Low flammability electrolytes for stable operation of lithium and sodium ion batteries

Xu, Wu; Chen, Shuru; Zhang, Ji-Guang; Cao, Xia; Jia, Haiping; Liu, Bin; Ren, Xiaodi

Title: Low flammability electrolytes for stable operation of lithium and sodium ion batteries

Patent · Tue Dec 01 00:00:00 EST 2020

OSTI ID:1771695

Xu, Wu; Chen, Shuru; Zhang, Ji-Guang; Cao, Xia; Jia, Haiping; Liu, Bin; Ren, Xiaodi

Low flammability and nonflammable localized superconcentrated electrolytes (LSEs) for stable operation of lithium and sodium ion batteries are disclosed. Electrochemical devices including the low flammability and nonflammable LSEs are also disclosed. The low flammability and nonflammable LSEs include an active salt, a solvent comprising a flame retardant compound, wherein the active salt is soluble in the solvent, and a diluent in which the active salt is insoluble or poorly soluble. The LSE may further include a cosolvent, such as a carbonate, a sulfone, a sulfite, a sulfate, a carboxylate, an ether, a nitrogen-containing solvent, or any combination thereof. In certain embodiments, such as when the solvent and diluent are immiscible, the LSE further includes a bridge solvent.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-05CH11231; AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 10,854,923

Application Number:: 16/119,641

OSTI ID:: 1771695

Resource Relation:: Patent File Date: 08/31/2018

Country of Publication:: United States

Language:: English

References (55)

