Rechargeable Zinc-Aqueous Polysulfide Battery with a Mediator-Ion Solid Electrolyte
Abstract
Large scale energy storage for the electric grid will need low cost and high energy density solutions. We demonstrate in this letter a rechargeable zinc-aqueous polysulfide battery in which a metallic zinc anode is separated from a liquid aqueous polysulfide catholyte by an alkali-metal-ion solid-state electrolyte, wherein the alkali metal ion is Na+ or Li+. The solid-state electrolyte effectively separates the anode from the reactive polysulfide catholyte, preventing the crossover of the polysulfide species and maintaining good electrochemical performance with a reversible discharge capacity of 822 mA h g-1 with nearly 100% Coulombic efficiency.
- Authors:
-
- Univ. of Texas, Austin, TX (United States)
- Publication Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1598148
- Grant/Contract Number:
- SC0005397
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 13; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Gross, Martha M., and Manthiram, Arumugam. Rechargeable Zinc-Aqueous Polysulfide Battery with a Mediator-Ion Solid Electrolyte. United States: N. p., 2018.
Web. doi:10.1021/acsami.8b00981.
Gross, Martha M., & Manthiram, Arumugam. Rechargeable Zinc-Aqueous Polysulfide Battery with a Mediator-Ion Solid Electrolyte. United States. https://doi.org/10.1021/acsami.8b00981
Gross, Martha M., and Manthiram, Arumugam. 2018.
"Rechargeable Zinc-Aqueous Polysulfide Battery with a Mediator-Ion Solid Electrolyte". United States. https://doi.org/10.1021/acsami.8b00981. https://www.osti.gov/servlets/purl/1598148.
@article{osti_1598148,
title = {Rechargeable Zinc-Aqueous Polysulfide Battery with a Mediator-Ion Solid Electrolyte},
author = {Gross, Martha M. and Manthiram, Arumugam},
abstractNote = {Large scale energy storage for the electric grid will need low cost and high energy density solutions. We demonstrate in this letter a rechargeable zinc-aqueous polysulfide battery in which a metallic zinc anode is separated from a liquid aqueous polysulfide catholyte by an alkali-metal-ion solid-state electrolyte, wherein the alkali metal ion is Na+ or Li+. The solid-state electrolyte effectively separates the anode from the reactive polysulfide catholyte, preventing the crossover of the polysulfide species and maintaining good electrochemical performance with a reversible discharge capacity of 822 mA h g-1 with nearly 100% Coulombic efficiency.},
doi = {10.1021/acsami.8b00981},
url = {https://www.osti.gov/biblio/1598148},
journal = {ACS Applied Materials and Interfaces},
issn = {1944-8244},
number = 13,
volume = 10,
place = {United States},
year = {Wed Mar 21 00:00:00 EDT 2018},
month = {Wed Mar 21 00:00:00 EDT 2018}
}
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