A highly efficient catalyst of palygorskite-supported manganese oxide for formaldehyde oxidation at ambient and low temperature: Performance, mechanism and reaction kinetics

Wang, Can; Zou, Xuehua; Liu, Haibo; Chen, Tianhu; Suib, Steven L.; Chen, Dong; Xie, Jingjing; Li, Mengxue; Sun, Fuwei

doi:10.1016/j.apsusc.2019.04.257

Title: A highly efficient catalyst of palygorskite-supported manganese oxide for formaldehyde oxidation at ambient and low temperature: Performance, mechanism and reaction kinetics

Journal Article · Mon Apr 29 00:00:00 EDT 2019 · Applied Surface Science

DOI:https://doi.org/10.1016/j.apsusc.2019.04.257· OSTI ID:1598238

Wang, Can ^[1]; Zou, Xuehua ^[2]; Liu, Haibo ^[1]; Chen, Tianhu ^[1]; Suib, Steven L. ^[3]; Chen, Dong ^[1]; Xie, Jingjing ^[1]; Li, Mengxue ^[1]; Sun, Fuwei ^[1]

Hefei Univ. of Technology (China)
Hefei Univ. of Technology (China); Univ. of Connecticut, Storrs, CT (United States)
Univ. of Connecticut, Storrs, CT (United States)

A series of palygorskite-supported manganese oxide (MnO_x/PG) catalysts were prepd. by a pptn. method using different manganese precursor. The as-prepared MnO_x/PG catalysts were used to evaluate the catalytic oxidn. of HCHO and characterized by BET, XRD, TG, Raman spectroscopy, TEM, H₂-TPR, XPS, and chemical titration. The results showed that the crystalline phase, distribution and Mn valence states of MnO_x on the surface of PG depended on the precursors. Birnessite-type manganese oxide (δ-MnO₂) formed and uniformly coated on the surface of PG when potassium permanganate (PP) was used as the precursor. The MnO_x/PG-PP catalyst showed the best catalytic activity for HCHO removal at low temp. among these catalysts and achieved complete HCHO conversion at 150 °C. More importantly, the dynamic single-pass removal efficiency of MnO_x/PG-PP catalyst for ppm-level HCHO oxidn. was as high as 95% under high GHSV (300 L/g·h) at ambient temp. MnO_x/PG-PP catalyst also exhibited excellent cycling stability and long-term activity at low and ambient temp. The kinetic results of MnO_x/PG-PP catalyst showed that the oxidn. of HCHO followed the Mars-van Krevelen mechanism. The possible reaction pathway of HCHO oxidn. was proposed based on in situ DRIFTS and TPSR studies. The large sp. surface area, highly distributed active component, a high proportion of Mn⁴⁺ species, and lattice oxygen content are responsible for the high catalytic activity of MnO_x/PG-PP for oxidn. of formaldehyde. This work developed a natural mineral supported manganese oxide as an inexpensive and efficient catalyst for the purifn. of HCHO in industrial or indoor air environment.

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Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: FG02-86ER13622; 41872040; 41772038; 41572028

OSTI ID:: 1598238

Journal Information:: Applied Surface Science, Vol. 486, Issue C; ISSN 0169-4332

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 41 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: A highly efficient catalyst of palygorskite-supported manganese oxide for formaldehyde oxidation at ambient and low temperature: Performance, mechanism and reaction kinetics

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