Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers

Chi, Xiaodong; Peters, Gretchen M.; Brockman, Chandler; Lynch, Vincent M.; Sessler, Jonathan L.

doi:10.1021/jacs.8b09620

Title: Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers

Journal Article · Mon Oct 08 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b09620· OSTI ID:1615751

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Univ. of Texas, Austin, TX (United States)
Univ. of Texas, Austin, TX (United States); Shanghai Univ. (China)

A diblock copolymer containing a strapped calix[4]pyrrole-based ion pair recognition subunit has been synthesized via RAFT polymerization. As prepared, the polymer is hydrophobic and devoid of any particular morphological form. Yet, upon ion pair complexation, the copolymer self-assembles to generate reverse micelles in organic media. The reverse micelle formed in this way may be used to extract alkali cation and cesium halide anion salts from an aqueous source into an organic receiving phase. The polymer confirmed more effective as an extractant than the corresponding free ion pair receptor.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); R. A. Welch Foundation

Grant/Contract Number:: FG02-01ER15186

OSTI ID:: 1615751

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 41; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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The Effect of Substitution Pattern on Binding Ability in Regioisomeric Ion Pair Receptors Based on an Aminobenzoic Platform Jagleniec, Damian; Ziach, Krzysztof; Dąbrowa, Kajetan Molecules, Vol. 24, Issue 16 https://doi.org/10.3390/molecules24162990	journal	August 2019
Counter Cation Dependent and Stimuli Responsive Supramolecular Polymers Constructed by Calix[4]pyrrole Based Host-Guest Interactions: Counter Cation Dependent and Stimuli Responsive Supramolecular Polymers Constructed by Calix[4]pyrrole Based Host-Guest Interactions Yuvayapan, Samet; Aydogan, Abdullah European Journal of Organic Chemistry, Vol. 2019, Issue 4 https://doi.org/10.1002/ejoc.201801663	journal	December 2018
Strapped calix[4]pyrroles: from syntheses to applications Peng, Sangshan; He, Qing; Vargas-Zúñiga, Gabriela I. Chemical Society Reviews, Vol. 49, Issue 3 https://doi.org/10.1039/c9cs00528e	journal	January 2020
Spectroscopic characterization and in silico modelling of polyvinylpyrrolidone as an anion-responsive fluorescent polymer in aqueous media Kam, Hiu C.; Ranathunga, Dineli T. S.; Payne, Ethan R. Taylor & Francis https://doi.org/10.6084/m9.figshare.8378540.v1	text	January 2019
Spectroscopic characterization and in silico modelling of polyvinylpyrrolidone as an anion-responsive fluorescent polymer in aqueous media Kam, Hiu C.; Ranathunga, Dineli T. S.; Payne, Ethan R. Taylor & Francis https://doi.org/10.6084/m9.figshare.8378540	text	January 2019

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Title: Controlling Structure Beyond the Initial Coordination Sphere: Complexation-Induced Reversed Micelle Formation in Calix[4]pyrrole-Containing Diblock Copolymers

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