Graphene quantum dots (GQDs)-polyethyleneimine as interlayer for the fabrication of high performance organic solvent nanofiltration (OSN) membranes

Journal Article · Wed Jan 15 00:00:00 EST 2020 · Chemical Engineering Journal

DOI:https://doi.org/10.1016/j.cej.2019.122462· OSTI ID:1559643

Liang, Yizhi ^[1]; Li, Can ^[1]; Li, Shuxuan ^[1]; Su, Baowei ^[1]; Hu, Michael  ^[2]; Gao, Xueli ^[1]; Gao, Congjie ^[1]

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1. Ocean Univ. of China, Qingdao (China)
2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Novel thin film nanocomposite (TFN) organic solvent nanofiltration (OSN) membranes with sandwich-like structure were developed via interfacial polymerization (IP) using both low concentration m-phenylenediamine (MPD) and trimesoyl chloride (TMC), on graphene quantum dots (GQDs)-polyethyleneimine (PEI) modified polyimide substrate surface, and followed by post-IP crosslinking and solvent activation. Such GQDs-interlayered OSN membranes have exhibited a remarkable reduced thickness (about 25 nm) and an ultra-low average surface roughness (less than 2 nm) of their IP skin layers, respectively. Both material features are rarely reported in literature. Meanwhile, our GQDs-interlayered OSN membranes have shown an increased Rhodamine B (479 Da) rejection (from 87.4% to 98.7%) and an increased ethanol permeance (from 33.5 to 40.3 L m^-2 h^-1 MPa^-1) compared with the pristine OSN membrane. Superior solvent resistance was demonstrated after long immersion in pure N, N-dimethylformamide (DMF) at room temperature for 81 days, and at 80 °C for 45 days, and after a long-term consecutively filtration with Rose Bengal (1017 Da) DMF solution at 25 °C for 5 days, without scarifying solute rejection. Antifouling properties during the long-term filtration were also indicated. This paper presents a novel GQDs-interlayered strategy in developing high-performance TFN membranes for OSN application.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE Office of Energy Efficiency and Renewable Energy (EERE)
• Grant/Contract Number: AC05-00OR22725
• OSTI ID: 1559643
• Journal Information: Chemical Engineering Journal, Vol. 380, Issue NA; ISSN 1385-8947
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

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