Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

Bunquin, Jeffrey Camacho; Ferrandon, Magali S.

Title: Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

Abstract

A catalyst for oxidative dehydrogenation of alkanes includes a substrate including an oxide; at least one promoter including a transition metal or a main group element of the periodic table; and an oxidation-active transition metal. The catalyst is multimetallic.

Inventors:: Bunquin, Jeffrey Camacho; Ferrandon, Magali S.

Publication Date:: Tue Nov 10 00:00:00 EST 2020

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1771598

Patent Number(s):: 10,828,621

Application Number:: 15/688,699

Assignee:: UChicago Argonne, LLC (Chicago, IL)

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 08/28/2017

Country of Publication:: United States

Language:: English

Citation Formats


                    Bunquin, Jeffrey Camacho, and Ferrandon, Magali S. Supported multimetallic catalysts for oxidative dehydrogenation of alkanes.  United States: N. p., 2020. 
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                    Bunquin, Jeffrey Camacho, & Ferrandon, Magali S. Supported multimetallic catalysts for oxidative dehydrogenation of alkanes.  United States.

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                    Bunquin, Jeffrey Camacho, and Ferrandon, Magali S. 2020.  
        "Supported multimetallic catalysts for oxidative dehydrogenation of alkanes".  United States.  https://www.osti.gov/servlets/purl/1771598.

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@article{osti_1771598,

  title        = {Supported multimetallic catalysts for oxidative dehydrogenation of alkanes},

  author       = {Bunquin, Jeffrey Camacho and Ferrandon, Magali S.},

  abstractNote = {A catalyst for oxidative dehydrogenation of alkanes includes a substrate including an oxide; at least one promoter including a transition metal or a main group element of the periodic table; and an oxidation-active transition metal. The catalyst is multimetallic.},

  doi          = {},

  url          = {https://www.osti.gov/biblio/1771598},
  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Nov 10 00:00:00 EST 2020},

  month        = {Tue Nov 10 00:00:00 EST 2020}

}

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Title: Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

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Citation Formats

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Propane Oxydehydrogenation over Molybdate-Based Catalysts journal, April 1997

n-Butane dehydrogenation over mono and bimetallic MCM-41 catalysts under oxygen free atmosphere journal, April 2013

Butane dehydrogenation on vanadium supported catalysts under oxygen free atmosphere journal, September 2004

Butane Dehydrogenation Reaction on Sulfur Poisoned Group 10 Metal/SiO 2 Catalysts journal, October 1996

Effect of Sn Addition on n-Butane Dehydrogenation over Alumina-supported Pt Catalysts Prepared by Co-impregnation and Sol-gel Methods journal, January 2012

Improved performance of carbon nanofiber-supported palladium particles in the selective 1,3-butadiene hydrogenation: Influence of carbon nanostructure, support functionalization treatment and metal precursor journal, July 2015

Catalyst for converting paraffinic hydrocarbon into corresponding olefin patent, July 2002

Influence of toluene on the catalytic activity of NiPdCe catalyst for selective hydrogenation of 1,3-butadiene journal, August 2013

n-Butane dehydrogenation over Pt/Mg(In)(Al)O journal, January 2014

Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties journal, January 2013

Selective Alkane Oxidation by Manganese Oxide: Site Isolation of MnO x Chains at the Surface of MnWO 4 Nanorods journal, February 2016

Dehydrogenation catalyst composition patent, June 2004

A theoretical view of 1,3-butadiene selective hydrogenation toward cis-2-butene on PdNi layered catalyst journal, October 2015

Dehydrogenation and Isomerization of Butane over Cr Catalysts Supported on H-SSZ-35 Type Zeolites journal, February 2004

Supported Catalyst for Direct Dehydrogenation of n-Butane and Preparing Method of Butenes from n-Butane Using the Same patent-application, March 2013

Fixed bed reactor for gas-phase catalytic oxidation and processes for producing acrolein or acrylic acid patent-application, October 2006

Single-Atom Pd 1 /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene journal, August 2015

Method for the production of butadiene from n-butane patent, April 2006

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit journal, October 2015

Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts journal, December 2007

Effect of the Synthesis Method of MgAl 2 O 4 and of Sn and Pb Addition to Platinum Catalysts on the Behavior in n -Butane Dehydrogenation journal, March 2010

Selective hydrogenation of 1,3-butadiene on Pt3Sn(111) alloys: comparison to Pt(111) journal, January 2005

Preparation Method of Platinum/Tin/Alumina Catalyst for Direct Dehydrogenation of n-Butane and Method for Producing C4 Olefins Using Said Catalyst patent-application, October 2014

