Evidence for a short-range chemical order of Ge atoms and its critical role in inducing a giant magnetocaloric effect in Gd5Si1.5Ge2.5

Kou, Ronghui; Gao, Jianrong; Nie, Zhihua; Wang, Yandong; Brown, Dennis E.; Ren, Yang

doi:10.1016/j.jallcom.2019.151751

Title: Evidence for a short-range chemical order of Ge atoms and its critical role in inducing a giant magnetocaloric effect in Gd₅Si_1.5Ge_2.5

Journal Article · Wed Aug 07 00:00:00 EDT 2019 · Journal of Alloys and Compounds

DOI:https://doi.org/10.1016/j.jallcom.2019.151751· OSTI ID:1618451

Kou, Ronghui ^[1];

^[1];

^[2]; Wang, Yandong ^[3]; Brown, Dennis E. ^[4]; Ren, Yang ^[5]

Northeastern Univ., Shenyang (China)
Beijing Inst. of Technology (China)
Univ. of Science and Technology, Beijing (China)
Northern Illinois Univ., De Kalb, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Crystal structure and magnetic properties of Gd₅Si_1.5Ge_2.5 and Gd_4.9Zr_0·1Si_1.5Ge_2.5 were investigated using high-energy X-ray diffraction and magnetic measurements. Results showed that a Zr substitution for 2% Gd reduces unit cell volumes of a room-temperature monoclinic and a low-temperature orthorhombic lattice and a difference between them at a magnetostructural transition. At a microscopic level, the Zr substitution increases length of disconnected interlayer T–T bonds of the monoclinic lattice at the expense of length of connected interlayer T–T bonds (T = Si, Ge). These opposing changes of the interlayer T–T bonds provided evidence for existence of a short-range chemical order of Ge atoms in lattices of Gd₅Si_1.5Ge_2.5 and its weakening by the Zr substitution. Magnetic measurements revealed that the Zr substitution brings about a change of the magnetic structure and a reduction of a giant magnetocaloric effect of Gd₅Si_1.5Ge_2.5. Based on such structural and magnetic changes due to the Zr substitution, we propose a relation between the short-range chemical order and the total entropy change at the magnetostructural transition. Finally, using this relation, a giant magnetocaloric effect and an annealing effect observed over a wide range of Gd₅(Si,Ge)₄ composition can be explained quantitatively.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Ministry of Science and Technology of the People's Republic of China

Grant/Contract Number:: AC02-06CH11357; 51831003; 2012CB619405; DE–AC02–06CH11357

OSTI ID:: 1618451

Alternate ID(s):: OSTI ID: 1701869

Journal Information:: Journal of Alloys and Compounds, Vol. 808, Issue C; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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References (41)

