Temperature-dependent Battery Performance of a Na3V2(PO4)2F3@MWCNT Cathode and In-situ Heat Generation on Cycling

Essehli, Rachid; Amin, Ruhul; Abouimrane, Ali; Li, Mengya; ben Yahia, Hamdi; Maher, Kenza; Zakaria, Yahya; Belharouak, Ilias

doi:10.1002/cssc.202001268

Title: Temperature-dependent Battery Performance of a Na₃V₂(PO₄)₂F₃@MWCNT Cathode and In-situ Heat Generation on Cycling

Journal Article · Thu Aug 06 00:00:00 EDT 2020 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.202001268· OSTI ID:1649259

Essehli, Rachid ^[1];

^[1]; Abouimrane, Ali ^[2];

^[1]; ben Yahia, Hamdi ^[2]; Maher, Kenza ^[2]; Zakaria, Yahya ^[2];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Hamad Bin Khalifa Univ., Doha (Qatar). Qatar Environment and Energy Research Inst.

Excellent structural stability, high operating voltage, and high capacity have made Na₃V₂(PO₄)₂F₃ a promising cathode material for sodium-ion batteries. However, high-temperature battery performances and heat generation measurements have not been systematically reported yet. Carbon-coated Na₃V₂(PO₄)₂F₃@MWCNT (multi-walled carbon nanotube) samples are fabricated by a hydrothermal-assisted sol-gel method and the electrochemical performances are evaluated at three different temperatures (25, 45, and 55 °C). Furthermore, the well-crystallized Na₃V₂(PO₄)₂F₃@MWCNT samples exhibit good cycling stability at both low and high temperatures; they deliver an initial discharge capacity of 120–125 mAhg^-1 at a 1 C rate with a retention of 53 % capacity after 1,400 cycles with 99 % columbic efficiency. The half-cell delivers a capacity of 100 mAhg^-1 even at a high rate of 10 C at room temperature. Furthermore, the Na₃V₂(PO₄)₂F₃@MWCNT samples show good long-term durability; the capacity loss is an average of 0.05 % per cycle at a 1 C rate at 55 °C. Additionally, ionic diffusivity and charge transfer resistance are evaluated as functions of state of charge, and they explain the high electrochemical performance of the Na₃V₂(PO₄)₂F₃@MWCNT samples. In-situ heat generation measurements reveal reversible results upon cycling owing to the high structural stability of the material. Excellent electrochemical performances are also demonstrated in the full-cell configuration with hard carbon as well as antimony Sb/C anodes.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1649259

Alternate ID(s):: OSTI ID: 1646551

Journal Information:: ChemSusChem, Vol. 13; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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Title: Temperature-dependent Battery Performance of a Na3V2(PO4)2F3@MWCNT Cathode and In-situ Heat Generation on Cycling

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Title: Temperature-dependent Battery Performance of a Na₃V₂(PO₄)₂F₃@MWCNT Cathode and In-situ Heat Generation on Cycling