Aqueous redox flow batteries

Zhang, Zhengcheng; Su, Chi Cheung; Cheng, Lei

Title: Aqueous redox flow batteries

Patent · Tue Feb 04 00:00:00 EST 2020

OSTI ID:1632533

Zhang, Zhengcheng; Su, Chi Cheung; Cheng, Lei

The present invention provides an aqueous redox flow battery comprising a negative electrode immersed in an aqueous liquid negative electrolyte, a positive electrode immersed in an aqueous liquid positive electrolyte, and a cation-permeable separator between the negative electrolyte from the positive electrolyte. During charging and discharging, the electrolytes are circulated over their respective electrodes. The electrolytes each comprise a redox reactant. Redox reactant of the positive electrolyte comprises a compound of Formula (I) as described in the specification.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Number(s):: 10,553,890

Application Number:: 15/631,239

OSTI ID:: 1632533

Resource Relation:: Patent File Date: 06/23/2017

Country of Publication:: United States

Language:: English

References (64)

Fuel System Using Redox Flow Battery Chiang, Yet-Ming; Bazzarella, Ricardo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100323264 US Patent Document 12/755379; 20100323264	patent-application	December 2010
Flow battery Nozaki, Ken; Kurokawa, Kosuke; Tsuda, Izumi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5366824 US Patent Document 5,366,824	patent	November 1994
Redox shuttles for lithium ion batteries Weng, Wei; Zhang, Zhengcheng; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110294017 US Patent Application 13/113499; 20110294017	patent-application	December 2011
Inhibitor of Reduction of Life Cycle of Redox Shuttle Additive and Non-Aqueous Electrolyte and Secondary Battery Comprising the Same Ahn, Soon Ho; Yu, Sung Hoon; Oh, Byung Hoon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070092802 US Patent Application 11/552,317; 2007/0092802 Al	patent-application	April 2007
Novel redox shuttles for overcharge protection of lithium batteries Amine, Khalil; Chen, Zonghai; Wang, Qingzheng https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060199080 US Patent Document 11/366891; 20060199080	patent-application	September 2006
Studies of Aromatic Redox Shuttle Additives for LiFePO₄-Based Li-Ion Cells Buhrmester, Claudia; Chen, Jun; Moshurchak, Lee Journal of The Electrochemical Society, Vol. 152, Issue 12, p. A2390-A2399 https://doi.org/10.1149/1.2098265	journal	January 2005
Additives for non-aqueous electrolyte and secondary battery using the same Son, Miyoung; Cho, Jeong-Ju; Lee, Hochun https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100297481 US Patent Application 12/600070; 20100297481	patent-application	November 2010
Overcharge and overdischarge protection in lithium-ion batteries Exnar, Ivan; Wang, Qing https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8003260 US Patent Document 8,003,260	patent	August 2011
Electrolyte for redox flow battery, and redox flow battery Kubata, Michiru; Nakaishi, Hiroyuki; Tokuda, Nobuyuki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7258947 US Patent Document 7,258,947	patent	August 2007
Lithium Rechargeable Electrochemical Cell Exnar, Ivan; Wang, Qing; Gratzel, Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090176162 US Patent Application 12/296211; 20090176162	patent-application	July 2009
N-oxide redox shuttles for rechargeable lithium-ion cell Dahn, Jeffrey R.; Buhrmester, Claudia https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060263695 US Patent Application 11/130849; 20060263695	patent-application	November 2006
Redox Flow Battery Yoshie, Tomohisa; Nishimura, Naoto; Tsukuda, Yoshihiro https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120135278 US Patent Application 13/377223; 20120135278	patent-application	May 2012
Redox-Flow Batteries: From Metals to Organic Redox-Active Materials Winsberg, Jan; Hagemann, Tino; Janoschka, Tobias Angewandte Chemie International Edition, Vol. 56, Issue 3 https://doi.org/10.1002/anie.201604925	journal	November 2016
