skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High efficiency iron electrode and additives for use in rechargeable iron-based batteries

Patent ·
OSTI ID:1568683

An iron electrode and a method of manufacturing an iron electrode for use in an iron-based rechargeable battery are disclosed. In one embodiment, the iron electrode includes carbonyl iron powder and one of a metal sulfide additive or metal oxide additive selected from the group of metals consisting of bismuth, lead, mercury, indium, gallium, and tin for suppressing hydrogen evolution at the iron electrode during charging of the iron-based rechargeable battery. An iron-air rechargeable battery including an iron electrode comprising carbonyl iron is also disclosed, as is an iron-air battery wherein at least one of the iron electrode and the electrolyte includes an organosulfur additive.

Research Organization:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AR0000136
Assignee:
University of Southern California (Los Angeles, CA)
Patent Number(s):
10,374,261
Application Number:
15/358,291
OSTI ID:
1568683
Resource Relation:
Patent File Date: 11/22/2016
Country of Publication:
United States
Language:
English

References (47)

Preparation of an alkaline iron electrode material using sulfur acids patent March 1976
Thin Film for Package of Alkaline Battery and Thin Air Battery Using the Same patent-application April 2007
Coiled Electrode Battery patent February 1962
Boardlock system for electrical connectors patent September 1993
Preparation of Battery Plates with Iron Oxides Having a Fused Coating patent March 1972
Alkaline Storage Battery Having Super-Activated Electrodes and Method of Superactivating the Electrode Materials patent November 1962
Method of producing self-supporting fully activated iron electrodes by thermal reduction-sintering patent January 1979
Alkaline storage battery and method for producing an electrode used therefor patent November 2000
Metal Oxide-Carbon Composite Catalyst Support and Fuel Cell Comprising the Same patent-application May 2005
Alkaline Storage Battery with Negative Iron Electrode patent January 1959
Method and Products for Improving Performance of Batteries/Fuel Cells patent-application March 2003
Method of Loading Iron-Sulfur Active Material Into Porous Metallic Plaques patent September 1970
Electrodeposition of Iron Active Mass patent July 1975
Iron Electrode patent July 1972
Negative, highly active iron electrode patent June 1980
Air Cathode Having Multiple Layered Sintering Structure and its Process for Producing the Same patent-application December 2005
Metal-rich iron sulfide cathode material patent June 1982
Reversible Galvanic Battery patent July 1901
Iron-Air Rechargeable Battery patent-application July 2012
High Efficiency Iron Electrode and Additives for Use in Rechargeable Iron-Based Batteries patent-application June 2013
Composite material for negative electrode, method for fabricating the same and electrochemical device using the same patent July 2013
Rechargeable Metal Electrode for Storage Batteries and Metal-Air Cells patent June 1974
Iron-silver battery having a shunt electrode patent May 1983
Process for producing iron electrode patent August 1975
High performance energy storage devices patent-application May 2007
Stabilized iron electrodes patent March 1978
Oxygen-reduction electrocatalysts for electrodes patent January 1976
Method for producing an iron electrode for an alkaline accumulator patent May 1977
Removing carbon dioxide from the air patent September 1977
Iron-air rechargeable battery patent June 2014
Iron Electrode Paste for Alkaline Battery Plates patent November 1974
Method of preparing a sintered iron electrode patent June 1982
High Efficiency Iron Electrode and Additives for Use in Rechargeable Iron-Based Batteries patent-application May 2017
Metal-Air Battery With Ion Exchange Materials patent-application February 2011
Method of manufacturing an iron electrode for alkaline accumulators patent October 1978
Electrochemical cell having a deposited gas electrode patent April 2010
Procedure to stabilize an iron air battery patent June 1977
Electrode, Method of its Production, Metal-Air Fuel Cell and Metal Hydride Cell patent-application April 2007
Battery with an Iron Electrode Having a Fused Coating patent April 1970
Oxygen Reduction Electrode patent-application July 2004
Iron active electrode and method of making same patent October 1982
Process of Manufacturing Iron Electrodes for Use in Alkaline Accumulators patent February 1911
Flexible Battery patent February 1962
Gas diffusion layer arrangement for a fuel cell patent May 2005
High Energy Density Iron-Nickel Battery patent December 1974
Method of Fabricating Iron Electrodes for Alkaline Storage Batteries patent August 1970
Additive for activating iron electrodes in alkaline batteries patent February 1981