Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots

Gu, Siyong; Christensen, Tommiejean; Hsieh, Chien-Te; Mallick, Bikash Chandra; Gandomi, Yasser Ashraf; Li, Jianlin; Chang, Jeng-Kuei

doi:10.1016/j.electacta.2020.136642

Title: Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots

Abstract

Adopting a solid-phase microwave-assisted technique followed by thermal pyrolysis of N-functionalized graphene quantum dots, novel nitrogen-doped graphite-like (NGL) electrode materials were synthesized in this work and served as the anode for Li-ion batteries. The NGL anode demonstrated reversible capacity of 530 mAh g^-1 at 0.1C, superior rate capability at high C rate operation (420 mAh g^-1 at 5C), remarkable initial coulombic efficiency (>95.7%), and excellent cyclic stability along with high efficiency (>99.1%) during entire cycling. The NGL anode nanostructure enables improved lithium ion mobility and reversible Li⁺ storage during cycling. The analysis of the Ragone plots revealed that the specific energy of NGL anode reaches to ca. 840 Wh kg^-1 at the power density of 4200 W kg^-1. The diffusion coefficient of Li ions was measured as 1.69 × 10^-9 cm² s^-1 for the NGL anode material, substantially improving over commonly used graphite electrodes (15–26 times higher Li⁺ diffusivity). The high-rate cyclability as well as the cyclic stability of the NGL anodes were also confirmed via long-term cycling of full pouch cells assembled with ternary cathode and NGL anode. The robust design of the NGL anode materials introduced in this work, paves the way for designing next-generation lithium-ion batteries operatingmore » at ultra-high C rates.« less

Authors:

Gu, Siyong ^[1]; Christensen, Tommiejean ^[2];

^[3]; Mallick, Bikash Chandra ^[4]; Gandomi, Yasser Ashraf ^[5];

^[6]; Chang, Jeng-Kuei ^[7]

Xiamen Univ. of Technology (China)
Univ. of Tennessee, Knoxville, TN (United States)
Yuan Ze Univ., Taoyuan (Taiwan); Univ. of Tennessee, Knoxville, TN (United States)
Yuan Ze Univ., Taoyuan (Taiwan)
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Chiao Tung Univ., Hsinchu (Taiwan)

Publication Date:: Mon Jun 22 00:00:00 EDT 2020

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE; Taiwan Ministry of Science and Technology (MOST); Chang Gung Medical Foundation

OSTI Identifier:: 1648881

Grant/Contract Number:: AC05-00OR22725; CMRPD2E0082

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Electrochimica Acta

Additional Journal Information:: Journal Volume: 354; Journal Issue: N/A; Journal ID: ISSN 0013-4686

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; Nitrogen doping; Graphite-like anodes; Lithium ion battery; Graphene quantum dots; Rate capability

Citation Formats


                    Gu, Siyong, Christensen, Tommiejean, Hsieh, Chien-Te, Mallick, Bikash Chandra, Gandomi, Yasser Ashraf, Li, Jianlin, and Chang, Jeng-Kuei. Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots.  United States: N. p., 2020. 
        Web.  doi:10.1016/j.electacta.2020.136642.

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                    Gu, Siyong, Christensen, Tommiejean, Hsieh, Chien-Te, Mallick, Bikash Chandra, Gandomi, Yasser Ashraf, Li, Jianlin, & Chang, Jeng-Kuei. Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots.  United States.  https://doi.org/10.1016/j.electacta.2020.136642

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                    Gu, Siyong, Christensen, Tommiejean, Hsieh, Chien-Te, Mallick, Bikash Chandra, Gandomi, Yasser Ashraf, Li, Jianlin, and Chang, Jeng-Kuei. 2020.  
        "Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots".  United States.  https://doi.org/10.1016/j.electacta.2020.136642.  https://www.osti.gov/servlets/purl/1648881.

