Nanoscale Mg–B via Surfactant Ball Milling of MgB2: Morphology, Composition, and Improved Hydrogen Storage Properties

Liu, Y. -S.; Ray, K. G.; Jørgensen, M.; Mattox, T. M.; Cowgill, D. F.; Eshelman, H. V.; Sawvel, A. M.; Snider, J. L.; York, W.; Wijeratne, P.; Pham, A. L.; Gunda, H.; Li, S.; Heo, T. W.; Kang, S.; Jensen, T. R.; Stavila, V.; Wood, B. C.; Klebanoff, L. E.

doi:10.1021/acs.jpcc.0c05142

Title: Nanoscale Mg–B via Surfactant Ball Milling of MgB₂: Morphology, Composition, and Improved Hydrogen Storage Properties

Journal Article · Fri Sep 04 00:00:00 EDT 2020 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.0c05142· OSTI ID:1670751

^[1]; Ray, K. G. ^[2]; Jørgensen, M. ^[3]; Mattox, T. M. ^[4]; Cowgill, D. F. ^[5]; Eshelman, H. V. ^[2];

^[2]; Snider, J. L. ^[5]; York, W. ^[5]; Wijeratne, P. ^[5]; Pham, A. L. ^[4]; Gunda, H. ^[6];

^[2];

^[2]; Kang, S. ^[2];

^[3];

^[5];

^[2];

^[5]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Aarhus Univ. (Denmark)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Indian Inst. of Technology (IIT), Gandhinagar (India)

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC04-94AL85000; AC52-07NA27344

OSTI ID:: 1670751

Alternate ID(s):: OSTI ID: 1811217

Report Number(s):: SAND-2020-4788J; LLNL-JRNL-809578; 685921

Journal Information:: Journal of Physical Chemistry. C, Vol. 124, Issue 39; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (54)