High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Lithium-Ion Electrolytes Containing Flame-Retardant Additives for Increased Safety Characteristics Smith, Kiah A.; Smart, Marshall C.; Prakash, G. K. Surya ECS Transactions, Vol. 16, Issue 35 https://doi.org/10.1149/1.3123125	journal	August 2009
Secondary Battery; Solar Power Generation System, Wind Power Generation System, and Vehicle Provided Therewith; and Method for Fabrication of a Secondary Battery Watanabe, Yuki; Nishimura, Naoto; Sakashita, Kazuya https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110200855 US Patent Application 13/027631; 20110200855	patent-application	August 2011
Dimethyl methylphosphonate (DMMP) as an efficient flame retardant additive for the lithium-ion battery electrolytes Xiang, H. F.; Xu, H. Y.; Wang, Z. Z. Journal of Power Sources, Vol. 173, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.05.001	journal	November 2007
Ionic Liquid Electrolyte and Fluorinated Carbon Electrode Wijaya, Olivia; Yazami, Rachid https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150364801 US Patent Application 14/761589; 20150364801	patent-application	December 2015
Low Flammability Electrolytes for Stable Operation of Electrochemical Devices Zhang, Ji-Guang; Chen, Shuru; Xu, Wu https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180251681 US Patent Application 15/788188; 20180251681	patent-application	September 2018
Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries Zhang, S. S.; Xu, K.; Jow, T. R. Journal of Power Sources, Vol. 113, Issue 1 https://doi.org/10.1016/S0378-7753(02)00537-2	journal	January 2003
Localized Superconcentrated Electrolytes for Stable Cycling of Electrochemical Devices Zhang, Ji-Guang; Zheng, Jinaming; Chen, Shuru https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180254524 US Patent Application 15/599298; 20180254524	patent-application	September 2018
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
High Salt Concentration Electrolytes For Rechargeable Lithium Battery Tiruvannamalai, Arunkumar; Hwang, Jaehee; Li, Xiaobo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160233549 US Patent Application 15/018579; 20160233549	patent-application	August 2016
Electrochemical performance of lithium-ion batteries with triphenylphosphate as a flame-retardant additive Shim, Eun-Gi; Nam, Tae-Heum; Kim, Jung-Gu Journal of Power Sources, Vol. 172, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.04.088	journal	October 2007
Review—Superconcentrated Electrolytes for Lithium Batteries Yamada, Yuki; Yamada, Atsuo Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0041514jes	journal	January 2015
Electrolyte for Lithium Second Battery, and Lithium Second Battery Comprising the Electrolyte Lee, Yonggun; Yang, Yooseong; Chang, Wonseok https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160294005 US Patent Application 15/089051; 20160294005	patent-application	October 2016
Negative Electrode for Lithium Battery and Lithium Battery Comprisin the Same Lee, Yonggun; Sugimoto, Toshinori; Yang, Yooseong https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160329567 US Patent Application 14/875951; 20160329567	patent-application	November 2016
Flame-retardant additives for lithium-ion batteries Hyung, Yoo E.; Vissers, Donald R.; Amine, Khalil Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00225-8	journal	June 2003
A Novel Flame-Retardant Additive for Lithium Batteries Lee, Chang Woo Electrochemical and Solid-State Letters, Vol. 3, Issue 2 https://doi.org/10.1149/1.1390959	journal	January 1999
The Evaluation of Triphenyl Phosphate as A Flame Retardant Additive to Improve The Safety of Lithium-Ion Battery Electrolytes Smart, Marshall C.; Krause, Frederick C.; Hwang, Constanza ECS Transactions, Vol. 35, Issue 13 https://doi.org/10.1149/1.3646164	journal	April 2011
Electrolyte System for Lithium Metal Secondary Battery and Lithium Metal Secondary Battery Including the Same Cho, Won Il; Kim, Mun Sek; Ryu, Ji Hynn https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20180331393 US Patent Application 15/975016; 20180331393	patent-application	November 2018
Thermal Behavior of Charged Graphite and Li[sub x]CoO[sub 2] in Electrolytes Containing Alkyl Phosphate for Lithium-Ion Cells Shigematsu, Yasuyuki; Ue, Makoto; Yamaki, Jun-ichi Journal of The Electrochemical Society, Vol. 156, Issue 3 https://doi.org/10.1149/1.3056035	journal	January 2009
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
A highly safe battery with a non-flammable triethyl-phosphate-based electrolyte Matsumoto, Kazuaki; Inoue, Kazuhiko; Utsugi, Koji Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.09.086	journal	January 2015
Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate Xu, Kang; Zhang, Shengshui; Allen, Jan L. Journal of The Electrochemical Society, Vol. 149, Issue 8 https://doi.org/10.1149/1.1490356	journal	January 2002
Electrolyte for Electrochemical Energy Storage Devices Rhodes, Christopher P.; Mullings, Matthew E. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160020489 US Patent Application 14/708079; 20160020489	patent-application	January 2016
Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: I. Fundamental Properties Wang, Xianming; Yasukawa, Eiki; Kasuya, Shigeaki Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1397773	journal	January 2001
Nonflammable Trimethyl Phosphate Solvent-Containing Electrolytes for Lithium-Ion Batteries: II. The Use of an Amorphous Carbon Anode Wang, Xianming; Yasukawa, Eiki; Kasuya, Shigeaki Journal of The Electrochemical Society, Vol. 148, Issue 10 https://doi.org/10.1149/1.1397774	journal	January 2001
Solvate Ionic Liquid Electrolyte for Li–S Batteries Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento Journal of The Electrochemical Society, Vol. 160, Issue 8 https://doi.org/10.1149/2.111308jes	journal	January 2013
Fire-extinguishing organic electrolytes for safe batteries Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0033-8	journal	November 2017