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@article{osti_1648881,

  title        = {Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots},

  author       = {Gu, Siyong and Christensen, Tommiejean and Hsieh, Chien-Te and Mallick, Bikash Chandra and Gandomi, Yasser Ashraf and Li, Jianlin and Chang, Jeng-Kuei},

  abstractNote = {Adopting a solid-phase microwave-assisted technique followed by thermal pyrolysis of N-functionalized graphene quantum dots, novel nitrogen-doped graphite-like (NGL) electrode materials were synthesized in this work and served as the anode for Li-ion batteries. The NGL anode demonstrated reversible capacity of 530 mAh g-1 at 0.1C, superior rate capability at high C rate operation (420 mAh g-1 at 5C), remarkable initial coulombic efficiency (>95.7%), and excellent cyclic stability along with high efficiency (>99.1%) during entire cycling. The NGL anode nanostructure enables improved lithium ion mobility and reversible Li+ storage during cycling. The analysis of the Ragone plots revealed that the specific energy of NGL anode reaches to ca. 840 Wh kg-1 at the power density of 4200 W kg-1. The diffusion coefficient of Li ions was measured as 1.69 × 10-9 cm2 s-1 for the NGL anode material, substantially improving over commonly used graphite electrodes (15–26 times higher Li+ diffusivity). The high-rate cyclability as well as the cyclic stability of the NGL anodes were also confirmed via long-term cycling of full pouch cells assembled with ternary cathode and NGL anode. The robust design of the NGL anode materials introduced in this work, paves the way for designing next-generation lithium-ion batteries operating at ultra-high C rates.},

  doi          = {10.1016/j.electacta.2020.136642},

  url          = {https://www.osti.gov/biblio/1648881},
  journal      = {Electrochimica Acta},

  issn         = {0013-4686},

  number       = N/A,

  volume       = 354,

  place        = {United States},

  year         = {Mon Jun 22 00:00:00 EDT 2020},

  month        = {Mon Jun 22 00:00:00 EDT 2020}

}

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The layer-structured Li[Ni_xCo_yMn_1-x-y]O₂ (NCM) cathode materials have been the best choice for increasing electric vehicle driving distance per charge. The high Ni layered oxide represents successfully commercialized NCM cathodes (such as NCM622 and NCA) in lithium-ion batteries (LIBs) for EV applications due to their high energy density and acceptable cycling stability. However, the price of cobalt, the key element within LIBs for stability, has nearly tripled over the past few years due to increased demand from the cell phone industry. As mentioned in the DOE Funding Opportunity Announcement, the current materials shortage will also cause speculation for a future globalmore »« less
https://doi.org/10.2172/1972477

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Title: Improved lithium storage capacity and high rate capability of nitrogen-doped graphite-like electrode materials prepared from thermal pyrolysis of graphene quantum dots

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Materials processing for lithium-ion batteries journal, March 2011

l -Cysteine-Assisted Synthesis of Layered MoS 2 /Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries journal, May 2011

Issues and challenges facing rechargeable lithium batteries journal, November 2001

Effect of High Voltage on the Structure and Electrochemistry of LiNi 0.5 Mn 0.5 O 2 : A Joint Experimental and Theoretical Study journal, October 2006

Electrospun SnO2 and TiO2 Composite Nanofibers for Lithium Ion Batteries journal, January 2014

Pulse Microwave Deposition of Cobalt Oxide Nanoparticles on Graphene Nanosheets as Anode Materials for Lithium Ion Batteries journal, July 2012

Synthesis of ZnO@Graphene composites as anode materials for lithium ion batteries journal, November 2013

Silicon@graphene composite prepared by spray–drying method as anode for lithium ion batteries journal, July 2019

Pitch carbon and LiF co-modified Si-based anode material for lithium ion batteries journal, August 2017

Improved storage capacity and rate capability of Fe3O4–graphene anodes for lithium-ion batteries journal, December 2011

Folded Structured Graphene Paper for High Performance Electrode Materials journal, January 2012

Graphene nanosheets for enhanced lithium storage in lithium ion batteries journal, July 2009

Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries journal, June 2009

Electrochemical storage of energy in carbon nanotubes and nanostructured carbons journal, August 2002

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal, September 2010

Doped Graphene Sheets As Anode Materials with Superhigh Rate and Large Capacity for Lithium Ion Batteries journal, June 2011