Potential enhancement of superconductivity in MgB2 nanosheets: First-principles calculations Ao, Bingyun; Zhang, Zhengjun; Tang, Tao Chemical Physics Letters, Vol. 591 https://doi.org/10.1016/j.cplett.2013.11.045	journal	January 2014
Superconductivity at 39 K in magnesium diboride Nagamatsu, Jun; Nakagawa, Norimasa; Muranaka, Takahiro Nature, Vol. 410, Issue 6824 https://doi.org/10.1038/35065039	journal	March 2001
Three-Coordinated Boron-11 Chemical Shifts in Borates Kroeker, Scott; Stebbins, Jonathan F. Inorganic Chemistry, Vol. 40, Issue 24 https://doi.org/10.1021/ic010305u	journal	November 2001
Core level photoemission study of polycrystalline MgB2 Garg, K. B.; Chatterji, T.; Dalela, S. Solid State Communications, Vol. 131, Issue 5 https://doi.org/10.1016/j.ssc.2004.01.006	journal	August 2004
Air-stable, unoxidized, hydrocarbon-dispersible boron nanoparticles Van Devener, Brian; Perez, Jesus Paulo L.; Anderson, Scott L. Journal of Materials Research, Vol. 24, Issue 11 https://doi.org/10.1557/jmr.2009.0412	journal	November 2009
Nanostructured Metal Hydrides for Hydrogen Storage Schneemann, Andreas; White, James L.; Kang, ShinYoung Chemical Reviews, Vol. 118, Issue 22 https://doi.org/10.1021/acs.chemrev.8b00313	journal	October 2018
Investigating possible kinetic limitations to MgB2 hydrogenation Liu, Y. -S.; Klebanoff, L. E.; Wijeratne, P. International Journal of Hydrogen Energy, Vol. 44, Issue 59 https://doi.org/10.1016/j.ijhydene.2019.09.125	journal	November 2019
Recent progress in magnesium borohydride Mg(BH4)2: Fundamentals and applications for energy storage Zavorotynska, Olena; El-Kharbachi, Abdelouahab; Deledda, Stefano International Journal of Hydrogen Energy, Vol. 41, Issue 32 https://doi.org/10.1016/j.ijhydene.2016.02.015	journal	August 2016
Synthesis and Characterization of NIR Luminescent LaF₃:Ln³⁺ Nanoparticles and their Transparent Epoxy Nanocomposites Nampoothiri, Pramod K.; Gandhi, Mayuri N.; Kulkarni, A. R. Advanced Materials Research, Vol. 748 https://doi.org/10.4028/www.scientific.net/amr.748.101	journal	August 2013
Synthesis of amorphous Mg(BH4)2 from MgB2 and H2 at room temperature Pistidda, Claudio; Garroni, Sebastiano; Dolci, Francesco Journal of Alloys and Compounds, Vol. 508, Issue 1 https://doi.org/10.1016/j.jallcom.2010.07.226	journal	October 2010
Kinetic Enhancement of Direct Hydrogenation of MgB ₂ to Mg(BH ₄ ) ₂ upon Mechanical Milling with THF, MgH ₂ , and/or Mg Sugai, Cody; Kim, Stephen; Severa, Godwin ChemPhysChem, Vol. 20, Issue 10 https://doi.org/10.1002/cphc.201801187	journal	March 2019
FTIR study of surfactant bonding to FePt nanoparticles Shukla, Nisha; Liu, Chao; Jones, Paul M. Journal of Magnetism and Magnetic Materials, Vol. 266, Issue 1-2 https://doi.org/10.1016/s0304-8853(03)00469-4	journal	October 2003
Photoabsorption and photoemission of magnesium diboride at the Mg K edge Prince, K. C.; Feyer, V.; Tadich, A. Journal of Physics: Condensed Matter, Vol. 21, Issue 40 https://doi.org/10.1088/0953-8984/21/40/405701	journal	September 2009
XPS O 1s binding energies for polymers containing hydroxyl, ether, ketone and ester groups López, Gabriel P.; Castner, David G.; Ratner, Buddy D. Surface and Interface Analysis, Vol. 17, Issue 5 https://doi.org/10.1002/sia.740170508	journal	May 1991
Polymorphism of Two-Dimensional Boron Penev, Evgeni S.; Bhowmick, Somnath; Sadrzadeh, Arta Nano Letters, Vol. 12, Issue 5 https://doi.org/10.1021/nl3004754	journal	April 2012
Preparation of Nd–Fe–B nanoparticles by surfactant-assisted ball milling technique Yue, M.; Wang, Y. P.; Poudyal, N. Journal of Applied Physics, Vol. 105, Issue 7 https://doi.org/10.1063/1.3059228	journal	April 2009
Nanoscaled Metal Borides and Phosphides: Recent Developments and Perspectives Carenco, Sophie; Portehault, David; Boissière, Cédric Chemical Reviews, Vol. 113, Issue 10, p. 7981-8065 https://doi.org/10.1021/cr400020d	journal	June 2013
Understanding and Mitigating the Effects of Stable Dodecahydro- closo -dodecaborate Intermediates on Hydrogen-Storage Reactions White, James L.; Newhouse, Rebecca J.; Zhang, Jin Z. The Journal of Physical Chemistry C, Vol. 120, Issue 45 https://doi.org/10.1021/acs.jpcc.6b09789	journal	November 2016
