Inorganic vacancy-ordered perovskite Cs2SnCl6:Bi/GaN heterojunction photodiode for narrowband, visible-blind UV detection

Shao, Dali; Zhu, Weiguang; Xin, Guoqing; Lian, Jie; Sawyer, Shayla

doi:10.1063/1.5123226

Title: Inorganic vacancy-ordered perovskite Cs₂SnCl₆:Bi/GaN heterojunction photodiode for narrowband, visible-blind UV detection

Journal Article · Tue Sep 17 00:00:00 EDT 2019 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.5123226· OSTI ID:1612667

^[1];

^[1]; Xin, Guoqing ^[1]; Lian, Jie ^[1]; Sawyer, Shayla ^[1]

Rensselaer Polytechnic Inst., Troy, NY (United States)

In this work, a heterojunction photodiode was fabricated from Bi doped Cs₂SnCl₆ nanoparticles (Cs₂SnCl₆:Bi NPs) spin-coated on an epitaxially grown GaN substrate. With the back illumination configuration, the heterojunction photodiode demonstrated excellent narrow-band UV sensing capability with a full wavelength of half maximum of 18 nm and a maximum detectivity of 1.2 × 10¹² jones, which is promising for biomedical applications. In addition to the excellent narrow band UV sensitivity, the device also demonstrated a large linear dynamic range of 71 decibels (dB) and a fast photoresponse speed (a rise time of 0.75 μs and a fall time of 0.91 μs). The excellent performance is attributed to excellent carrier separation efficiency at the heterojunction interface and improved carrier collection efficiency through the multi-walled carbon nanotube (MWCNT) network. All the above advantages are of great importance for commercial deployment of perovskite-based photodetectors.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: The Ohio State Univ., Columbus, OH (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD); Rensselaer Polytechnic Inst., Troy, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016584

OSTI ID:: 1612667

Alternate ID(s):: OSTI ID: 1562336; OSTI ID: 1865542

Journal Information:: Applied Physics Letters, Vol. 115, Issue 12; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 24 works

Citation information provided by
Web of Science

References (32)