Materials Challenges for High Performance Magnetocaloric Refrigeration Devices Smith, Anders; Bahl, Christian R. H.; Bjørk, Rasmus Advanced Energy Materials, Vol. 2, Issue 11 https://doi.org/10.1002/aenm.201200167	journal	September 2012
Low-field-actuated giant magnetocaloric effect and excellent mechanical properties in a NiMn-based multiferroic alloy Cong, D. Y.; Huang, L.; Hardy, V. Acta Materialia, Vol. 146 https://doi.org/10.1016/j.actamat.2017.12.047	journal	March 2018
Mixed Magnetism for Refrigeration and Energy Conversion Dung, Nguyen H.; Ou, Zhi Qiang; Caron, Luana Advanced Energy Materials, Vol. 1, Issue 6 https://doi.org/10.1002/aenm.201100252	journal	September 2011
Giant Magnetocaloric Effect in ${Gd}_{5} ({Si}_{2} {Ge}_{2})$ Pecharsky, V. K.; Gschneidner, Jr., K. A. Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497 https://doi.org/10.1103/PhysRevLett.78.4494	journal	June 1997
Gd5(SixGe1-x)4: An Extremum Material Pecharsky, V. K.; Gschneidner Jr., K. A. Advanced Materials, Vol. 13, Issue 9 https://doi.org/10.1002/1521-4095(200105)13:9<683::AID-ADMA683>3.0.CO;2-O	journal	May 2001
Phase relationships and crystallography in the pseudobinary system Gd5Si4Gd5Ge4 Pecharsky, V. K.; Gschneidner, K. A. Journal of Alloys and Compounds, Vol. 260, Issue 1-2 https://doi.org/10.1016/S0925-8388(97)00143-6	journal	September 1997
Making and Breaking Covalent Bonds across the Magnetic Transition in the Giant Magnetocaloric Material ${Gd}_{5} ({Si}_{2} {Ge}_{2})$ Choe, W.; Pecharsky, V. K.; Pecharsky, A. O. Physical Review Letters, Vol. 84, Issue 20 https://doi.org/10.1103/PhysRevLett.84.4617	journal	May 2000
Tunable magnetic regenerator alloys with a giant magnetocaloric effect for magnetic refrigeration from ∼20 to ∼290 K Pecharsky, V. K.; Gschneidner, K. A. Applied Physics Letters, Vol. 70, Issue 24 https://doi.org/10.1063/1.119206	journal	June 1997
Recent developments in magnetocaloric materials Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O. Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539 https://doi.org/10.1088/0034-4885/68/6/R04	journal	May 2005
Active and passive magnetic regenerators in gas/magnetic refrigerators Barclay, John A. Journal of Alloys and Compounds, Vol. 207-208 https://doi.org/10.1016/0925-8388(94)90239-9	journal	June 1994
Electron correlation effects on the magnetostructural transition and magnetocaloric effect in ${Gd}_{5} {Si}_{2} {Ge}_{2}$ Paudyal, Durga; Pecharsky, Vitalij K.; Gschneidner, Karl A. Physical Review B, Vol. 73, Issue 14 https://doi.org/10.1103/PhysRevB.73.144406	journal	April 2006
Role of Ge in Bridging Ferromagnetism in the Giant Magnetocaloric ${Gd}_{5} ({Ge}_{1 - x} {Si}_{x})_{4}$ Alloys Haskel, D.; Lee, Y. B.; Harmon, B. N. Physical Review Letters, Vol. 98, Issue 24 https://doi.org/10.1103/PhysRevLett.98.247205	journal	June 2007
Electronic structure of Gd5(Si, Ge)4 Skorek, G.; Deniszczyk, J.; Szade, J. Journal of Physics: Condensed Matter, Vol. 14, Issue 30 https://doi.org/10.1088/0953-8984/14/30/316	journal	July 2002
The giant magnetocaloric effect of optimally prepared Gd5Si2Ge2 Pecharsky, A. O.; Gschneidner, K. A.; Pecharsky, V. K. Journal of Applied Physics, Vol. 93, Issue 8 https://doi.org/10.1063/1.1558210	journal	April 2003
TEM analysis of Gd5(SixGel−x)4, where x=1/2 Meyers, J. S.; Chumbley, S.; Laabs, F. Acta Materialia, Vol. 51, Issue 1 https://doi.org/10.1016/S1359-6454(02)00227-6	journal	January 2003
