Long Cycle Life, Low Self-Discharge Sodium-Selenium Batteries with High Selenium Loading and Suppressed Polyselenide Shuttling

Wang, Hui; Jiang, Yang; Manthiram, Arumugam

doi:10.1002/aenm.201701953

Title: Long Cycle Life, Low Self-Discharge Sodium-Selenium Batteries with High Selenium Loading and Suppressed Polyselenide Shuttling

Journal Article · Wed Nov 08 00:00:00 EST 2017 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201701953· OSTI ID:1596645

Wang, Hui ^[1]; Jiang, Yang ^[2];

^[3]

Univ. of Texas, Austin, TX (United States); Hefei Univ. of Technology (China)
Hefei Univ. of Technology (China)
Univ. of Texas, Austin, TX (United States)

The utilization of selenium as a cathode in rechargeable sodium–selenium batteries is hampered by low Se loading, inferior electrode kinetics, and polyselenide shuttling between the cathode and anode. Here a high-performance sodium–selenium cell is presented by coupling a binder-free, self-interwoven carbon nanofiber–selenium cathode with a light-weight carbon-coated bifunctional separator. With this strategy, electrodes with a high Se mass loading (4.4 mg cm^-2) render high reversible capacities of 599 mA h g^-1 at 0.1C rate and 382 mA h g^-1 at 5C rate. In addition, this novel cell offers good shelf-life with a low self-discharge, retaining 93.4% of its initial capacity even after resting for six months. As evidenced by experimental and density functional theory analysis, the remarkable dynamic (cycle life) and static (shelf-life) stabilities originate from the high electrical conductivity, improved Na-ion accessibility through the 3D interconnected open channels, and highly restrained polyselenide shuttle. The findings demonstrate the viability of high-performance sodium–selenium batteries with high selenium loading.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; China Scholarship Council

Grant/Contract Number:: SC0005397; 201606690005

OSTI ID:: 1596645

Alternate ID(s):: OSTI ID: 1408155

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 7; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 78 works

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References (48)

