Tomislav; Mottillo, Cristina; Titi, Hatem M. Angewandte Chemie International Edition, Vol. 59, Issue 3 https://doi.org/10.1002/anie.201906755	journal	January 2020
Controlling the Polymorphism and Topology Transformation in Porphyrinic Zirconium Metal–Organic Frameworks via Mechanochemistry Karadeniz, Bahar; Žilić, Dijana; Huskić, Igor Journal of the American Chemical Society, Vol. 141, Issue 49 https://doi.org/10.1021/jacs.9b10251	journal	November 2019
Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru) Wade, Casey R.; Dincă, Mircea Dalton Transactions, Vol. 41, Issue 26 https://doi.org/10.1039/c2dt30372h	journal	January 2012
Metallopolymerization as a Strategy to Translate Ligand-Modulated Chemoselectivity to Porous Catalysts Gao, Wen-Yang; Ezazi, Andrew A.; Wang, Chen-Hao Organometallics, Vol. 38, Issue 18 https://doi.org/10.1021/acs.organomet.9b00162	journal	May 2019
Inorganic and Bioinorganic Solvent Exchange Mechanisms Helm, Lothar; Merbach, André E. Chemical Reviews, Vol. 105, Issue 6 https://doi.org/10.1021/cr030726o	journal	June 2005
Grand Challenges and Future Opportunities for Metal–Organic Frameworks Hendon, Christopher H.; Rieth, Adam J.; Korzyński, Maciej D. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00197	journal	June 2017
A Family of Porous Lonsdaleite-e Networks Obtained through Pillaring of Decorated Kagomé Lattice Sheets Schoedel, Alexander; Boyette, Wesley; Wojtas, Lukasz Journal of the American Chemical Society, Vol. 135, Issue 38 https://doi.org/10.1021/ja406030p	journal	September 2013
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Direct Characterization of a Reactive Lattice-Confined Ru ₂ Nitride by Photocrystallography Das, Anuvab; Reibenspies, Joseph H.; Chen, Yu-Sheng Journal of the American Chemical Society, Vol. 139, Issue 8 https://doi.org/10.1021/jacs.6b13357	journal	February 2017
Kinetic-Controlled Formation of Bimetallic Metal-Organic Framework Hybrid Structures Guo, Wenhan; Xia, Wei; Cai, Kunting Small, Vol. 13, Issue 41 https://doi.org/10.1002/smll.201702049	journal	September 2017
Measuring and Modulating Substrate Confinement during Nitrogen-Atom Transfer in a Ru ₂ -Based Metal-Organic Framework Wang, Chen-Hao; Gao, Wen-Yang; Powers, David C. Journal of the American Chemical Society, Vol. 141, Issue 49 https://doi.org/10.1021/jacs.9b09620	journal	November 2019
The preparation of an ultrastable mesoporous Cr( iii )-MOF via reductive labilization Lian, Xizhen; Feng, Dawei; Chen, Ying-Pin Chemical Science, Vol. 6, Issue 12 https://doi.org/10.1039/C5SC02587G	journal	January 2015
Mechanochemical Synthesis of Metal−Organic Frameworks: A Fast and Facile Approach toward Quantitative Yields and High Specific Surface Areas Klimakow, Maria; Klobes, Peter; Thünemann, Andreas F. Chemistry of Materials, Vol. 22, Issue 18 https://doi.org/10.1021/cm1012119	journal	September 2010
Ruthenium Metal-Organic Frameworks with Different Defect Types: Influence on Porosity, Sorption, and Catalytic Properties Zhang, Wenhua; Kauer, Max; Halbherr, Olesia Chemistry - A European Journal, Vol. 22, Issue 40 https://doi.org/10.1002/chem.201602641	journal	August 2016

Similar Records

Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Journal Article · Mon Apr 20 00:00:00 EDT 2020 · Angewandte Chemie · OSTI ID:1780803

Gao, Wen‐Yang; Sur, Aishanee; Wang, Chen‐Hao; +7 more

Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

Journal Article · Sun Feb 10 00:00:00 EST 2019 · Coordination Chemistry Reviews · OSTI ID:1780803

Chen, Zhijie; Hanna, Sylvia L.; Redfern, Louis R.; +3 more

Leveraging Exchange Kinetics for the Synthesis of Atomically Precise Porous Catalysts

Journal Article · Wed Jan 20 00:00:00 EST 2021 · ChemCatChem · OSTI ID:1780803

Ezazi, Andrew A.; Gao, Wen‐Yang; Powers, David C.

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
reticular chemistry
mechanochemistry
kinetically inert metal
crystalline materials
primary coordination sphere

Title: Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions via Reticular Mechanopolymerization

Citation Formats

References (70)

Similar Records

Related Subjects