NMR Confirmation for Formation of [B ₁₂ H ₁₂ ] ^2- Complexes during Hydrogen Desorption from Metal Borohydrides Hwang, Son-Jong; Bowman, Robert C.; Reiter, Joseph W. The Journal of Physical Chemistry C, Vol. 112, Issue 9 https://doi.org/10.1021/jp710894t	journal	March 2008
X-ray photoemission study of ${MgB}_{2}$ Vasquez, R. P.; Jung, C. U.; Park, Min-Seok Physical Review B, Vol. 64, Issue 5 https://doi.org/10.1103/physrevb.64.052510	journal	July 2001
The kinetic properties of Mg(BH ₄ ) ₂ infiltrated in activated carbon Fichtner, Maximilian; Zhao-Karger, Zhirong; Hu, Jianjiang Nanotechnology, Vol. 20, Issue 20 https://doi.org/10.1088/0957-4484/20/20/204029	journal	April 2009
Sm–Co hard magnetic nanoparticles prepared by surfactant-assisted ball milling Wang, Yiping; Li, Yang; Rong, Chuanbing Nanotechnology, Vol. 18, Issue 46 https://doi.org/10.1088/0957-4484/18/46/465701	journal	October 2007
Oxide-Free, Catalyst-Coated, Fuel-Soluble, Air-Stable Boron Nanopowder as Combined Combustion Catalyst and High Energy Density Fuel Van Devener, Brian; Perez, Jesus Paulo L.; Jankovich, Joseph Energy & Fuels, Vol. 23, Issue 12 https://doi.org/10.1021/ef900765h	journal	December 2009
Quantum confinement induced band gaps in MgB ₂ nanosheets Xu, Bo Z.; Beckman, Scott P. 2D Materials, Vol. 3, Issue 3 https://doi.org/10.1088/2053-1583/3/3/031003	journal	July 2016
Nd3+ sensitized Yb3+ luminescence in oleic acid functionalized LaF3: Nd3+Yb3+ nanoparticles Nampoothiri, Pramod K. Advanced Materials Proceedings, Vol. 2, Issue 5 https://doi.org/10.5185/amp.2017/502	journal	May 2017
Enhanced hydrogen desorption from Mg(BH4)2 by combining nanoconfinement and a Ni catalyst Wahab, M. Abdul; Jia, Yi (Alec); Yang, Dongjiang Journal of Materials Chemistry A, Vol. 1, Issue 10 https://doi.org/10.1039/c2ta00899h	journal	January 2013
Formation Mechanism of Boron-Based Nanosheet through the Reaction of MgB ₂ with Water Nishino, Hiroaki; Fujita, Takeshi; Yamamoto, Akiyasu The Journal of Physical Chemistry C, Vol. 121, Issue 19 https://doi.org/10.1021/acs.jpcc.7b02348	journal	May 2017
p H-dependent x-ray absorption spectra of aqueous boron oxides Duffin, Andrew M.; Schwartz, Craig P.; England, Alice H. The Journal of Chemical Physics, Vol. 134, Issue 15 https://doi.org/10.1063/1.3574838	journal	April 2011
Simple, Green, and High‐Yield Production of Boron‐Based Nanostructures with Diverse Morphologies by Dissolution and Recrystallization of Layered Magnesium Diboride Crystals in Water Gunda, Harini; Das, Saroj Kumar; Jasuja, Kabeer ChemPhysChem, Vol. 19, Issue 7 https://doi.org/10.1002/cphc.201701033	journal	February 2018
Hydroxylation of the surface of PbS nanocrystals passivated with oleic acid Zherebetskyy, D.; Scheele, M.; Zhang, Y. Science, Vol. 344, Issue 6190 https://doi.org/10.1126/science.1252727	journal	May 2014
Multispectroscopic (FTIR, XPS, and TOFMS−TPD) Investigation of the Core−Shell Bonding in Sonochemically Prepared Aluminum Nanoparticles Capped with Oleic Acid Lewis, William K.; Rosenberger, Andrew T.; Gord, Joseph R. The Journal of Physical Chemistry C, Vol. 114, Issue 14 https://doi.org/10.1021/jp100274j	journal	March 2010
Large-Scale Exfoliation of Inorganic Layered Compounds in Aqueous Surfactant Solutions Smith, Ronan J.; King, Paul J.; Lotya, Mustafa Advanced Materials, Vol. 23, Issue 34 https://doi.org/10.1002/adma.201102584	journal	July 2011
The indirect to direct band gap transition in multilayered MoS ₂ as predicted by screened hybrid density functional theory Ellis, Jason K.; Lucero, Melissa J.; Scuseria, Gustavo E. Applied Physics Letters, Vol. 99, Issue 26 https://doi.org/10.1063/1.3672219	journal	December 2011
Analysis of the Interaction of Surfactants Oleic Acid and Oleylamine with Iron Oxide Nanoparticles through Molecular Mechanics Modeling Harris, Richard Anthony; Shumbula, Poslet Morgan; van der Walt, Hendriëtte Langmuir, Vol. 31, Issue 13 https://doi.org/10.1021/acs.langmuir.5b00671	journal	March 2015
Formation and Characterization of Hydrogen Boride Sheets Derived from MgB ₂ by Cation Exchange Nishino, Hiroaki; Fujita, Takeshi; Cuong, Nguyen Thanh Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b06153	journal	September 2017
Ab Initio Study of the Electronic, Vibrational, and Mechanical Properties of the Magnesium Diboride Monolayer Pešić, Jelena; Popov, Igor; Šolajić, Andrijana Condensed Matter, Vol. 4, Issue 2 https://doi.org/10.3390/condmat4020037	journal	April 2019
