skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Bivalence Mn5O8 with hydroxylated interphase for high-voltage aqueous sodium-ion storage

Journal Article · · Nature Communications
DOI:https://doi.org/10.1038/ncomms13370· OSTI ID:1594578
 [1];  [1];  [2];  [3];  [2]; ORCiD logo [3];  [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Univ. of New Hampshire, Durham, NH (United States)
  2. Univ. of Pittsburgh, PA (United States)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  5. Brookhaven National Lab. (BNL), Upton, NY (United States)
+ Show Author Affiliations

Aqueous electrochemical energy storage devices have attracted significant attention owing to their high safety, low cost and environmental friendliness. However, their applications have been limited by a narrow potential window (1/41.23 V), beyond which the hydrogen and oxygen evolution reactions occur. Here we report the formation of layered Mn 5 O 8 pseudocapacitor electrode material with a well-ordered hydroxylated interphase. A symmetric full cell using such electrodes demonstrates a stable potential window of 3.0 V in an aqueous electrolyte, as well as high energy and power performance, nearly 100% coulombic efficiency and 85% energy efficiency after 25,000 charge-discharge cycles. The interplay between hydroxylated interphase on the surface and the unique bivalence structure of Mn 5 O 8 suppresses the gas evolution reactions, offers a two-electron charge transfer via Mn 2+ /Mn 4+ redox couple, and provides facile pathway for Na-ion transport via intra-/inter-layer defects of Mn 5 O 8.

Research Organization:
Univ. of New Hampshire, Durham, NH (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0010286; SC00112704; AC02-05CH11231
OSTI ID:
1594578
Alternate ID(s):
OSTI ID: 1328373; OSTI ID: 1337640; OSTI ID: 1377589
Report Number(s):
BNL-112679-2016-JA; BNL-113277-2016-JA
Journal Information:
Nature Communications, Vol. 7, Issue 1; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 104 works
Citation information provided by
Web of Science

References (32)

High-voltage aqueous battery approaching 3 V using an acidic–alkaline double electrolyte journal January 2013
Performance Enhancement and Mechanistic Studies of Room-Temperature Sodium–Sulfur Batteries with a Carbon-Coated Functional Nafion Separator and a Na 2 S/Activated Carbon Nanofiber Cathode journal January 2016
An Aqueous Rechargeable Lithium Battery Using Coated Li Metal as Anode journal March 2013
True Performance Metrics in Electrochemical Energy Storage journal November 2011
Energetics of Hydrogen Bond Network Rearrangements in Liquid Water journal October 2004
Crystal Data of Mn5O8 and Cd2Mn3O8 journal July 1965
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides journal May 2013
Hierarchically structured MnO 2 /graphene/carbon fiber and porous graphene hydrogel wrapped copper wire for fiber-based flexible all-solid-state asymmetric supercapacitors journal January 2015
Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon journal August 2010
The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy journal October 2014
Impedance, power, energy, and pulse performance characteristics of small commercial Li-ion cells journal October 1999
The Structure of the First Coordination Shell in Liquid Water journal May 2004
Towards High Power High Energy Aqueous Sodium-Ion Batteries: The NaTi 2 (PO 4 ) 3 /Na 0.44 MnO 2 System journal October 2012
Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors journal January 1998
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries journal January 2014
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide journal September 2013
Battery materials for ultrafast charging and discharging journal March 2009
High-Performance Sodium-Ion Pseudocapacitors Based on Hierarchically Porous Nanowire Composites journal April 2012
Revealing and suppressing surface Mn(II) formation of Na0.44MnO2 electrodes for Na-ion batteries journal September 2015
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance journal April 2013
Nanostructured materials for advanced energy conversion and storage devices journal May 2005
X-ray absorption spectroscopy and X-ray Raman scattering of water and ice; an experimental view journal March 2010
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries journal November 2015
Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors journal March 2012
High-Performance Supercapacitors Based on Nanocomposites of Nb2O5 Nanocrystals and Carbon Nanotubes journal October 2011
Core Level Spectroscopy of Solids book January 2008
A Spinel-Integrated P2-Type Layered Composite: High-Rate Cathode for Sodium-Ion Batteries journal January 2016
Oxygen 1 s x-ray-absorption edges of transition-metal oxides journal September 1989
Rechargeable Lithium Batteries with Aqueous Electrolytes journal May 1994
Mn 5 O 8 Nanoparticles as Efficient Water Oxidation Catalysts at Neutral pH journal July 2015
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides text January 2012
Comment on "Energetics of Hydrogen Bond Network Rearrangements in Liquid Water" journal May 2005

Cited By (20)

Development of High-Voltage Aqueous Electrochemical Energy Storage Devices journal July 2017
Ultrathin Surface Coating Enables Stabilized Zinc Metal Anode journal August 2018
Noninterference Revealing of “Layered to Layered” Zinc Storage Mechanism of δ‐MnO 2 toward Neutral Zn–Mn Batteries with Superior Performance journal March 2020
Sodium-Ion Batteries: From Academic Research to Practical Commercialization journal September 2017
Progress in Aqueous Rechargeable Sodium-Ion Batteries journal March 2018
A Flexible Solid‐State Aqueous Zinc Hybrid Battery with Flat and High‐Voltage Discharge Plateau journal October 2019
A High Energy Density Aqueous Battery Achieved by Dual Dissolution/Deposition Reactions Separated in Acid‐Alkaline Electrolyte journal March 2020
Toward High‐Voltage, Energy‐Dense, and Durable Aqueous Organic Redox Flow Batteries: Role of the Supporting Electrolytes journal September 2018
Advanced Materials for Sodium‐Ion Capacitors with Superior Energy–Power Properties: Progress and Perspectives journal September 2019
Manganese oxides/N-doped carbon particles with high capacity retention for aqueous rechargeable zinc battery journal March 2019
Fabrication of highly sensitive non-enzymatic sensor based on Pt/PVF modified Pt electrode for detection of glucose journal September 2019
Electric-field control of tri-state phase transformation with a selective dual-ion switch journal May 2017
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities journal September 2017
Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers journal April 2018
Highly Efficient Non-Enzymatic Glucose Sensor Based on CuO Modified Vertically-Grown ZnO Nanorods on Electrode journal July 2017
Comparison of the electrochemical performance of iron hexacyanoferrate with high and low quality as cathode materials for aqueous sodium-ion batteries journal January 2017
Voltage issue of aqueous rechargeable metal-ion batteries journal January 2020
Soft x-ray spectroscopy of high pressure liquid journal January 2018
Calorimetric study of the thermodynamic properties of Mn 5 O 8 journal July 2018
Emergent electric field control of phase transformation in oxide superlattices text January 2020

Similar Records

Related Subjects

25 ENERGY STORAGE
Mn5O8
aqueous sodium-ion storage
Center for Functional Nanomaterials
29 ENERGY PLANNING, POLICY, AND ECONOMY
Mn5O8