Deep UV narrow-band photodetector based on ion beam synthesized indium oxide quantum dots in Al ₂ O ₃ matrix Rajamani, Saravanan; Arora, Kanika; Konakov, Anton Nanotechnology, Vol. 29, Issue 30 https://doi.org/10.1088/1361-6528/aabfaf	journal	May 2018
Heterojunction photodiode fabricated from multiwalled carbon nanotube/ZnO nanowire/p-silicon composite structure Shao, Dali; Yu, Mingpeng; Lian, Jie Applied Physics Letters, Vol. 102, Issue 2 https://doi.org/10.1063/1.4776691	journal	January 2013
Co ₃ O ₄ Nanosheets as Active Material for Hybrid Zn Batteries Tan, Peng; Chen, Bin; Xu, Haoran Small, Vol. 14, Issue 21 https://doi.org/10.1002/smll.201800225	journal	April 2018
Highly Efficient Blue-Emitting Bi-Doped Cs ₂ SnCl ₆ Perovskite Variant: Photoluminescence Induced by Impurity Doping Tan, Zhifang; Li, Jinghui; Zhang, Cheng Advanced Functional Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adfm.201801131	journal	May 2018
Perspectives and Design Principles of Vacancy-Ordered Double Perovskite Halide Semiconductors Maughan, Annalise E.; Ganose, Alex M.; Scanlon, David O. Chemistry of Materials, Vol. 31, Issue 4 https://doi.org/10.1021/acs.chemmater.8b05036	journal	January 2019
CsPbX ₃ Quantum Dots for Lighting and Displays: Room-Temperature Synthesis, Photoluminescence Superiorities, Underlying Origins and White Light-Emitting Diodes Li, Xiaoming; Wu, Ye; Zhang, Shengli Advanced Functional Materials, Vol. 26, Issue 15 https://doi.org/10.1002/adfm.201600109	journal	February 2016
Ultrahigh-Performance Self-Powered Flexible Double-Twisted Fibrous Broadband Perovskite Photodetector Sun, Haoxuan; Tian, Wei; Cao, Fengren Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706986	journal	April 2018
Electrical characteristics of magnesium-doped gallium nitride junction diodes Fedison, J. B.; Chow, T. P.; Lu, H. Applied Physics Letters, Vol. 72, Issue 22 https://doi.org/10.1063/1.121475	journal	June 1998
Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX ₃ ) Song, Jizhong; Li, Jianhai; Li, Xiaoming Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201502567	journal	October 2015
Solution-processed hybrid perovskite photodetectors with high detectivity Dou, Letian; Yang, Yang (Micheal); You, Jingbi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6404	journal	November 2014
Heterojunction photodiode fabricated from hydrogen treated ZnO nanowires grown on p -silicon substrate Shao, Dali; Yu, Mingpeng; Lian, Jie Applied Physics Letters, Vol. 101, Issue 21 https://doi.org/10.1063/1.4767679	journal	November 2012
Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality Xiao, Zewen; Meng, Weiwei; Wang, Jianbo Materials Horizons, Vol. 4, Issue 2 https://doi.org/10.1039/C6MH00519E	journal	January 2017
Progress in Theoretical Study of Metal Halide Perovskite Solar Cell Materials Xiao, Zewen; Yan, Yanfa Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701136	journal	August 2017
From Lead Halide Perovskites to Lead‐Free Metal Halide Perovskites and Perovskite Derivatives Xiao, Zewen; Song, Zhaoning; Yan, Yanfa Advanced Materials, Vol. 31, Issue 47 https://doi.org/10.1002/adma.201803792	journal	January 2019
Preparation of large scale and highly ordered vanadium pentoxide (V ₂ O ₅ ) nanowire arrays towards high performance photodetectors Fu, Wen Biao; Shang, Guo Liang; Gong, Xin Xin Journal of Materials Chemistry C, Vol. 5, Issue 6 https://doi.org/10.1039/C6TC04894C	journal	January 2017
Distinguishable Detection of Ultraviolet, Visible, and Infrared Spectrum with High-Responsivity Perovskite-Based Flexible Photosensors Wu, Xiaohan; Zhou, Bilei; Zhou, Jiachen Small, Vol. 14, Issue 19 https://doi.org/10.1002/smll.201800527	journal	April 2018
Inorganic Halide Perovskites for Efficient Light-Emitting Diodes Yantara, Natalia; Bhaumik, Saikat; Yan, Fei The Journal of Physical Chemistry Letters, Vol. 6, Issue 21 https://doi.org/10.1021/acs.jpclett.5b02011	journal	October 2015
Self-powered, ultraviolet-visible perovskite photodetector based on TiO ₂ nanorods Zhou, Hai; Song, Zehao; Tao, Pan RSC Advances, Vol. 6, Issue 8 https://doi.org/10.1039/C5RA27840F	journal	January 2016
Low-Noise and Large-Linear-Dynamic-Range Photodetectors Based on Hybrid-Perovskite Thin-Single-Crystals Bao, Chunxiong; Chen, Zhaolai; Fang, Yanjun Advanced Materials, Vol. 29, Issue 39 https://doi.org/10.1002/adma.201703209	journal	August 2017
All-Inorganic Perovskite Nanocrystals for High-Efficiency Light Emitting Diodes: Dual-Phase CsPbBr ₃ -CsPb ₂ Br ₅ Composites Zhang, Xiaoli; Xu, Bing; Zhang, Jinbao Advanced Functional Materials, Vol. 26, Issue 25 https://doi.org/10.1002/adfm.201600958	journal	April 2016
Self-Filtered Narrowband Perovskite Photodetectors with Ultrafast and Tuned Spectral Response Li, Lingliang; Deng, Yehao; Bao, Chunxiong Advanced Optical Materials, Vol. 5, Issue 22 https://doi.org/10.1002/adom.201700672	journal	September 2017
Lead‐Free Perovskite Derivative Cs ₂ SnCl ₆₋ _x Br _x Single Crystals for Narrowband Photodetectors Zhou, Jun; Luo, Jiajun; Rong, Ximing Advanced Optical Materials, Vol. 7, Issue 10 https://doi.org/10.1002/adom.201900139	journal	March 2019
Computational Study of Halide Perovskite-Derived A ₂ BX ₆ Inorganic Compounds: Chemical Trends in Electronic Structure and Structural Stability Cai, Yao; Xie, Wei; Ding, Hong Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b02013	journal	September 2017
Quantum dot-induced phase stabilization of -CsPbI3 perovskite for high-efficiency photovoltaics Swarnkar, A.; Marshall, A. R.; Sanehira, E. M. Science, Vol. 354, Issue 6308 https://doi.org/10.1126/science.aag2700	journal	October 2016
Air-Stable Molecular Semiconducting Iodosalts for Solar Cell Applications: Cs₂SnI₆ as a Hole Conductor Lee, Byunghong; Stoumpos, Constantinos C.; Zhou, Nanjia Journal of the American Chemical Society, Vol. 136, Issue 43, p. 15379-15385 https://doi.org/10.1021/ja508464w	journal	October 2014
Electrical and ultraviolet photoresponse properties of quasialigned ZnO nanowires/p-Si heterojunction Ghosh, R.; Basak, D. Applied Physics Letters, Vol. 90, Issue 24 https://doi.org/10.1063/1.2748333	journal	June 2007
Self-Filtered Narrowband Perovskite Photodetectors with Ultrafast and Tuned Spectral Response S., Tang,; H., Wei,; Y., Fang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/0cct-yg83	text	January 2017
How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr ₃ Cells Kulbak, Michael; Cahen, David; Hodes, Gary The Journal of Physical Chemistry Letters, Vol. 6, Issue 13 https://doi.org/10.1021/acs.jpclett.5b00968	journal	June 2015
High-Performance Photodiode-Type Photodetectors Based on Polycrystalline Formamidinium Lead Iodide Perovskite Thin Films Zhang, Meng; Zhang, Fan; Wang, Yue Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-29147-6	journal	July 2018
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Low-Noise and Large-Linear-Dynamic-Range Photodetectors Based on Hybrid-Perovskite Thin-Single-Crystals L., Li,; Y., Fang,; H., Wei, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/n8v7-9d83	text	January 2017
Computational Study of Halide Perovskite-Derived A$_2$BX$_6$ Inorganic Compounds: Chemical Trends in Electronic Structure and Structural Stability Cai, Yao; Xie, Wei; Ding, Hong arXiv https://doi.org/10.48550/arxiv.1706.08674	preprint	January 2017