Effects of Feed Compositions on Oxidative Dehydrogenation of Propane over Mn−P−O Catalyst journal, January 2005

Catalytic performance and stability of isomorphic molybdates used for the oxidative dehydrogenation of propane journal, May 2005

Catalyst and systems incorporating the catalyst patent, July 2011

Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina journal, April 2011

Use of Al2O3–SnO2 as a support of Pt for selective dehydrogenation of light paraffins journal, April 2008

Atmospheric pressure studies of selective 1,3-butadiene hydrogenation on well-defined Pd/Al2O3/NiAl(110) model catalysts: Effect of Pd particle size journal, May 2006

Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al2O3 journal, January 2008

n-Butane Dehydrogenation on PtSn/Carbon Modified MgO Catalysts journal, April 2013

Pd–Au single-crystal surfaces: Segregation properties and catalytic activity in the selective hydrogenation of 1,3-butadiene journal, November 2005

Catalytic reactor patent, February 1977

Effect of oxide supports on Pd–Ni bimetallic catalysts for 1,3-butadiene hydrogenation journal, January 2015

Pd Cluster Nanowires as Highly Efficient Catalysts for Selective Hydrogenation Reactions journal, January 2012

Selective and stable bimetallic PtSn/θ-Al2O3 catalyst for dehydrogenation of n-butane to n-butenes journal, October 2013

Preparation of nanostructured Pd particles using a seeding synthesis approach—Application to the selective hydrogenation of buta-1,3-diene journal, July 2007

Propane oxydehydrogenation over alumina-supported vanadia doped with manganese and potassium journal, May 2000

Oxidative dehydrogenation of propane over monoliths at short contact times journal, August 2000

Spatially controlled atomic layer deposition in porous materials patent, November 2012

Catalytic Dehydrogenation Process patent, November 1970

Catalysis by Gold: Isolated Surface Au3+ Ions are Active Sites for Selective Hydrogenation of 1,3-Butadiene over Au/ZrO2 Catalysts journal, November 2005

Dehydrogenation of hydrocarbons with zinc titanate catalyst patent, November 1979

Behavior of PtPb/MgAl2O4 catalysts with different Pb contents and trimetallic PtPbIn catalysts in n-butane dehydrogenation journal, November 2013

Alumina- and Zirconia−Alumina-Loaded Tin−Platinum. Surface Features and Performance for Butane Dehydrogenation journal, December 2000

Characterization of Mo-MnO catalyst for propane oxidative dehydrogenation journal, July 2002

Selective hydrogenation of 1,3-butadiene on TiO2-modified Pd/SiO2 catalysts journal, May 2003

Paraffin dehydrogenation using platinum-tin promoted zinc aluminate catalyst and silica-free particles patent, August 1977

Stable and selective dehydrogenation catalyst and a process for the preparation thereof patent, October 2003

Precisely Controlled Porous Alumina Overcoating on Pd Catalyst by Atomic Layer Deposition: Enhanced Selectivity and Durability in Hydrogenation of 1,3-Butadiene journal, March 2015

Direct dehydrogenation of n-butane over Pt/Sn/M/γ-Al2O3 catalysts: Effect of third metal (M) addition journal, March 2014

Support for gas-phase oxidation catalyst and process for its production, gas-phase oxidation catalyst, and process for producing acrylic acid patent, November 2008

Platinum-Tin Nano-Catalysts Supported on Alumina for Direct Dehydrogenation of n -Butane journal, October 2015

n-Butane Dehydrogenation on PtSn Supported on MAl 2 O 4 (M: Mg or Zn) Catalysts journal, July 2004

Direct Dehydrogenation of n -Butane Over Pt/Sn/Zn/ γ -Al 2 O 3 Nano-Catalyst: Effect of Zn Content journal, October 2015

Single Gold Atoms in Heterogeneous Catalysis: Selective 1,3-Butadiene Hydrogenation over Au/ZrO2 journal, October 2006

Selective hydrogenation of mixed C4 containing high vinyl acetylene by Mn-Pd, Ni-Pd and Ag-Pd on Al2O3 catalysts journal, November 2015

Strained Pd overlayers on Ni nanoparticles supported on alumina and catalytic activity for buta-1,3-diene selective hydrogenation journal, January 2007

Process for the Selective Conversion of Alkanes to Unsaturated Carboxylic Acids patent-application, January 2006

Selective hydrogenation of 1,3-butadiene on PdNi bimetallic catalyst: From model surfaces to supported catalysts journal, July 2014

Dehydrogenation of n-Butane to Butadiene over Pt–Sn/MgO–Al2O3 journal, January 2012

