High temperature oxidation of steels in CO2 containing impurities

Oleksak, Richard P.; Tylczak, Joseph H.; Holcomb, Gordon R.; Doğan, Ömer N.

doi:10.1016/j.corsci.2019.108316

Title: High temperature oxidation of steels in CO₂ containing impurities

Journal Article · Sat Nov 09 00:00:00 EST 2019 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2019.108316· OSTI ID:1635618

Oleksak, Richard P. ^[1]; Tylczak, Joseph H. ^[2]; Holcomb, Gordon R. ^[2]; Doğan, Ömer N. ^[2]

National Energy Technology Lab. (NETL), Albany, OR (United States); Leidos Research Support Team, Albany, OR (United States)
National Energy Technology Lab. (NETL), Albany, OR (United States)

Future power systems require steels that resist corrosion in high temperature CO₂ containing combustion products/impurities. Here we evaluate the corrosion behavior of several commercial steels exposed to 95% CO₂-4 % H₂O-1 % O₂, with/without 0.1 % SO₂, at 550 °C and 1 atm. High-Cr steels formed thin Cr-rich oxides and low-Cr steels thick Fe-rich oxides during SO₂-free exposures. Additions of SO₂ had little effect on low-Cr steels but enhanced corrosion of high-Cr steels, where S within the chromia scale led to its failure and subsequent Fe-rich oxide nodule growth. Ultimately, the results are rationalized by considering the thermodynamic and kinetic factors controlling the reaction.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: 89243318CFE000003

OSTI ID:: 1635618

Alternate ID(s):: OSTI ID: 1775697

Report Number(s):: RSS097

Journal Information:: Corrosion Science, Vol. 164, Issue C; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 21 works

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