The effect of varying the crystal structure on the magnetism, electronic structure and thermodynamics in the Gd 5 (Si x Ge 1−x ) 4 system near x =0.5 Pecharsky, V. K.; Samolyuk, G. D.; Antropov, V. P. Journal of Solid State Chemistry, Vol. 171, Issue 1-2 https://doi.org/10.1016/S0022-4596(02)00146-9	journal	February 2003
Large magnetocaloric effect and refrigerant capacity near room temperature in as-cast Gd ₅ Ge ₂ Si _2−x Sn _x compounds Carvalho, A. Magnus G.; Tedesco, J. C. G.; Pires, M. J. M. Applied Physics Letters, Vol. 102, Issue 19 https://doi.org/10.1063/1.4806971	journal	May 2013
Phase Transformation Driven by Valence Electron Concentration: Tuning Interslab Bond Distances in Gd ₅ Ga _x Ge ₄ _- _x Mozharivskyj, Yurij; Choe, Wonyoung; Pecharsky, Alexandra O. Journal of the American Chemical Society, Vol. 125, Issue 49 https://doi.org/10.1021/ja037649z	journal	December 2003
Gd ₅ Si _{4− x} P _x : Targeted Structural Changes through Increase in Valence Electron Count Svitlyk, Volodymyr; Miller, Gordon J.; Mozharivskyj, Yurij Journal of the American Chemical Society, Vol. 131, Issue 6 https://doi.org/10.1021/ja8085033	journal	February 2009
Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron Provenzano, Virgil; Shapiro, Alexander J.; Shull, Robert D. Nature, Vol. 429, Issue 6994 https://doi.org/10.1038/nature02657	journal	June 2004
Effect of Fe-substitution on microstructure, hysteresis behaviour and magnetocaloric effect in Gd5Si2Ge2 Alloys Raj Kumar, D. M.; Manivel Raja, M.; Gopalan, R. Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 9 https://doi.org/10.1016/j.jmmm.2008.11.094	journal	May 2009
The nonpareil R5(SixGe1−x)4 phases Gschneidner, K. A.; Pecharsky, V. K.; Pecharsky, A. O. Journal of Alloys and Compounds, Vol. 303-304 https://doi.org/10.1016/S0925-8388(00)00747-7	journal	May 2000
Crystal structures, phase relationships, and magnetic phase transitions of R ₅ M ₄ compounds ( R = rare earths, M = Si, Ge) Ouyang, Zhong-Wen; Rao, Guang-Hui Chinese Physics B, Vol. 22, Issue 9 https://doi.org/10.1088/1674-1056/22/9/097501	journal	September 2013
Magnetic ordering in the monoclinic structure of Nd ₅ Si _1.45 Ge _2.55 and Pr ₅ Si _1.5 Ge _2.5 studied by means of neutron powder diffraction Magen, C.; Ritter, C.; Morellon, L. Journal of Physics: Condensed Matter, Vol. 16, Issue 41 https://doi.org/10.1088/0953-8984/16/41/022	journal	October 2004
The magnetocaloric effect, magnetic refrigeration and ductile intermetallic compounds Gschneidner, K. A. Acta Materialia, Vol. 57, Issue 1 https://doi.org/10.1016/j.actamat.2008.08.048	journal	January 2009
Charge transfer-tuned magnetism in Nd-substituted Gd ₅ Si ₄ Kou, R. H.; Gao, J.; Ren, Y. AIP Advances, Vol. 8, Issue 12 https://doi.org/10.1063/1.5081457	journal	December 2018
Site Preference of Metal Atoms in Gd5-xMxTt4 (M = Zr, Hf; Tt = Si, Ge) Yao, Jinlei; Mozharivskyj, Yurij Zeitschrift für anorganische und allgemeine Chemie, Vol. 637, Issue 13 https://doi.org/10.1002/zaac.201100281	journal	October 2011
Phase analysis and magnetocaloric properties of Zr substituted Gd–Si–Ge alloys Prabahar, K.; Raj Kumar, D. M.; Manivel Raja, M. Journal of Magnetism and Magnetic Materials, Vol. 323, Issue 13 https://doi.org/10.1016/j.jmmm.2011.01.029	journal	July 2011