UV Raman spectroscopic studies of V/θ-Al2O3 catalysts in butane dehydrogenation journal, January 2006

Selective hydrogenation of 1,3-butadiene in mixture with isobutene on a Pd/α-alumina catalyst in a semi-batch reactor journal, September 2007

Hydrogenation of 1,3-butadiene over Au and Pt/SiO2-N catalysts at low temperature journal, July 2015

Catalyst material, the preparation thereof and the use thereof in converting hydrocarbons patent, February 2001

Kinetics and mechanism of the oxidative dehydrogenation of isobutane on cobalt, nickel, and manganese molybdates
journal, March 2007

Tuning catalytic reactivity on metal surfaces: Insights from DFT
journal, December 2013

Propane oxydehydrogenation over transition metal modified zeolite ZSM-5
journal, April 2003

Cu, Mn and Co molybdates derived from novel precursors catalyze the oxidative dehydrogenation of propane
journal, October 2005

Pd–Sn/Al2O3 catalysts from colloidal oxide synthesis II. Surface characterization and catalytic properties for buta-1,3-diene selective hydrogenation
journal, September 2003

Comparative study of Au/ZrO2 catalysts in CO oxidation and 1,3-butadiene hydrogenation
journal, April 2007

Propane Oxydehydrogenation over Molybdate-Based Catalysts
journal, April 1997

n-Butane dehydrogenation over mono and bimetallic MCM-41 catalysts under oxygen free atmosphere
journal, April 2013

Butane dehydrogenation on vanadium supported catalysts under oxygen free atmosphere
journal, September 2004

Butane Dehydrogenation Reaction on Sulfur Poisoned Group 10 Metal/SiO ₂ Catalysts
journal, October 1996

Effect of Sn Addition on n-Butane Dehydrogenation over Alumina-supported Pt Catalysts Prepared by Co-impregnation and Sol-gel Methods
journal, January 2012

Improved performance of carbon nanofiber-supported palladium particles in the selective 1,3-butadiene hydrogenation: Influence of carbon nanostructure, support functionalization treatment and metal precursor
journal, July 2015

Catalyst for converting paraffinic hydrocarbon into corresponding olefin
patent, July 2002

Influence of toluene on the catalytic activity of NiPdCe catalyst for selective hydrogenation of 1,3-butadiene
journal, August 2013

n-Butane dehydrogenation over Pt/Mg(In)(Al)O
journal, January 2014

Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties
journal, January 2013

Selective Alkane Oxidation by Manganese Oxide: Site Isolation of MnO _x Chains at the Surface of MnWO ₄ Nanorods
journal, February 2016

Dehydrogenation catalyst composition
patent, June 2004

A theoretical view of 1,3-butadiene selective hydrogenation toward cis-2-butene on PdNi layered catalyst
journal, October 2015

Dehydrogenation and Isomerization of Butane over Cr Catalysts Supported on H-SSZ-35 Type Zeolites
journal, February 2004

Supported Catalyst for Direct Dehydrogenation of n-Butane and Preparing Method of Butenes from n-Butane Using the Same
patent-application, March 2013

Fixed bed reactor for gas-phase catalytic oxidation and processes for producing acrolein or acrylic acid
patent-application, October 2006

Single-Atom Pd ₁ /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
journal, August 2015

Method for the production of butadiene from n-butane
patent, April 2006

Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit
journal, October 2015

Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts
journal, December 2007

Effect of the Synthesis Method of MgAl ₂ O ₄ and of Sn and Pb Addition to Platinum Catalysts on the Behavior in n -Butane Dehydrogenation
journal, March 2010

Selective hydrogenation of 1,3-butadiene on Pt3Sn(111) alloys: comparison to Pt(111)
journal, January 2005

Preparation Method of Platinum/Tin/Alumina Catalyst for Direct Dehydrogenation of n-Butane and Method for Producing C4 Olefins Using Said Catalyst
patent-application, October 2014

Effects of Feed Compositions on Oxidative Dehydrogenation of Propane over Mn−P−O Catalyst
journal, January 2005

Catalytic performance and stability of isomorphic molybdates used for the oxidative dehydrogenation of propane
journal, May 2005

Catalyst and systems incorporating the catalyst
patent, July 2011

Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina
journal, April 2011

Use of Al2O3–SnO2 as a support of Pt for selective dehydrogenation of light paraffins
journal, April 2008

Atmospheric pressure studies of selective 1,3-butadiene hydrogenation on well-defined Pd/Al2O3/NiAl(110) model catalysts: Effect of Pd particle size
journal, May 2006

Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al2O3
journal, January 2008

n-Butane Dehydrogenation on PtSn/Carbon Modified MgO Catalysts
journal, April 2013

Pd–Au single-crystal surfaces: Segregation properties and catalytic activity in the selective hydrogenation of 1,3-butadiene
journal, November 2005

Catalytic reactor
patent, February 1977

Effect of oxide supports on Pd–Ni bimetallic catalysts for 1,3-butadiene hydrogenation
journal, January 2015

Pd Cluster Nanowires as Highly Efficient Catalysts for Selective Hydrogenation Reactions
journal, January 2012

Selective and stable bimetallic PtSn/θ-Al2O3 catalyst for dehydrogenation of n-butane to n-butenes
journal, October 2013

Preparation of nanostructured Pd particles using a seeding synthesis approach—Application to the selective hydrogenation of buta-1,3-diene
journal, July 2007

Propane oxydehydrogenation over alumina-supported vanadia doped with manganese and potassium
journal, May 2000

Oxidative dehydrogenation of propane over monoliths at short contact times
journal, August 2000

Spatially controlled atomic layer deposition in porous materials
patent, November 2012

Catalytic Dehydrogenation Process
patent, November 1970

Catalysis by Gold: Isolated Surface Au3+ Ions are Active Sites for Selective Hydrogenation of 1,3-Butadiene over Au/ZrO2 Catalysts
journal, November 2005

Dehydrogenation of hydrocarbons with zinc titanate catalyst
patent, November 1979

Behavior of PtPb/MgAl2O4 catalysts with different Pb contents and trimetallic PtPbIn catalysts in n-butane dehydrogenation
journal, November 2013

Alumina- and Zirconia−Alumina-Loaded Tin−Platinum. Surface Features and Performance for Butane Dehydrogenation
journal, December 2000

Characterization of Mo-MnO catalyst for propane oxidative dehydrogenation
journal, July 2002

Selective hydrogenation of 1,3-butadiene on TiO2-modified Pd/SiO2 catalysts
journal, May 2003

Paraffin dehydrogenation using platinum-tin promoted zinc aluminate catalyst and silica-free particles
patent, August 1977

Stable and selective dehydrogenation catalyst and a process for the preparation thereof
patent, October 2003

Precisely Controlled Porous Alumina Overcoating on Pd Catalyst by Atomic Layer Deposition: Enhanced Selectivity and Durability in Hydrogenation of 1,3-Butadiene
journal, March 2015

Direct dehydrogenation of n-butane over Pt/Sn/M/γ-Al2O3 catalysts: Effect of third metal (M) addition
journal, March 2014

Support for gas-phase oxidation catalyst and process for its production, gas-phase oxidation catalyst, and process for producing acrylic acid
patent, November 2008

Platinum-Tin Nano-Catalysts Supported on Alumina for Direct Dehydrogenation of n -Butane
journal, October 2015

n-Butane Dehydrogenation on PtSn Supported on MAl ₂ O ₄ (M: Mg or Zn) Catalysts
journal, July 2004

Direct Dehydrogenation of n -Butane Over Pt/Sn/Zn/ γ -Al ₂ O ₃ Nano-Catalyst: Effect of Zn Content
journal, October 2015

Single Gold Atoms in Heterogeneous Catalysis: Selective 1,3-Butadiene Hydrogenation over Au/ZrO2
journal, October 2006

Selective hydrogenation of mixed C4 containing high vinyl acetylene by Mn-Pd, Ni-Pd and Ag-Pd on Al2O3 catalysts
journal, November 2015

Strained Pd overlayers on Ni nanoparticles supported on alumina and catalytic activity for buta-1,3-diene selective hydrogenation
journal, January 2007

Process for the Selective Conversion of Alkanes to Unsaturated Carboxylic Acids
patent-application, January 2006

Selective hydrogenation of 1,3-butadiene on PdNi bimetallic catalyst: From model surfaces to supported catalysts
journal, July 2014

Dehydrogenation of n-Butane to Butadiene over Pt–Sn/MgO–Al₂O₃
journal, January 2012

UV Raman spectroscopic studies of V/θ-Al2O3 catalysts in butane dehydrogenation
journal, January 2006

Selective hydrogenation of 1,3-butadiene in mixture with isobutene on a Pd/α-alumina catalyst in a semi-batch reactor
journal, September 2007

Hydrogenation of 1,3-butadiene over Au and Pt/SiO2-N catalysts at low temperature
journal, July 2015

Catalyst material, the preparation thereof and the use thereof in converting hydrocarbons
patent, February 2001