FT-IR Characterization of Metal Acetates in Aqueous Solution Tackett, James E. Applied Spectroscopy, Vol. 43, Issue 3 https://doi.org/10.1366/0003702894202931	journal	March 1989
X-ray photoemission spectroscopy of nonmetallic materials: Electronic structures of boron and BxOy Ong, C. W.; Huang, H.; Zheng, B. Journal of Applied Physics, Vol. 95, Issue 7 https://doi.org/10.1063/1.1651321	journal	April 2004
Short and Medium Range Order in Sodium Aluminoborate Glasses. 2. Site Connectivities and Cation Distributions Studied by Rotational Echo Double Resonance NMR Spectroscopy Bertmer, Marko; Züchner, Lars; Chan, Jerry C. C. The Journal of Physical Chemistry B, Vol. 104, Issue 28 https://doi.org/10.1021/jp9941918	journal	July 2000
Thermodynamic and Kinetic Characterization of Hydrogen−Deuterium Exchange in β-Phase Palladium Luo, Weifang; Cowgill, Donald F.; Causey, Rion A. The Journal of Physical Chemistry B, Vol. 113, Issue 39 https://doi.org/10.1021/jp903633b	journal	September 2009
Oleylamine in Nanoparticle Synthesis Mourdikoudis, Stefanos; Liz-Marzán, Luis M. Chemistry of Materials, Vol. 25, Issue 9 https://doi.org/10.1021/cm4000476	journal	February 2013
Mechanical milling of metal sulfide particles and their catalytic activity—hydrogenation of 1-methylnaphthalene with molybdenum sulfide Kuriki, Yasunori; Uchida, Kunio; Sekreta, Ellen Fuel Processing Technology, Vol. 59, Issue 2-3 https://doi.org/10.1016/s0378-3820(99)00019-3	journal	May 1999
Magnesium borohydride as a hydrogen storage material: Properties and dehydrogenation pathway of unsolvated Mg(BH₄)₂ Soloveichik, G.; Gao, Y.; Rijssenbeek, J. International Journal of Hydrogen Energy, Vol. 34, Issue 2, p. 916-928 https://doi.org/10.1016/j.ijhydene.2008.11.016	journal	January 2009
Large-scale production of two-dimensional nanosheets Yao, Yagang; Lin, Ziyin; Li, Zhuo Journal of Materials Chemistry, Vol. 22, Issue 27 https://doi.org/10.1039/c2jm30587a	journal	January 2012
Enhancement of the hydrogen release of Mg(BH4)2 by concomitant effects of nano-confinement and catalysis Clémençon, D.; Davoisne, C.; Chotard, J. -N. International Journal of Hydrogen Energy, Vol. 44, Issue 8 https://doi.org/10.1016/j.ijhydene.2018.12.143	journal	February 2019
Degradation behavior of MgB2 superconductor Aswal, D. K.; Muthe, K. P.; Singh, Ajay Physica C: Superconductivity, Vol. 363, Issue 3 https://doi.org/10.1016/s0921-4534(01)00974-1	journal	November 2001
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki Nature Chemistry, Vol. 5, Issue 4, p. 263-275 https://doi.org/10.1038/nchem.1589	journal	April 2013
Reversible Storage of Hydrogen in Destabilized LiBH ₄ Vajo, John J.; Skeith, Sky L.; Mertens, Florian The Journal of Physical Chemistry B, Vol. 109, Issue 9 https://doi.org/10.1021/jp040769o	journal	March 2005
Characterization of the nitridation process of boric acid Gouin, X.; Grange, P.; Bois, L. Journal of Alloys and Compounds, Vol. 224, Issue 1 https://doi.org/10.1016/0925-8388(95)01532-9	journal	June 1995
Aqueous dispersions of few-layer-thick chemically modified magnesium diboride nanosheets by ultrasonication assisted exfoliation Das, Saroj Kumar; Bedar, Amita; Kannan, Aadithya Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep10522	journal	June 2015
Unexpected kinetic effect of MgB2 in reactive hydride composites containing complex borohydrides Barkhordarian, Gagik; Klassen, Thomas; Dornheim, Martin Journal of Alloys and Compounds, Vol. 440, Issue 1-2 https://doi.org/10.1016/j.jallcom.2006.09.048	journal	August 2007
Electrolyte-Assisted Hydrogen Storage Reactions Vajo, John J.; Tan, Hongjin; Ahn, Channing C. The Journal of Physical Chemistry C, Vol. 122, Issue 47 https://doi.org/10.1021/acs.jpcc.8b08335	journal	November 2018
Boron-11 NMR spectra of boranes, main-group heteroboranes, and substituted derivatives. Factors influencing chemical shifts of skeletal atoms Hermanek, Stanislav Chemical Reviews, Vol. 92, Issue 2 https://doi.org/10.1021/cr00010a007	journal	March 1992
The investigations of electronic structure, optical and magnetic properties of MgB2 nanosheets Zaari, Halima; Naji, Sufyan; El Hachimi, A. G. 2014 International Renewable and Sustainable Energy Conference (IRSEC) https://doi.org/10.1109/IRSEC.2014.7059868	conference	October 2014

