Correlating inter-particle forces and particle shape to shear-induced aggregation/fragmentation and rheology for dilute anisotropic particle suspensions: A complementary study via capillary rheometry and in-situ small and ultra-small angle X-ray scattering

Krzysko, Anthony J.; Nakouzi, Elias; Zhang, Xin; Graham, Trent R.; Rosso, Kevin M.; Schenter, Gregory K.; Ilavsky, Jan; Kuzmenko, Ivan; Frith, Matthew G.; Ivory, Cornelius F.; Clark, Sue B.; Weston, Javen S.; Weigandt, Katie M.; De Yoreo, James J.; Chun, Jaehun; Anovitz, Lawrence M.

doi:10.1016/j.jcis.2020.04.016

Title: Correlating inter-particle forces and particle shape to shear-induced aggregation/fragmentation and rheology for dilute anisotropic particle suspensions: A complementary study via capillary rheometry and in-situ small and ultra-small angle X-ray scattering

Journal Article · Sat Apr 25 00:00:00 EDT 2020 · Journal of Colloid and Interface Science

DOI:https://doi.org/10.1016/j.jcis.2020.04.016· OSTI ID:1638026

Krzysko, Anthony J. ^[1]; Nakouzi, Elias ^[2];

^[2]; Graham, Trent R. ^[2]; Rosso, Kevin M. ^[2]; Schenter, Gregory K. ^[2]; Ilavsky, Jan ^[3]; Kuzmenko, Ivan ^[3]; Frith, Matthew G. ^[3]; Ivory, Cornelius F. ^[4]; Clark, Sue B. ^[1]; Weston, Javen S. ^[5]; Weigandt, Katie M. ^[6]; De Yoreo, James J. ^[7]; Chun, Jaehun ^[2]; Anovitz, Lawrence M. ^[8]

Washington State Univ., Pullman, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Washington State Univ., Pullman, WA (United States). The Gene and Linda Violand School of Chemical Engineering and Bioengineering.
Univ. of Tulsa, Tulsa, OK (United States). Russell School of Chemical Engineering.
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Center for Neutron Research
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Univ. of Washington, Seattle, WA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Hypothesis: Understanding the stability and rheological behavior of suspensions composed of anisotropic particles is challenging due to the complex interplay of hydrodynamic and colloidal forces. We propose that orientationally-dependent interactions resulting from the anisotropic nature of non-spherical subunits strongly influences shear-induced particle aggregation/fragmentation and suspension rheological behavior. Experiments: Wide-, small-, and ultra-small-angle X-ray scattering experiments were used to simultaneously monitor changes in size and fractal dimensions of boehmite aggregates from 6 to 10,000 A as the sample was recirculated through an in-situ capillary rheometer. The latter also provided simultaneous suspension viscosity data. Computational fluid dynamics modeling of the apparatus provided a more rigorous analysis of the fluid flow. Findings: Shear-induced aggregation/fragmentation was correlated with a complicated balance between hydrodynamic and colloidal forces. Multi-scale fractal aggregates formed in solution but the largest could be fragmented by shear. Orientationally-dependent interactions lead to a relatively large experimental suspension viscosity when the hydrodynamic force was small compared to colloidal forces. This manifests even at low boehmite mass fractions. (C) 2020 Published by Elsevier Inc.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Interfacial Dynamics in Radioactive Environments and Materials (IDREAM); Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Contributing Organization:: Energy Frontier Research Center

Grant/Contract Number:: AC05-76RL01830; AC02-06CH11357; SC0014664

OSTI ID:: 1638026

Alternate ID(s):: OSTI ID: 1659112

Report Number(s):: PNNL-SA-148317

Journal Information:: Journal of Colloid and Interface Science, Vol. 576, Issue 1; ISSN 0021-9797

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Boehmite
aggregation
fragmentation
rheology
small-angle x-ray scattering
ultra-small-angle x-ray scattering
wide-angle x-ray scattering
power-law fluid
boehmite
small angle X-ray scattering
ultra-small angle X-ray scattering

Title: Correlating inter-particle forces and particle shape to shear-induced aggregation/fragmentation and rheology for dilute anisotropic particle suspensions: A complementary study via capillary rheometry and in-situ small and ultra-small angle X-ray scattering

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References (55)

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