High Efficiency Electrolytes for High Voltage Battery Systems Ren, Xiaodi; Xu, Wu; Zhang, Ji-Guang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190140322 US Patent Application 16/230531; 20190140322	patent-application	May 2019
Negative Electrode for Ltihium Metal Battery and Lithium Metal Battery Including the Same Yang, Yooseong; Jeong, Joonseon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160380314 US Patent Application 15/189042; 20160380314	patent-application	December 2016
Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries Shiga, Tohru; Kato, Yuichi; Kondo, Hiroki Journal of Materials Chemistry A, Vol. 5, Issue 10 https://doi.org/10.1039/C6TA09915G	journal	January 2017
Lithium Metal Battery Kim, Youngsoo; Lee, Seoksoo; Yu, Taehwan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170331152 US Patent Application 15/398132; 20170331152	patent-application	November 2017
Electrolyte for a Lithium Ion Battery Halalay, Ion C.; Frisch, Damon R.; Geiculescu, Olt E. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110111308 US Patent Application 12/902120; 20110111308	patent-application	May 2011
Lithium Energy Storage Device Best, Adam Samuel; Lane, George Hamilton https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140125292 US Patent Application 14/064395; 20140125292	patent-application	May 2014
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Dilution of Highly Concentrated LiBF ₄ /Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi _0.5 Mn _1.5 O ₄ Positive Electrodes Doi, Takayuki; Shimizu, Yusuke; Hashinokuchi, Michihiro Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0611701jes	journal	January 2017
Lithium Secondary Batteries Containing Lithium Salt-ionic Liquid Solvent Electrolyte He, Hui; Jang, Bor Z.; Wang, Yanbo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140342249 US Patent Application 13/986576; 20140342249	patent-application	November 2014
Lithium-Ion Electrolytes with Improved Safety Tolerance to High Voltage Systems Smart, Marshall C.; Bugga, Ratnakuma V.; Prakash, Surya G. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120141883 US Patent Application 13/396322; 20120141883	patent-application	June 2012
Nonaqueous Electrolyte Solution and Secondary Battery Using the Electrolyte Solution Yamamoto, Kouhei; Suzuki, Satoru; Yamada, Manabu https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070243470 US Patent Application 11/783961; 20070243470	patent-application	October 2007
Localized Superconcentrated Electrolytes for Silicon Anodes Zhang, Ji-Guang; Jia, Haiping; Li, Xiaolin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190148775 US Patent Application 16/247143; 20190148775	patent-application	May 2019
Flame Retardant Electrolyte for Rechargeable Lithium Battery and Rechargeable Lithium Battery Including the Same Choi, Nam-Soon; Profatilova, Irina; Roh, Sae-Weon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100209782 US Patent Application 12/582668; 20100209782	patent-application	August 2010
Cathode Additive for Rechargeable Sodium Batteries Goodenough, John B.; Park, Kyusung https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170005327 US Patent Application 15/196670; 20170005327	patent-application	January 2017
Low Flammability Electrolytes for Stable Operation of Lithium and Sodium Ion Batteries Xu, Wu; Chen, Shuru; Zhang, Ji-Guang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20190123390 US Patent Application 16/119641; 20190123390	patent-application	April 2019
Electrolyte System for High Voltage Lithium Ion Battery Hwang, Jaehee; Li, Xiaobo; Hu, Qichao https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160248122 US Patent Application 15/049528; 20160248122	patent-application	August 2016
Comparative study of trimethyl phosphite and trimethyl phosphate as electrolyte additives in lithium ion batteries Yao, X. L.; Xie, S.; Chen, C. H. Journal of Power Sources, Vol. 144, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.11.042	journal	June 2005
Tumorigenesis protein Hillman, Jennifer L.; Goli, Surya K. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5830660 US Patent Document 5,830,660	patent	November 1998
High Coulombic Efficiency Cycling of Metal Batteries Zhang, Ji-Guang; Adams, Brian D. G.; Xu, Wu https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160240896 US Patent Application 15/142322; 20160240896	patent-application	August 2016
Lithium Metal Battery Kim, Jusik; Kim, Hyunseok; Ryu, Saebom https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20170098858 US Patent Application 15/221743; 20170098858	patent-application	April 2017
Electrolyte Structure for Metal Batteries Cai, Mei; Lu, Yunfeng; Yang, Li https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160254567 US Patent Application 15/055306; 20160254567	patent-application	September 2016
Alkali metal/niobium triselenide cell having a dioxolane-based electrolyte Whittingham, M. Stanley; Newman, Gerald H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4086403 US Patent Document 4,086,403	patent	April 1978
An Attempt to Formulate Nonflammable Lithium Ion Electrolytes with Alkyl Phosphates and Phosphazenes Xu, Kang; Ding, Michael S.; Zhang, Shengshui Journal of The Electrochemical Society, Vol. 149, Issue 5 https://doi.org/10.1149/1.1467946	journal	January 2002
Flame retardant battery Tsukamoto, Hisashi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8815453 US Patent Document 8,815,453	patent	August 2014
Superconcentrated electrolytes for a high-voltage lithium-ion battery Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12032	journal	June 2016
Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode Ding, Fei; Xu, Wu; Chen, Xilin Journal of The Electrochemical Society, Vol. 160, Issue 10 https://doi.org/10.1149/2.100310jes	journal	January 2013
Methylene ethylene carbonate: Novel additive to improve the high temperature performance of lithium ion batteries Chalasani, Dinesh; Li, Jing; Jackson, Nicole M. Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.004	journal	June 2012

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