Similar Records

Superconducting films of MgB₂ via ion beam mixing of Mg/B multilayers

Journal Article · Wed Mar 18 00:00:00 EDT 2020 · Journal of Physics. D, Applied Physics · OSTI ID:1670751

Beckham, J. L.; Bayu Aji, L. B.; Baker, A. A.; +5 more

The influence of LiH and TiH₂ on hydrogen storage in MgB₂ I: Promotion of bulk hydrogenation at reduced temperature

Journal Article · Wed Oct 27 00:00:00 EDT 2021 · International Journal of Hydrogen Energy · OSTI ID:1670751

Snider, J. L.; Liu, Y. -S.; Sawvel, A. M.; +7 more

Elucidating the mechanism of MgB₂ initial hydrogenation via a combined experimental–theoretical study

Journal Article · Wed Jul 19 00:00:00 EDT 2017 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1670751

Ray, Keith G.; Klebanoff, Leonard E.; Lee, Jonathan R. I.; +9 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Nanoscale Mg–B via Surfactant Ball Milling of MgB2: Morphology, Composition, and Improved Hydrogen Storage Properties

Citation Formats

References (54)

Similar Records

Related Subjects

Title: Nanoscale Mg–B via Surfactant Ball Milling of MgB₂: Morphology, Composition, and Improved Hydrogen Storage Properties