Ionic-Liquid-Gating Induced Protonation and Superconductivity in FeSe, FeSe0.93S0.07, ZrNCl, 1T-TaS2 and Bi2Se3 *

Cui, Yi; Hu, Ze; Zhang, Jin-Shan; Ma, Wen-Long; Ma, Ming-Wei; Ma, Zhen; Wang, Cong; Yan, Jia-Qiang; Sun, Jian-Ping; Cheng, Jin-Guang; Jia, Shuang; Li, Yuan; Wen, Jin-Sheng; Lei, He-Chang; Yu, Pu; Ji, Wei; Yu, Wei-Qiang

doi:10.1088/0256-307X/36/7/077401

Title: Ionic-Liquid-Gating Induced Protonation and Superconductivity in FeSe, FeSe_0.93S_0.07, ZrNCl, 1T-TaS₂ and Bi₂Se₃ ^*

Journal Article · Sat Jun 01 00:00:00 EDT 2019 · Chinese Physics Letters

DOI:https://doi.org/10.1088/0256-307X/36/7/077401· OSTI ID:1564119

Cui, Yi ^[1]; Hu, Ze ^[2]; Zhang, Jin-Shan ^[3]; Ma, Wen-Long ^[4]; Ma, Ming-Wei ^[4]; Ma, Zhen ^[5]; Wang, Cong ^[2]; Yan, Jia-Qiang ^[6]; Sun, Jian-Ping ^[7]; Cheng, Jin-Guang ^[7]; Jia, Shuang ^[8]; Li, Yuan ^[8]; Wen, Jin-Sheng ^[9]; Lei, He-Chang ^[2]; Yu, Pu ^[10]; Ji, Wei ^[2]; Yu, Wei-Qiang ^[2]

North China Electric Power Univ., Beijing (China). School of Mathematics and Physics; Renmin Univ., Beijing (China). Dept. of Physics, and Beijing Key Lab. of Optoelectronic Functional Materials & Micro-nano Devices
Renmin Univ., Beijing (China). Dept. of Physics, and Beijing Key Lab. of Optoelectronic Functional Materials & Micro-nano Devices
North China Electric Power Univ., Beijing (China). School of Mathematics and Physics
Peking Univ., Beijing (China). International Center for Quantum Materials, School of Physics
Nanjing Univ., Nanjing (China). National Lab. of Solid State Microstructures and Dept. of Physics
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Chinese Academy of Sciences, Beijing (China). Beijing National Lab. for Condensed Matter Physics and Institute of Physics
Peking Univ., Beijing (China). International Center for Quantum Materials, School of Physics; Collaborative Innovation Center of Quantum Matter, Beijing (China)
Nanjing Univ., Nanjing (China). National Lab. of Solid State Microstructures and Dept. of Physics; Nanjing Univ. (China). Innovative Center for Advanced Microstructures
Collaborative Innovation Center of Quantum Matter, Beijing (China); Tsinghua Univ., Beijing (China). State Key Lab. of Low Dimensional Quantum Physics and Dept. of Physics

We report protonation in several compounds by an ionic-liquid-gating method, under optimized gating conditions. This leads to single superconducting phases for several compounds. Non-volatility of protons allows post-gating magnetization and transport measurements. The superconducting transition temperature T_c is enhanced to 43.5 K for FeSe_0.93S_0.07, and 41 K for FeSe after protonation. Superconducting transitions with T_c ~ 15 K for ZrNCl, ~7.2 K for 1T-TaS₂, and ~3.8 K for Bi₂Se₃ are induced after protonation. Electric transport in protonated FeSe_0.93S_0.07 confirms high-temperature superconductivity. Our ¹H nuclear magnetic resonance (NMR) measurements on protonated FeSe_1-xS_x reveal enhanced spin-lattice relaxation rate 1/¹ T₁ with increasing x, which is consistent with the LDA calculations that H⁺ is located in the interstitial sites close to the anions.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1564119

Journal Information:: Chinese Physics Letters, Vol. 36, Issue 7; ISSN 0256-307X

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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Title: Ionic-Liquid-Gating Induced Protonation and Superconductivity in FeSe, FeSe_0.93S_0.07, ZrNCl, 1T-TaS₂ and Bi₂Se₃ ^*