Versatile Graphene Quantum Dots with Tunable Nitrogen Doping journal, December 2013

Large-Scale Growth and Characterizations of Nitrogen-Doped Monolayer Graphene Sheets journal, April 2011

3D nitrogen-doped carbon supported non-precious metals electrocatalyst for oxygen reduction reaction journal, April 2020

Pure nitrogen-doped graphene aerogel with rich micropores yields high ORR performance journal, March 2019

Full-faradaic-active nitrogen species doping enables high-energy-density carbon-based supercapacitor journal, September 2020

Electro-spun graphene-enriched carbon fibres with high nitrogen-contents for electrochemical water desalination journal, February 2018

Nitrogen-doped carbon derived from onion waste as anode material for high performance sodium-ion battery journal, March 2020

Nitrogen-doped mesoporous carbon as an anode material for high performance potassium-ion batteries journal, April 2020

Microwave growth and tunable photoluminescence of nitrogen-doped graphene and carbon nitride quantum dots journal, January 2019

Superior Cathode Performance of Nitrogen-Doped Graphene Frameworks for Lithium Ion Batteries journal, March 2017

Synergistic effect of S,N-co-doped mesoporous carbon materials with high performance for oxygen-reduction reaction and Li-ion batteries journal, January 2015

Toward N-Doped Graphene via Solvothermal Synthesis journal, March 2011

Edge-functionalized and substitutionally doped graphene nanoribbons: Electronic and spin properties journal, April 2008

Spin Gapless Semiconductor−Metal−Half-Metal Properties in Nitrogen-Doped Zigzag Graphene Nanoribbons journal, June 2009

Oligomer-salt derived 3D, heavily nitrogen doped, porous carbon for Li-ion hybrid electrochemical capacitors application journal, December 2014

Fabrication of well-aligned carbon nanofiber array and its gaseous-phase adsorption behavior journal, February 2004

Parameter setting on growth of carbon nanotubes over transition metal/alumina catalysts in a fluidized bed reactor journal, May 2009

A simple drain current model for Schottky-barrier carbon nanotube field effect transistors journal, September 2007

Synthesis of carbon nanotubes over Ni- and Co-supported CaCO3 catalysts using catalytic chemical vapor deposition journal, April 2009

The effect of high-temperature annealing on the structure and electrical properties of well-aligned carbon nanotubes journal, March 2007

Bottom-up synthesis of nitrogen-doped graphene sheets for ultrafast lithium storage journal, January 2014

Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries journal, April 2018

Improved Graphite Anode for Lithium-Ion Batteries Chemically journal, January 1996

Rapid synthesis of nitrogen-doped graphene for a lithium ion battery anode with excellent rate performance and super-long cyclic stability journal, January 2014

Nitrogen doping and chirality of carbon nanotubes journal, December 2004

Electronic Transport and Mechanical Properties of Phosphorus- and Phosphorus−Nitrogen-Doped Carbon Nanotubes journal, June 2009

Nitrogen-Doped Graphene: Efficient Growth, Structure, and Electronic Properties journal, December 2011

Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries journal, April 2010

Tailoring nitrogen content in doped carbon by a facile synthesis with ionic liquid precursors for lithium ion batteries journal, November 2019

Reduced graphene oxide@nitrogen doped carbon with enhanced electrochemical performance in lithium ion batteries journal, June 2019

Nitrogen-doped 3D nanocarbon with nanopore defects as high-capacity and stable anode materials for sodium/lithium-ion batteries journal, June 2020

Nitrogen-doped porous hard carbons derived from shaddock peel for high-capacity lithium-ion battery anodes journal, April 2020

Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance journal, October 2012

Nitrogen-doped graphene nanosheets as anode materials for lithium ion batteries: a first-principles study journal, January 2012

High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework journal, November 2014

Nitrogen-Doped Multiwall Carbon Nanotubes for Lithium Storage with Extremely High Capacity journal, April 2012

Long-term cyclability of LiFePO4/carbon composite cathode material for lithium-ion battery applications journal, October 2009