Organic electronic devices and polymers, including photovoltaic cells and diketone-based polymers Brown, Christopher T.; Grenier, Christophe René Gaston; Landis, Chad https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8968885 US Patent Document 8,968,885	patent	March 2015
High-Potential Redox Shuttle for Use in Lithium-Ion Batteries Moshurchak, L. M.; Lamanna, W. M.; Bulinski, Mike Journal of The Electrochemical Society, Vol. 156, Issue 4, p. A309-A312 https://doi.org/10.1149/1.3077578	journal	January 2009
Redox Species of Redox Flow Batteries: A Review Pan, Feng; Wang, Qing Molecules, Vol. 20, Issue 11 https://doi.org/10.3390/molecules201119711	journal	November 2015
New electrode materials derived from polyquinonic ionic compounds and their use in electrochemical generators Armand, Michel; Michot, Christophe; Ravet, Nathalie https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100237298 US Patent Application 12/792607; 20100237298	patent-application	September 2010
Redox Flow Battery Sun, Hee-Young; Park, Joung-won; Hwang, Seung-sik https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110189549 US Patent Application 12/828551; 20110189549	patent-application	August 2011
A metal-free organic–inorganic aqueous flow battery Huskinson, Brian; Marshak, Michael P.; Suh, Changwon Nature, Vol. 505, Issue 7482, p. 195-198 https://doi.org/10.1038/nature12909	journal	January 2014
Aqueous redox flow batteries featuring improved cell design characteristics Esswein, Arthur J.; Reece, Steven Y.; King, Evan R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9382274 US Patent Document 9,382,274	patent	July 2016
An Aqueous Redox-Flow Battery with High Capacity and Power: The TEMPTMA/MV System Janoschka, Tobias; Martin, Norbert; Hager, Martin D. Angewandte Chemie International Edition, Vol. 55, Issue 46 https://doi.org/10.1002/anie.201606472	journal	October 2016
Redox Shuttles for Overcharge Protection of Lithium-Ion Battery Zhang, L.; Zhang, Z.; Amine, K. ECS Transactions, Vol. 45, Issue 29 https://doi.org/10.1149/04529.0057ecst	journal	April 2013
Organic Active Materials for Batteries Abouimrane, Ali; Weng, Wei; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130189571 US Patent Application 13/449661; 20130189571	patent-application	July 2013
Semi-Solid Lithium Rechargeable Flow Battery Duduta, Mihai; Ho, Bryan; Wood, Vanessa C. Advanced Energy Materials, Vol. 1, Issue 4, p. 511-516 https://doi.org/10.1002/aenm.201100152	journal	May 2011
Electrically rechargeable REDOX flow cell Thaller, Lawrence H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3996064 US Patent Document 3,996,064	patent	December 1976
Non-aqueous electrolyte secondary battery Shimizu, Ryuichi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5709968 US Patent Document 5,709,968	patent	January 1998
Overcharge Protection by Coupling Redox Shuttle Chemistry with Radical Polymerization Additives Casteel, William Jack https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080220335 US Patent Application 12/042,387; 2008/0220335 Al	patent-application	September 2008
Electrochemical Properties of an All-Organic Redox Flow Battery Using 2,2,6,6-Tetramethyl-1-Piperidinyloxy and N-Methylphthalimide Li, Zhen; Li, Sha; Liu, Suqin Electrochemical and Solid-State Letters, Vol. 14, Issue 12, p. A171-A173 https://doi.org/10.1149/2.012112esl	journal	January 2011
Redox flow battery and method of operating it Zocchi, Andrea https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6692862 US Patent Document 6,692,862	patent	February 2004
Flow Battery And Regeneration System With Improved Safety Tolmachev, Yuriy Vyacheslalovovich https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140170511 US Patent Application 14/184702; 20140170511	patent-application	June 2014