“Nanoscale Zippers” in the Crystalline Solid. Structural Variations in the Giant Magnetocaloric Material Gd ₅ Si _1.5 Ge _2.5 Choe, Wonyoung; Miller, Gordon J.; Meyers, John Chemistry of Materials, Vol. 15, Issue 7 https://doi.org/10.1021/cm020928l	journal	April 2003
Effect of a magnetic field on the magnetostructural phase transition in ${Gd}_{5} ({Si}_{x} {Ge}_{1 - x})_{4}$ Casanova, Fèlix; Labarta, Amílcar; Batlle, Xavier Physical Review B, Vol. 69, Issue 10 https://doi.org/10.1103/PhysRevB.69.104416	journal	March 2004
Magnetic phase transitions and ferromagnetic short-range correlations in single-crystal ${Tb}_{5} {Si}_{2.2} {Ge}_{1.8}$ Zou, M.; Pecharsky, V. K.; Gschneidner, K. A. Physical Review B, Vol. 78, Issue 1 https://doi.org/10.1103/PhysRevB.78.014435	journal	July 2008
Griffiths-like behavior in Ge-rich magnetocaloric compounds Gd5(SixGe1−x)4 Ouyang, Z. W. Journal of Applied Physics, Vol. 108, Issue 3 https://doi.org/10.1063/1.3467800	journal	August 2010
Estimating spontaneous magnetization from a mean field analysis of the magnetic entropy change Amaral, J. S.; Silva, N. J. O.; Amaral, V. S. Journal of Magnetism and Magnetic Materials, Vol. 322, Issue 9-12 https://doi.org/10.1016/j.jmmm.2009.09.024	journal	May 2010
Some common misconceptions concerning magnetic refrigerant materials Pecharsky, V. K.; Gschneidner, K. A. Journal of Applied Physics, Vol. 90, Issue 9 https://doi.org/10.1063/1.1405836	journal	November 2001
Pressure-Induced Three-Dimensional Ferromagnetic Correlations in the Giant Magnetocaloric Compound ${G d}_{5} {G e}_{4}$ Magen, C.; Arnold, Z.; Morellon, L. Physical Review Letters, Vol. 91, Issue 20 https://doi.org/10.1103/PhysRevLett.91.207202	journal	November 2003
The Curie temperature of the ferromagnetic transition metals and their compounds Mohn, P.; Wohlfarth, E. P. Journal of Physics F: Metal Physics, Vol. 17, Issue 12 https://doi.org/10.1088/0305-4608/17/12/016	journal	December 1987
Effect of hydrostatic pressure upon the magnetic transitions in the ${Gd}_{5} {({Si}_{x} {Ge}_{1 - x})}_{4}$ giant magnetocaloric compounds: X-ray magnetic circular dichroism study Tseng, Y. C.; Haskel, D.; Lang, J. C. Physical Review B, Vol. 76, Issue 1 https://doi.org/10.1103/PhysRevB.76.014411	journal	July 2007
Elastic properties of ${Gd}_{5} {Si}_{2} {Ge}_{2}$ studied with an ultrasonic pulse-echo technique Svitelskiy, O.; Suslov, A.; Schlagel, D. L. Physical Review B, Vol. 74, Issue 18 https://doi.org/10.1103/PhysRevB.74.184105	journal	November 2006
Magnetocaloric effect in strong magnetic fields Tishin, A. M. Cryogenics, Vol. 30, Issue 2 https://doi.org/10.1016/0011-2275(90)90258-E	journal	February 1990
On the nature of the magnetocaloric effect of the first-order magnetostructural transition Gschneidner, K. A.; Mudryk, Y.; Pecharsky, V. K. Scripta Materialia, Vol. 67, Issue 6 https://doi.org/10.1016/j.scriptamat.2011.12.042	journal	September 2012
Preparation, crystal structure, magnetic and magnetothermal properties of (Gd[sub x]R[sub 5−x])Si[sub 4], where R=Pr and Tb, alloys Spichkin, Y. I.; Pecharsky, V. K.; Gschneidner, K. A. Journal of Applied Physics, Vol. 89, Issue 3 https://doi.org/10.1063/1.1335821	journal	January 2001

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Title: Evidence for a short-range chemical order of Ge atoms and its critical role in inducing a giant magnetocaloric effect in Gd5Si1.5Ge2.5

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