Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly

Zhou, Min; Zhao, Jiahua; Zhang, Pengfei; Chen, Nanqing; Yang, Shize

doi:10.1039/C9CY00970A

Title: Solvent-free and rapid synthesis of mesoporous Pt–iron oxide catalysts via mechanochemical assembly

Journal Article · Mon Jul 01 00:00:00 EDT 2019 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/C9CY00970A· OSTI ID:1570676

Zhou, Min ^[1]; Zhao, Jiahua ^[2];

^[2]; Chen, Nanqing ^[3];

^[4]

East China Normal Univ., Shanghai (China)
Shanghai Jiao Tong Univ. (China)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Mesoporous Fe_xO_y and Pt@Fe_xO_y have proven promising performance in catalysis. Yet, current methods usually use wet chemistry, which poses several drawbacks. Here, we introduce a simple process of mechanochemical assembly between an iron salt and a triblock copolymer in the solid state that can not only directly form abundant mesopores into Fe_xO_y, but also enable a high dispersion of Pt species at the nm or sub-nm scale. In this regard, mesoporous FexOy and Pt@Fe_xO_y catalysts with high surface areas (up to 149 m² g^-1) and narrow pore size distributions (~5 nm) can be obtained in a solvent-free and rapid (0.5 h) way. The kinetic energy and frictional heating of ball milling are expected to promote the interaction and diffusion between iron precursors and surfactants, while the solvent-free feature confines their assembly to the mesophase of the P123 copolymer. Moreover, these Pt@Fe_xO_y catalysts provide good activity in the total oxidation of propylene and CO.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: SC0012704

OSTI ID:: 1570676

Report Number(s):: BNL-212200-2019-JAAM; CSTAGD

Journal Information:: Catalysis Science and Technology, Vol. 9, Issue 15; ISSN 2044-4753

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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