Effects of TiO2 coating on high-temperature cycle performance of LiFePO4-based lithium-ion batteries journal, October 2008

Effective enhancement of electrochemical properties for LiFePO4/C cathode materials by Na and Ti co-doping journal, February 2013

Electrochemical performance of lithium iron phosphate cathodes at various temperatures journal, January 2014

Lithium Intercalation into Mechanically Milled Natural Graphite: Electrochemical and Kinetic Characterization journal, January 2002

Enabling high rate charge and discharge capability, low internal resistance, and excellent cycleability for Li-ion batteries utilizing graphene additives journal, May 2018

Pulse Laser Deposition and Electrochemical Characterization of LiFePO 4 −C Composite Thin Films journal, May 2008

An Electrochemical Impedance Spectroscopic Study of the Electronic and Ionic Transport Properties of Spinel LiMn 2 O 4 journal, April 2010

Intercalation Mechanism of Lithium Ions into Graphite Layers Studied by Nuclear Magnetic Resonance and Impedance Experiments journal, January 2001

Charge/discharge cycling behavior of pitch-based carbon fiber in organic electrolyte solutions journal, September 1993

Li diffusion through doped and defected graphene journal, January 2013

Materials processing for lithium-ion batteries
journal, March 2011

l -Cysteine-Assisted Synthesis of Layered MoS ₂ /Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries
journal, May 2011

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

Effect of High Voltage on the Structure and Electrochemistry of LiNi _0.5 Mn _0.5 O ₂ : A Joint Experimental and Theoretical Study
journal, October 2006

Electrospun SnO2 and TiO2 Composite Nanofibers for Lithium Ion Batteries
journal, January 2014

Pulse Microwave Deposition of Cobalt Oxide Nanoparticles on Graphene Nanosheets as Anode Materials for Lithium Ion Batteries
journal, July 2012

Synthesis of ZnO@Graphene composites as anode materials for lithium ion batteries
journal, November 2013

Silicon@graphene composite prepared by spray–drying method as anode for lithium ion batteries
journal, July 2019

Pitch carbon and LiF co-modified Si-based anode material for lithium ion batteries
journal, August 2017

Improved storage capacity and rate capability of Fe3O4–graphene anodes for lithium-ion batteries
journal, December 2011

Folded Structured Graphene Paper for High Performance Electrode Materials
journal, January 2012

Graphene nanosheets for enhanced lithium storage in lithium ion batteries
journal, July 2009

Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries
journal, June 2009

Electrochemical storage of energy in carbon nanotubes and nanostructured carbons
journal, August 2002

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010

Doped Graphene Sheets As Anode Materials with Superhigh Rate and Large Capacity for Lithium Ion Batteries
journal, June 2011

Versatile Graphene Quantum Dots with Tunable Nitrogen Doping
journal, December 2013

Large-Scale Growth and Characterizations of Nitrogen-Doped Monolayer Graphene Sheets
journal, April 2011

3D nitrogen-doped carbon supported non-precious metals electrocatalyst for oxygen reduction reaction
journal, April 2020

Pure nitrogen-doped graphene aerogel with rich micropores yields high ORR performance
journal, March 2019

Full-faradaic-active nitrogen species doping enables high-energy-density carbon-based supercapacitor
journal, September 2020

Electro-spun graphene-enriched carbon fibres with high nitrogen-contents for electrochemical water desalination
journal, February 2018

Nitrogen-doped carbon derived from onion waste as anode material for high performance sodium-ion battery
journal, March 2020

Nitrogen-doped mesoporous carbon as an anode material for high performance potassium-ion batteries
journal, April 2020

Microwave growth and tunable photoluminescence of nitrogen-doped graphene and carbon nitride quantum dots
journal, January 2019

Superior Cathode Performance of Nitrogen-Doped Graphene Frameworks for Lithium Ion Batteries
journal, March 2017

Synergistic effect of S,N-co-doped mesoporous carbon materials with high performance for oxygen-reduction reaction and Li-ion batteries
journal, January 2015