Electrochemical energy storage in a sustainable modern society Goodenough, John B. Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42613K	journal	January 2014
Design and Preparation of Materials for Advanced Electrochemical Storage Melot, Brent C.; Tarascon, J. -M. Accounts of Chemical Research, Vol. 46, Issue 5 https://doi.org/10.1021/ar300088q	journal	June 2012
Ultrathin-Nanosheet-Induced Synthesis of 3D Transition Metal Oxides Networks for Lithium Ion Battery Anodes Zhu, Shan; Li, Jiajun; Deng, Xiaoyang Advanced Functional Materials, Vol. 27, Issue 9 https://doi.org/10.1002/adfm.201605017	journal	January 2017
High Voltage, Transition Metal Complex Enables Efficient Electrochemical Energy Storage in a Li-Ion Battery Full Cell Zheng, Qi; Niu, Zhihui; Ye, Jing Advanced Functional Materials, Vol. 27, Issue 4 https://doi.org/10.1002/adfm.201604299	journal	December 2016
A Targeted Functional Design for Highly Efficient and Stable Cathodes for Rechargeable Li-Ion Batteries He, Guanjie; Han, Xiaoyu; Zou, Rujia Advanced Functional Materials, Vol. 27, Issue 4 https://doi.org/10.1002/adfm.201604903	journal	December 2016
V ₅ S ₈ –graphite hybrid nanosheets as a high rate-capacity and stable anode material for sodium-ion batteries Yang, Chenghao; Ou, Xing; Xiong, Xunhui Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE03173K	journal	January 2017
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage Guo, Shaohua; Liu, Pan; Sun, Yang Angewandte Chemie International Edition, Vol. 54, Issue 40 https://doi.org/10.1002/anie.201505215	journal	August 2015
Na ₂ Ti ₃ O ₇ @N-Doped Carbon Hollow Spheres for Sodium-Ion Batteries with Excellent Rate Performance Xie, Fangxi; Zhang, Lei; Su, Dawei Advanced Materials, Vol. 29, Issue 24 https://doi.org/10.1002/adma.201700989	journal	April 2017
Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
Disodium Terephthalate (Na2C8H4O4) as High Performance Anode Material for Low-Cost Room-Temperature Sodium-Ion Battery Zhao, Liang; Zhao, Junmei; Hu, Yong-Sheng Advanced Energy Materials, Vol. 2, Issue 8 https://doi.org/10.1002/aenm.201200166	journal	May 2012
Superior Electrochemical Performance and Storage Mechanism of Na ₃ V ₂ (PO ₄ ) ₃ Cathode for Room-Temperature Sodium-Ion Batteries Jian, Zelang; Han, Wenze; Lu, Xia Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200558	journal	October 2012
Effect of Carbon Matrix Dimensions on the Electrochemical Properties of Na ₃ V ₂ (PO ₄ ) ₃ Nanograins for High-Performance Symmetric Sodium-Ion Batteries Li, Shuo; Dong, Yifan; Xu, Lin Advanced Materials, Vol. 26, Issue 21 https://doi.org/10.1002/adma.201305522	journal	March 2014
Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
In situ X-ray diffraction characterization of NiSe2 as a promising anode material for sodium ion batteries Ou, Xing; Li, Jiao; Zheng, Fenghua Journal of Power Sources, Vol. 343 https://doi.org/10.1016/j.jpowsour.2017.01.097	journal	March 2017
Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials Ong, Shyue Ping; Chevrier, Vincent L.; Hautier, Geoffroy Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01782a	journal	January 2011
Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries Masquelier, Christian; Croguennec, Laurence Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr3001862	journal	June 2013
FeSe ₂ Microspheres as a High-Performance Anode Material for Na-Ion Batteries Zhang, Kai; Hu, Zhe; Liu, Xue Advanced Materials, Vol. 27, Issue 21 https://doi.org/10.1002/adma.201500196	journal	April 2015
A New rGO-Overcoated Sb ₂ Se ₃ Nanorods Anode for Na ⁺ Battery: In Situ X-Ray Diffraction Study on a Live Sodiation/Desodiation Process Ou, Xing; Yang, Chenghao; Xiong, Xunhui Advanced Functional Materials, Vol. 27, Issue 13 https://doi.org/10.1002/adfm.201606242	journal	February 2017
An advanced cathode for Na-ion batteries with high rate and excellent structural stability Lee, Dae Hoe; Xu, Jing; Meng, Ying Shirley Physical Chemistry Chemical Physics, Vol. 15, Issue 9 https://doi.org/10.1039/c2cp44467d	journal	January 2013
Cu3(PO4)2/C composite as a high-capacity cathode material for rechargeable Na-ion batteries Zhao, Wengao; Zhong, Guiming; McDonald, Matthew J. Nano Energy, Vol. 27 https://doi.org/10.1016/j.nanoen.2016.07.011	journal	September 2016
Crystallographic-plane tuned Prussian-blue wrapped with RGO: a high-capacity, long-life cathode for sodium-ion batteries Wang, Hui; Wang, Li; Chen, Shuangming Journal of Materials Chemistry A, Vol. 5, Issue 7 https://doi.org/10.1039/C6TA10592K	journal	January 2017
Sodium Storage and Transport Properties in Layered Na ₂ Ti ₃ O ₇ for Room-Temperature Sodium-Ion Batteries Pan, Huilin; Lu, Xia; Yu, Xiqian Advanced Energy Materials, Vol. 3, Issue 9 https://doi.org/10.1002/aenm.201300139	journal	May 2013
Highly Ordered Mesoporous MoS2 with Expanded Spacing of the (002) Crystal Plane for Ultrafast Lithium Ion Storage Liu, Hao; Su, Dawei; Zhou, Ruifeng Advanced Energy Materials, Vol. 2, Issue 8 https://doi.org/10.1002/aenm.201200087	journal	May 2012
Ultrathin MoS ₂ /Nitrogen-Doped Graphene Nanosheets with Highly Reversible Lithium Storage Chang, Kun; Geng, Dongsheng; Li, Xifei Advanced Energy Materials, Vol. 3, Issue 7 https://doi.org/10.1002/aenm.201201108	journal	April 2013