Progress in Flow Battery Research and Development Skyllas-Kazacos, M.; Chakrabarti, M. H.; Hajimolana, S. A. Journal of The Electrochemical Society, Vol. 158, Issue 8, p. R55-R79 https://doi.org/10.1149/1.3599565	journal	June 2011
High Energy Density Redox Flow Device Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100047671 US Patent Document 12/484113; 20100047671	patent-application	February 2010
Redox flow cells for energy conversion Ponce de Leon, C.; Frias-Ferrer, A.; Gonzalez-Garcia, J. Journal of Power Sources, Vol. 160, Issue 1, p. 716-732 https://doi.org/10.1016/j.jpowsour.2006.02.095	journal	September 2006
Redox battery Kaneko, Hiroko; Nozaki, Ken https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4362791 US Patent Document 4,362,791	patent	December 1982
Redox shuttles for safer lithium-ion batteries Chen, Zonghai; Qin, Yan; Amine, Khalil Electrochimica Acta, Vol. 54, Issue 24, p. 5605-5613 https://doi.org/10.1016/j.electacta.2009.05.017	journal	October 2009
A Review on Lithium-Ion Batteries Safety Issues: Existing Problems and Possible Solutions Wen, Jianwu; Yu, Yan; Chen, Chunhua Materials Express, Vol. 2, Issue 3 https://doi.org/10.1166/mex.2012.1075	journal	September 2012
Sodium Based Aqueous Electrolyte Electrochemical Secondary Energy Storage Device Whitacre, Jay https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110052945 US Patent Application 12/943275; 20110052945	patent-application	March 2011
Development of metal-based electrodes for non-aqueous redox flow batteries Kim, Jae-Hun; Kim, Ki Jae; Park, Min-Sik Electrochemistry Communications, Vol. 13, Issue 9, p. 997-1000 https://doi.org/10.1016/j.elecom.2011.06.022	journal	September 2011
Low band-gap polymers based on quinoxaline derivatives and fused thiophene as donor materials for high efficiency bulk-heterojunction photovoltaic cells Lee, Jang-Yong; Shin, Won-Suk; Haw, Jung-Rim Journal of Materials Chemistry, Vol. 19, Issue 28, p. 4938-4945 https://doi.org/10.1039/b823536h	journal	January 2009
Non-aqueous Redox Flow Batteries Including 3,7-Perfluoroalkylated Phenothiazine Derivatives Odom, Susan A.; Kaur, Aman P.; Elliott, Corrine F. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150372333 US Patent Application 14/747816; 20150372333	patent-application	December 2015
Organic non-aqueous cation-based redox flow batteries Jansen, Andrew; Vaughey, John T.; Chen, Zonghai https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9300000 US Patent Document 9,300,000	patent	March 2016
Modified vanadium compound, producing method thereof, redox flow battery electrolyte composite and redox flow battery electrolyte producing method Tanaka, Yasuyuki; Mita, Muneo; Horikawa, Ken https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6872376 US Patent Document 6,872,376	patent	March 2005
A redox-flow battery with an alloxazine-based organic electrolyte Lin, Kaixiang; Gómez-Bombarelli, Rafael; Beh, Eugene S. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.102	journal	July 2016
An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery Brushett, Fikile R.; Vaughey, John T.; Jansen, Andrew N. Advanced Energy Materials, Vol. 2, Issue 11, p. 1390-1396 https://doi.org/10.1002/aenm.201200322	journal	June 2012
Vanadium Redox Battery Incorporating Multiple Electrolyte Reservoirs Lepp, Gary; Harper, Mathew Albert MacLennan; Klassen, Andy https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080241643 US Patent Application 11/728,521; 2008/0241643 Al	patent-application	October 2008
High-performance Lithium Secondary Batteries Using Cathode Active Materials of Triquinoxalinylenes Exhibiting Six Electron Migration Matsunaga, Takayuki; Kubota, Takayuki; Sugimoto, Toyonari Chemistry Letters, Vol. 40, Issue 7, p. 750-752 https://doi.org/10.1246/cl.2011.750	journal	July 2011
Process for preparing para-aminophenol DeLue, Norman R.; Pickens, Stanley R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4584070 US Patent Document 4,584,070	patent	April 1986
