In Situ Determination of the HfO2-Ta2O5-Temperature Phase Diagram up to 3000 °C

McCormack, Scott J.; Tseng, Kuo‐Pin; Weber, Richard J.  K.; Kapush, Denys; Ushakov, Sergey V.; Navrotsky, Alexandra; Kriven, Waltraud M.

doi:10.1111/jace.16271

Title: In Situ Determination of the HfO₂-Ta₂O₅-Temperature Phase Diagram up to 3000 °C

Journal Article · Wed Dec 19 00:00:00 EST 2018 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.16271· OSTI ID:1598613

^[1]; Tseng, Kuo‐Pin ^[1]; Weber, Richard J. K. ^[2]; Kapush, Denys ^[3]; Ushakov, Sergey V. ^[3];

^[3];

^[1]

Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering
Materials Development, Inc., Evanston, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of California, Davis, CA (United States). Peter A. Rock Thermochemistry Lab.

The previously unknown experimental HfO₂-Ta₂O₅-temperature phase diagram has been elucidated up to 3000 degrees C using a quadrupole lamp furnace and conical nozzle levitator system equipped with a CO₂ laser, in conjunction with synchrotron X-ray diffraction. These in-situ techniques allowed the determination of the following: (a) liquidus, solidus, and invariant transformation temperatures as a function of composition from thermal arrest experiments, (b) determination of equilibrium phases through testing of reversibility via in-situ X-ray diffraction, and (c) molar volume measurements as a function of temperature for equilibrium phases. From these, an experimental HfO₂-Ta₂O₅-temperature phase diagram has been constructed which is consistent with the Gibbs Phase Rule.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1598613

Journal Information:: Journal of the American Ceramic Society, Vol. 102, Issue 8; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 70 works

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