A Sugar-Derived Room-Temperature Sodium Sulfur Battery with Long Term Cycling Stability Carter, Rachel; Oakes, Landon; Douglas, Anna Nano Letters, Vol. 17, Issue 3 https://doi.org/10.1021/acs.nanolett.6b05172	journal	February 2017
Covalent sulfur for advanced room temperature sodium-sulfur batteries Fan, Ling; Ma, Ruifang; Yang, Yuhua Nano Energy, Vol. 28 https://doi.org/10.1016/j.nanoen.2016.08.056	journal	October 2016
A High-Energy Room-Temperature Sodium-Sulfur Battery Xin, Sen; Yin, Ya-Xia; Guo, Yu-Guo Advanced Materials, Vol. 26, Issue 8 https://doi.org/10.1002/adma.201304126	journal	December 2013
Main Challenges for High Performance NAS Battery: Materials and Interfaces Wen, Zhaoyin; Hu, Yingying; Wu, Xiangwei Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200473	journal	May 2012
Nano-Copper-Assisted Immobilization of Sulfur in High-Surface-Area Mesoporous Carbon Cathodes for Room Temperature Na-S Batteries Zheng, Shiyou; Han, Pan; Han, Zhuo Advanced Energy Materials, Vol. 4, Issue 12 https://doi.org/10.1002/aenm.201400226	journal	April 2014
Ambient-Temperature Sodium-Sulfur Batteries with a Sodiated Nafion Membrane and a Carbon Nanofiber-Activated Carbon Composite Electrode Yu, Xingwen; Manthiram, Arumugam Advanced Energy Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aenm.201500350	journal	April 2015
Achieving High-Performance Room-Temperature Sodium–Sulfur Batteries With S@Interconnected Mesoporous Carbon Hollow Nanospheres Wang, Yun-Xiao; Yang, Jianping; Lai, Weihong Journal of the American Chemical Society, Vol. 138, Issue 51 https://doi.org/10.1021/jacs.6b08685	journal	December 2016
A new energy storage system: Rechargeable potassium-selenium battery Liu, Yajie; Tai, Zhixin; Zhang, Qing Nano Energy, Vol. 35 https://doi.org/10.1016/j.nanoen.2017.03.029	journal	May 2017
Confined selenium within porous carbon nanospheres as cathode for advanced Li–Se batteries Li, Zhen; Yuan, Lixia; Yi, Ziqi Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.07.012	journal	October 2014
The Electrochemistry with Lithium versus Sodium of Selenium Confined To Slit Micropores in Carbon Xin, Sen; Yu, Le; You, Ya Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01819	journal	June 2016
A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium–Sulfur as a Positive Electrode Abouimrane, Ali; Dambournet, Damien; Chapman, Karena W. Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja211766q	journal	February 2012
Elemental Selenium for Electrochemical Energy Storage Yang, Chun-Peng; Yin, Ya-Xia; Guo, Yu-Guo The Journal of Physical Chemistry Letters, Vol. 6, Issue 2 https://doi.org/10.1021/jz502405h	journal	January 2015
Exceptional energy and new insight with a sodium–selenium battery based on a carbon nanosheet cathode and a pseudographite anode Ding, Jia; Zhou, Hui; Zhang, Hanlei Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE02274J	journal	January 2017
A New Salt-Baked Approach for Confining Selenium in Metal Complex-Derived Porous Carbon with Superior Lithium Storage Properties Li, Xiaona; Liang, Jianwen; Hou, Zhiguo Advanced Functional Materials, Vol. 25, Issue 32 https://doi.org/10.1002/adfm.201501956	journal	July 2015
Selenium@Mesoporous Carbon Composite with Superior Lithium and Sodium Storage Capacity Luo, Chao; Xu, Yunhua; Zhu, Yujie ACS Nano, Vol. 7, Issue 9 https://doi.org/10.1021/nn403108w	journal	August 2013
A novel type of one-dimensional organic selenium-containing fiber with superior performance for lithium–selenium and sodium–selenium batteries Wang, Hongqiang; Li, Sha; Chen, Zhixin RSC Adv., Vol. 4, Issue 106 https://doi.org/10.1039/C4RA10967H	journal	January 2014
A Flexible Porous Carbon Nanofibers-Selenium Cathode with Superior Electrochemical Performance for Both Li-Se and Na-Se Batteries Zeng, Linchao; Zeng, Wencong; Jiang, Yu Advanced Energy Materials, Vol. 5, Issue 4 https://doi.org/10.1002/aenm.201401377	journal	November 2014
Bifunctional Separator with a Light-Weight Carbon-Coating for Dynamically and Statically Stable Lithium-Sulfur Batteries Chung, Sheng-Heng; Manthiram, Arumugam Advanced Functional Materials, Vol. 24, Issue 33 https://doi.org/10.1002/adfm.201400845	journal	June 2014
Electrochemistry of Selenium with Sodium and Lithium: Kinetics and Reaction Mechanism Li, Qianqian; Liu, Heguang; Yao, Zhenpeng ACS Nano, Vol. 10, Issue 9 https://doi.org/10.1021/acsnano.6b04519	journal	August 2016
Origin of non-SEI related coulombic efficiency loss in carbons tested against Na and Li Memarzadeh Lotfabad, Elmira; Kalisvaart, Peter; Kohandehghan, Alireza J. Mater. Chem. A, Vol. 2, Issue 46 https://doi.org/10.1039/C4TA04995K	journal	January 2014
Hydroxylated Graphene-Sulfur Nanocomposites for High-Rate Lithium-Sulfur Batteries Zu, Chenxi; Manthiram, Arumugam Advanced Energy Materials, Vol. 3, Issue 8 https://doi.org/10.1002/aenm.201201080	journal	April 2013
Controlling SEI Formation on SnSb-Porous Carbon Nanofibers for Improved Na Ion Storage Ji, Liwen; Gu, Meng; Shao, Yuyan Advanced Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adma.201304962	journal	February 2014
Sodium-Ion Batteries Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201800880	journal	June 2018
A High-Voltage and Ultralong-Life Sodium Full Cell for Stationary Energy Storage Guo, Shaohua; Liu, Pan; Sun, Yang Angewandte Chemie, Vol. 127, Issue 40 https://doi.org/10.1002/ange.201505215	journal	August 2015

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