Organic electrolyte solution and redox flow battery including the same Sun, Hee-young; Park, Joung-won; Lee, Doo-yeon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110195283 US Patent Application 13/016317; 20110195283	patent-application	August 2011
All-Vanadium Redox Flow Battery System Employing a V+4/V+5 Redox Couple and an Ancillary CE+3/CE+4 Redox Couple in the Positive Electrolyte Solution Spaziante, Placido Maria; Dichand, Michael https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150380760 US Patent Application 14/766,638; 2015/0380760 Al	patent-application	December 2015
Alkaline quinone flow battery Lin, K.; Chen, Q.; Gerhardt, M. R. Science, Vol. 349, Issue 6255, p. 1529-1532 https://doi.org/10.1126/science.aab3033	journal	September 2015
Redox Flow Battery Dong, Yongrong; Kaku, Hirokazu; Hanafusa, Kei https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160013506 US Patent Application 14/773112; 20160013506	patent-application	January 2016
Redox flow batteries a review Weber, Adam Z.; Mench, Matthew M.; Meyers, Jeremy P. Journal of Applied Electrochemistry, Vol. 41, Issue 10, p. 1137-1164 https://doi.org/10.1007/s10800-011-0348-2	journal	September 2011
Cyclopropenium Salts as Cyclable, High-Potential Catholytes in Nonaqueous Media Sevov, Christo S.; Samaroo, Sharmila K.; Sanford, Melanie S. Advanced Energy Materials, Vol. 7, Issue 5 https://doi.org/10.1002/aenm.201602027	journal	November 2016
Molecular engineering towards safer lithium-ion batteries: a highly stable and compatible redox shuttle for overcharge protection Zhang, Lu; Zhang, Zhengcheng; Redfern, Paul C. Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee21977h	journal	January 2012
High Energy Density Redox Flow Device Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110200848 US Patent Application 12/970753; 20110200848	patent-application	August 2011
Polyether-functionalized redox shuttle additives for lithium ion batteries Zhang, Zhengcheng; Zhang, Lu; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110294003 US Patent Application 13/114452; 20110294003	patent-application	December 2011
Revisiting the stability of endo/exo Diels-Alder adducts between cyclopentadiene and 1,4-benzoquinone Tormena, Claudio F.; Lacerda Jr., Valdemar; Oliveira, Kleber T. de Journal of the Brazilian Chemical Society, Vol. 21, Issue 1 https://doi.org/10.1590/S0103-50532010000100017	journal	January 2010
Secondary Battery, Power Supply System Using Same and Usage of Power Supply System Inatomi, Yuu; Hojo, Nobuhiko; Kuranuki, Masaaki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090017379 US Patent Application 11/915456; 20090017379	patent-application	January 2009
The 1:1 and 2:1 adducts of cyclopentadiene with p-benzoquinone Yates, Peter; Switlak, Krzysztof Canadian Journal of Chemistry, Vol. 68, Issue 10 https://doi.org/10.1139/v90-293	journal	October 1990
Vanadium/polyhalide redox flow battery Skyllas-Kazacos, Maria https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7320844 US Patent Document 7,320,844	patent	January 2008
Electrochemical investigation of uranium β-diketonates for all-uranium redox flow battery Yamamura, Tomoo; Shiokawa, Yoshinobu; Yamana, Hajimu Electrochimica Acta, Vol. 48, Issue 1, p. 43-50 https://doi.org/10.1016/S0013-4686(02)00546-7	journal	November 2002
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Evaluation of electrolytes for redox flow battery applications Chakrabarti, M. H.; Dryfe, R. A. W.; Roberts, E. P. L. Electrochimica Acta, Vol. 52, Issue 5, p. 2189-2195 https://doi.org/10.1016/j.electacta.2006.08.052	journal	January 2007
Energy storage for the electricity grid : benefits and market potential assessment guide : a study for the DOE Energy Storage Systems Program. Eyer, James M.; Corey, Garth P. https://doi.org/10.2172/1031895 SAND2010-0815	report	February 2010

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