Cited By (1)

A high performance UV–visible dual-band photodetector based on an inorganic Cs ₂ SnI ₆ perovskite/ZnO heterojunction structure Shao, Dali; Zhu, Weiguang; Xin, Guoqing Journal of Materials Chemistry C, Vol. 8, Issue 5 https://doi.org/10.1039/c9tc05940g	journal	January 2020

Similar Records

A high performance UV–visible dual-band photodetector based on an inorganic Cs ₂ SnI ₆ perovskite/ZnO heterojunction structure

Journal Article · Wed Dec 11 00:00:00 EST 2019 · Journal of Materials Chemistry C · OSTI ID:1612667

Shao, Dali; Zhu, Weiguang; Xin, Guoqing; +5 more

Ti3+-TiO2/Ce3+-CeO2 Nanosheet heterojunctions as efficient visible-light-driven photocatalysts

Journal Article · Sun Apr 15 00:00:00 EDT 2018 · Materials Research Bulletin · OSTI ID:1612667

Xiu, Ziyuan; Xing, Zipeng; Li, Zhenzi; +6 more

Comparison of carrier transport mechanism under UV/Vis illumination in an AZO photodetector and an AZO/p-Si heterojunction photodiode produced by spray pyrolysis

Journal Article · Wed Jan 14 00:00:00 EST 2015 · Journal of Applied Physics · OSTI ID:1612667

Shasti, M.; Dariani, R. S.

Related Subjects

71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
Physics
Photodetectors
Heterostructures
Perovskites
Nanoparticles
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES

Title: Inorganic vacancy-ordered perovskite Cs2SnCl6:Bi/GaN heterojunction photodiode for narrowband, visible-blind UV detection

Citation Formats

References (32)

Cited By (1)

Similar Records

Related Subjects

Title: Inorganic vacancy-ordered perovskite Cs₂SnCl₆:Bi/GaN heterojunction photodiode for narrowband, visible-blind UV detection