Toward N-Doped Graphene via Solvothermal Synthesis
journal, March 2011

Edge-functionalized and substitutionally doped graphene nanoribbons: Electronic and spin properties
journal, April 2008

Spin Gapless Semiconductor−Metal−Half-Metal Properties in Nitrogen-Doped Zigzag Graphene Nanoribbons
journal, June 2009

Oligomer-salt derived 3D, heavily nitrogen doped, porous carbon for Li-ion hybrid electrochemical capacitors application
journal, December 2014

Fabrication of well-aligned carbon nanofiber array and its gaseous-phase adsorption behavior
journal, February 2004

Parameter setting on growth of carbon nanotubes over transition metal/alumina catalysts in a fluidized bed reactor
journal, May 2009

A simple drain current model for Schottky-barrier carbon nanotube field effect transistors
journal, September 2007

Synthesis of carbon nanotubes over Ni- and Co-supported CaCO3 catalysts using catalytic chemical vapor deposition
journal, April 2009

The effect of high-temperature annealing on the structure and electrical properties of well-aligned carbon nanotubes
journal, March 2007

Bottom-up synthesis of nitrogen-doped graphene sheets for ultrafast lithium storage
journal, January 2014

Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries
journal, April 2018

Improved Graphite Anode for Lithium-Ion Batteries Chemically
journal, January 1996

Rapid synthesis of nitrogen-doped graphene for a lithium ion battery anode with excellent rate performance and super-long cyclic stability
journal, January 2014

Nitrogen doping and chirality of carbon nanotubes
journal, December 2004

Electronic Transport and Mechanical Properties of Phosphorus- and Phosphorus−Nitrogen-Doped Carbon Nanotubes
journal, June 2009

Nitrogen-Doped Graphene: Efficient Growth, Structure, and Electronic Properties
journal, December 2011

Large reversible capacity of high quality graphene sheets as an anode material for lithium-ion batteries
journal, April 2010

Tailoring nitrogen content in doped carbon by a facile synthesis with ionic liquid precursors for lithium ion batteries
journal, November 2019

Reduced graphene oxide@nitrogen doped carbon with enhanced electrochemical performance in lithium ion batteries
journal, June 2019

Nitrogen-doped 3D nanocarbon with nanopore defects as high-capacity and stable anode materials for sodium/lithium-ion batteries
journal, June 2020

Nitrogen-doped porous hard carbons derived from shaddock peel for high-capacity lithium-ion battery anodes
journal, April 2020

Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance
journal, October 2012

Nitrogen-doped graphene nanosheets as anode materials for lithium ion batteries: a first-principles study
journal, January 2012

High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework
journal, November 2014

Nitrogen-Doped Multiwall Carbon Nanotubes for Lithium Storage with Extremely High Capacity
journal, April 2012

Long-term cyclability of LiFePO4/carbon composite cathode material for lithium-ion battery applications
journal, October 2009

Effects of TiO2 coating on high-temperature cycle performance of LiFePO4-based lithium-ion batteries
journal, October 2008

Effective enhancement of electrochemical properties for LiFePO4/C cathode materials by Na and Ti co-doping
journal, February 2013

Electrochemical performance of lithium iron phosphate cathodes at various temperatures
journal, January 2014

Lithium Intercalation into Mechanically Milled Natural Graphite: Electrochemical and Kinetic Characterization
journal, January 2002

Enabling high rate charge and discharge capability, low internal resistance, and excellent cycleability for Li-ion batteries utilizing graphene additives
journal, May 2018

Pulse Laser Deposition and Electrochemical Characterization of LiFePO ₄ −C Composite Thin Films
journal, May 2008

An Electrochemical Impedance Spectroscopic Study of the Electronic and Ionic Transport Properties of Spinel LiMn ₂ O ₄
journal, April 2010

Intercalation Mechanism of Lithium Ions into Graphite Layers Studied by Nuclear Magnetic Resonance and Impedance Experiments
journal, January 2001

Charge/discharge cycling behavior of pitch-based carbon fiber in organic electrolyte solutions
journal, September 1993

Li diffusion through doped and defected graphene
journal, January 2013